Novel approaches for the production of bio-diesel using waste vegetable oil

2014 ◽  
Vol 3 (10) ◽  
pp. 3419
Author(s):  
Mohan Reddy Nalabolu* ◽  
Varaprasad Bobbarala ◽  
Mahesh Kandula

At the present moment worldwide waning fossil fuel resources as well as the tendency for developing new renewable biofuels have shifted the interest of the society towards finding novel alternative fuel sources. Biofuels have been put forward as one of a range of alternatives with lower emissions and a higher degree of fuel security and gives potential opportunities for rural and regional communities. Biodiesel has a great potential as an alternative diesel fuel. In this work, biodiesel was prepared from waste cooking oil it was converted into biodiesel through single step transesterification. Methanol with Potassium hydroxide as a catalyst was used for the transesterification process. The biodiesel was characterized by its fuel properties including acid value, cloud and pour points, water content, sediments, oxidation stability, carbon residue, flash point, kinematic viscosity, density according to IS: 15607-05 standards. The viscosity of the waste cooking oil biodiesel was found to be 4.05 mm2/sec at 400C. Flash point was found to be 1280C, water and sediment was 236mg/kg, 0 % respectively, carbon residue was 0.017%, total acid value was 0.2 mgKOH/g, cloud point was 40C and pour point was 120C. The results showed that one step transesterification was better and resulted in higher yield and better fuel properties. The research demonstrated that biodiesel obtained under optimum conditions from waste cooking oil was of good quality and could be used as a diesel fuel.

2014 ◽  
Vol 660 ◽  
pp. 386-390 ◽  
Author(s):  
Norazwan Azman ◽  
Mirnah Suardi ◽  
Amir Khalid

The use of fossil fuels as energy sources has grown to significantly be likely to have a major environmental impact. Reduction of world oil reserves and increasing environmental concerns have prompted alternative is found and renewable source of energy called biodiesel. Biodiesel fuel from vegetable oil is considered as the best candidates for diesel fuel replacement in diesel engines because of its closer. Fuel prices are going up day by day in the world. Thus, the means and methods have been trying for years to get fuel alternative outcomes. This study investigated the effects of different storage periods used in quality biodiesel blends (B5, B10, B15) of waste cooking oil and diesel fuel under low temperature and the temperature of the environment. Biodiesel samples were stored in glass containers under indoor conditions, and outdoor conditions for 10 weeks in total. These samples were monitored on a weekly basis through the test properties. The experimental density, viscosity, acid value, water content and flash point discussed in detail. Biodiesel storage at low temperatures is suitable and more advantageous because the impact on the physical properties is minimal and beneficial to slow down the degradation of biodiesel and storage.


2022 ◽  
Vol 34 (2) ◽  
pp. 319-323
Author(s):  
K.A. Viraj Miyuranga ◽  
Udara S.P.R. Arachchige ◽  
Danushka Thilakarathne ◽  
Randika A. Jayasinghe ◽  
Nuwan A. Weerasekara

Biodiesel is a renewable fuel with similar chemical and physical properties to diesel. The study used waste cooking oil to make biodiesel because reusing waste cooking oil harms human health by raising FFA levels above the norm. Transesterification was performed at 60 °C using a 1:5 methanol to waste cooking oil volume ratio, 30 min reaction time, 600 rpm stirring speed and 1% wt. KOH was employed as a homogenous base catalyst. Biodiesel samples of B0, B2, B5, B20, B40 and B100 were processed at 25 ºC in combination with petrodiesel. Samples were tested for density, kinetic viscosity, flash point, acid value and pH. The fuel economy and flue gas analysis were performed using three-wheeler diesel. The amount of waste cooking oil biodiesel increases the density, kinematic viscosity, flash point, acid value and pH of the sample. In blended diesel, the amount of biodiesel also lowered CO2, CO, NO, NOx, hydrocarbon (HC) and SO2 emissions.


2012 ◽  
Vol 550-553 ◽  
pp. 687-692
Author(s):  
Guang Rui Liu ◽  
Guan Yi Chen

Biodiesel, as an alternative auto fuel for conventional fossil fuel, has drawn wide attention in recent years. In this research, a two-step process for biodiesel production using waste cooking oil as feedstock was studied in a pilot plant with a treatment capacity of 3 ton/d. The results show that: the process exihibited a good conversion ratio and the biodiesel displayed suitable physical-chemical properties in comparison with diesel fuel, such as flash point of 137°C, viscosity of 4.49 mm2/s, acid value of 0.44 mg KOH/g etc. The quality of biodiesel meets the agreement with the European specification defined by EN 14214. Afterwards, the mixture of biodiesel and diesel were test in the engine with a ratio of 50/50(v/v), 20/80(v/v), and 0/100(v/v). It indicates the mixed fuel has a reasonable fuel consumption rates without diesel engine modification, when the biodiesel blended with 0# diesel as fuel. The present results demonstrated that the industrial scale plant would achieve promising objective with waste cooking oils and animal fats as raw material. Also, this biodiesel-based diesel fuel could be applied in Tianjin local public transportation system that improves its sustainable development.


2020 ◽  
Vol 24 (5) ◽  
pp. 749-753
Author(s):  
A.O. Mustapha ◽  
T.A. Amodu ◽  
R.A. Adepoju

The waste cooking oil (WCO) has been a prospective and cheap feedstock for biodiesel with no competing food uses, but impurities affects biodiesel yield and result in higher production cost. This study examined the effects of degumming WCO on the physicochemical and fuel properties of biodiesel using degummed-bleached cooking oil (DCO), and methanol in the presence of sodium hydroxide catalyst. The properties and fatty acids profile were determined using the Association of Officials of Analytical Chemists (AOAC), American Society for Test and Material (ASTM) Quality, gas chromatography mass spectroscopy (GCMS) technique while the Fourier transform infrared (FTIR) gave the foremost peak regions between 1600-3600 cm-1. The pH of degummed cooking methyl ester (DCME), degummed-bleached cooking oil (DCO) and WCO varied between 5.83 and 8.61. Density of DCME, DCO and WCO varied between 0.88 and 0.93 (g/cm3). Comparing the quality improvements between DCO and WCO, the results showed percentage increases in properties such as recovery yield (8.5%), acid value (61.5%), saponification value (10.8%), iodine value (4.9%), peroxide value (26.9%), calorific value (10.9%), specific gravity (6.3%), density (2.2%), kinematic viscosity @ 40OC (54.2%), smoke point, OC (30.9%), flash point, OC (12.1%), fire point, OC (10.8%), pour point @ 40oC (2.3%), higher heating value (0.7%), and cetane number (-29.6%). The fatty acids profile in DCO has octanoic acid (5.86%), benzoic acid (3.74%), and hexadecanoic acid (74%) was the most abundant. The biodiesel from DCO as feedstock have quality improvements over WCO, and values compared well with ASTM standard recommendations. Keywords: biodiesel, waste cooking oil, degumming, physicochemical


Author(s):  
Ramanathan Velmurugan ◽  
Jaikumar Mayakrishnan ◽  
S. Induja ◽  
Selvakumar Raja ◽  
Sasikumar Nandagopal ◽  
...  

Vegetable oil is considered as one among the promising alternatives for diesel fuel as it holds properties very close to diesel fuel. However, straight usage of vegetable oil in compression ignition (CI) engine resulted in inferior performance and emission behavior. This can be improved by modifying the straight vegetable oil into its esters, emulsion, and using them as a fuel in CI engine showcased an improved engine behavior. Waste cooking oil (WCO) is one such kind of vegetable oil gained a lot of attraction globally as it is generated in a large quantity locally. The present investigation aims at analyzing various parameters of single cylinder four stroke CI engine fueled with waste cooking oil biodiesel (WCOB), waste cooking oil biodiesel water emulsion (WCOBE) while the engine is operated with a constant speed of 1500 rpm. Furthermore, an attempt is made to study the impact of nanofluids in the behavior of the engine fueled with WCOB blended with nanofluids (WCOBN50). This work also explored a novel method of producing nanofluids using one-step chemical synthesis method. Copper oxide (CuO) nanofluids were prepared by the above mentioned method and blended with waste cooking oil biodiesel (WCOBN50) using ethylene glycol as a suitable emulsifier. Results revealed that brake thermal efficiency (BTE) and brake specific fuel consumption (BSFC) of WCOBN50 are significantly improved when compared to WCOB and WCOBE. Furthermore, a higher reduction in oxides of nitrogen (NOx), carbon monoxide (CO), hydrocarbon (HC), and smoke emissions were observed with WCOBN50 on comparison with all other tested fuels at different power outputs. It is also identified that one-step chemical synthesis method is a promising technique for preparing nanofluids with a high range of stability.


Author(s):  
H. Sharon ◽  
Joel Jackson R. ◽  
Prabha C.

Feed stock cost and NOX emission are the major barriers for commercialization of biodiesel. Waste cooking oil is well identified as one of the cheapest feed stocks for biodiesel production. This chapter reduces NOX emission of waste cooking oil biodiesel. Test fuel blends are prepared by mixing diesel (20 to 50 v/v%), butanol (5 v/v%), and waste cooking oil biodiesel (45 to 75 v/v%). Fuel properties of waste cooking oil biodiesel are enhanced due to addition of diesel and butanol. Brake specific energy consumption of the blends is higher than diesel fuel. Harmful emissions like carbon monoxide, nitrous oxide, and smoke opacity are lower for blends than diesel fuel. Increasing biodiesel concentration in blend also reduces hydrocarbon emission to a significant extent. The obtained results justify the suitability of proposed cheap blends for diesel engine emission reduction.


2018 ◽  
Vol 1049 ◽  
pp. 012091 ◽  
Author(s):  
Nadiarulah Nanihar ◽  
Amir Khalid ◽  
Fathul Hakim ◽  
Norshuhaila Mohamed Sunar ◽  
Bukhari Manshoor ◽  
...  

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