Application of spectroscopic methods for identification (FT-IR, Raman spectroscopy) and determination (UV, EPR) of quercetin-3-O-rutinoside. Experimental and DFT based approach

2015 ◽  
Vol 140 ◽  
pp. 132-139 ◽  
Author(s):  
Magdalena Paczkowska ◽  
Kornelia Lewandowska ◽  
Waldemar Bednarski ◽  
Mikołaj Mizera ◽  
Agnieszka Podborska ◽  
...  
Keyword(s):  
Raman Spectroscopy ◽  
Spectroscopic Methods ◽  
Ft Ir

Urinary Stone Layer Analysis of Mineral Components by Raman Spectroscopy, IR Spectroscopy, and X-ray Powder Diffraction: A Comparative Study

1997 ◽  
Vol 51 (8) ◽  
pp. 1205-1209 ◽  
Author(s):  
C. G. Kontoyannis ◽  
N. C. Bouropoulos ◽  
P. G. Koutsoukos
Keyword(s):  
Raman Spectroscopy ◽  
Powder Diffraction ◽  
Topological Analysis ◽  
Urinary Stone ◽  
Spectroscopic Methods ◽  
Accurate Analysis ◽  
X Ray ◽  
Layer Analysis ◽  
Mineral Components ◽  
Ft Ir

Mineral components of a urinary stone forming layers have been analyzed with the use of Raman spectroscopy (RS), Fourier transform infrared spectroscopy (FT-IR), and X-ray powder diffraction (XRD). The three spectroscopic methods were compared with respect to their capability of yielding reliable analytical qualitative results. The application of RS yielded less crowded spectra with sharper bands in comparison with those obtained by FT-IR. The analysis of the various mineral layers found in a human stone was possible with RS by focusing the laser beam at the desired layer. Overlapping broad bands were produced from the application of FT-IR, which made it difficult to identify components whose bands showed overlapping. Powder XRD could not be used for accurate analysis of the mineral components of the various stone layers since the material contained in the layers of small stones is not sufficient for analytical purposes. Moreover, the necessary stone grinding precludes the possibility of mineral topological analysis.

scholarly journals Quantitative analysis of doxorubicin hydrochloride and arterolane maleate by mid IR spectroscopy using transmission and reflectance modes

BMC Chemistry ◽  
2021 ◽  
Vol 15 (1) ◽  
Author(s):  
Ranju Bansal ◽  
Ranjit Singh ◽  
Khushpal Kaur
Keyword(s):  
Quantitative Analysis ◽  
Spectroscopic Methods ◽  
Doxorubicin Hydrochloride ◽  
Intermediate Precision ◽  
Solid Dosage ◽  
Ich Guidelines ◽  
Relative Standard ◽  
Ft Ir ◽  
Solid Bulk ◽  
Ir Spectroscopic

Abstract Background Environment-friendly fast and accurate mid-infrared spectroscopic methods have been developed for the quantitative analysis of doxorubicin hydrochloride (DOX) and arterolane maleate (ALM) in bulk and marketed formulations. Both transmittance and reflectance modes have been used for the analysis and a comparison has been drawn for better accuracy. The analytical methods were validated in accordance with International Council for Harmonisation (ICH) guidelines Results The proposed methods have been successfully developed and validated for the quantification of doxorubicin and arterolane maleate in solid bulk and dosage form. High recovery values in both the modes, while analysing DOX and ALM, indicated good accuracy of the methods. The methods showed excellent repeatability and intermediate precision [% RSD (Relative Standard Deviation < 2.0%]. The assay values of the drugs in solid dosage forms were also found close to the labelled claim. Conclusion The proposed Fourier transform infrared (FT-IR) spectroscopic methods were found to be specific, reproducible, valid and could be used as general methods for the quantification of most of the solid drug preparations such as tablets, capsules and powders.

scholarly journals Spectroscopic Methods in the Evaluation of Modified Vegetable Base Oils from Crambe abyssinica

Molecules ◽  
2018 ◽  
Vol 23 (12) ◽  
pp. 3243 ◽  
Author(s):  
Michał Szmatoła ◽  
Justyna Chrobak ◽  
Rafał Grabowski ◽  
Jolanta Iłowska ◽  
Julia Woch ◽  
...  
Keyword(s):  
Nmr Spectroscopy ◽  
Vegetable Oil ◽  
Supercritical Co2 ◽  
Spectroscopic Methods ◽  
Spectroscopic Techniques ◽  
Chemical Transformations ◽  
Chemical Changes ◽  
Crambe Abyssinica ◽  
Oxidation Processes ◽  
Ft Ir

Raw vegetable oil from Crambe abyssinica was subjected to oxidative treatment to enhance its viscosity. The oxidation processes were carried out in the presence of N-hydroxyphthalimide with or without supercritical CO2 as a solvent. Four spectroscopic techniques (Raman, UV-VIS, FT-IR, NMR) were applied to assess the chemical changes taking place during the oxidation. Raman and NMR spectroscopy proved best in the assessment of the chemical transformations leading to increased viscosity of the modified vegetable oil.

scholarly journals Use of Raman Spectroscopy and FT-IR to Characterize the Biochar in Yellow Oxisol of Central Amazonia

2017 ◽  
Vol 9 (5) ◽  
pp. 1996-2006
Author(s):  
Felipe J. Padilha ◽  
Marcondes S. Silva ◽  
Rodrigo S. Guimarães ◽  
Johnny C. C. Cedano ◽  
Danielle M. Oliveira ◽  
...  
Keyword(s):  
Raman Spectroscopy ◽  
Central Amazonia ◽  
Ft Ir

scholarly journals Vitamin C − protective role in oxidative stress conditions induced in human normal colon cells by label free Raman spectroscopy and imaging

2021 ◽  
Author(s):  
Karolina Beton ◽  
Beata Brozek-Pluska
Keyword(s):  
Oxidative Stress ◽  
Raman Spectroscopy ◽  
Vitamin C ◽  
Human Colon ◽  
Protective Role ◽  
Spectroscopic Methods ◽  
Label Free ◽  
Normal Cells ◽  
Colon Cells ◽  
Cancerous Cells

Colorectal cancer is the second most frequently diagnosed cancer worldwide. Conventional diagnostics methods of colorectal cancer, can detect it in advanced stage. Spectroscopic methods, including Raman spectroscopy and imaging, are becoming more and more popular in medical applications, and allow fast, precise and unambiguous differentiation of healthy and cancerous samples. the most important advantage of Raman spectroscopy is ability to identify biomarkers that help in differentiation of healthy and cancerous cells based on biochemistry of sample and spectra typical for: lipids, proteins, DNA. The aim of the study was to evaluate the biochemical and structural features of human colon cell lines based on Raman spectroscopy and imaging: normal cells CCD-18 Co, normal cells CCD-18 Co under oxidative stress conditions, normal cells CCD-18 Co at first treated by using tert-Butyl hydroperoxide and then supplemented by vitamin C in high concentration to show the protective role of vitamin C in micromolar concentrations against ROS by spectroscopic methods. Raman data obtained for normal cells injured by ROS were compared with spectra typical for cancerous cells. Statistically assisted analysis has shown that normal, ROS injured and cancerous human colon cells can be distinguished based on their unique vibrational properties. The research carried out proves that label-free Raman spectroscopy may play an important role in clinical diagnostics differentiation of normal and cancerous colon cells and may be a source of intraoperative information supporting histopathological analysis.

scholarly journals SYNTHESIS AND CHARACTERIZATION: COMPOSITE OF GRAPHENE OXIDE BASED PALM KERNEL SHELL WASTE WITH FE3O4

2021 ◽  
Vol 22 (2) ◽  
pp. 101
Author(s):  
Bernadeta Ayu Widyaningrum ◽  
Dita Apriani ◽  
Putri Amanda ◽  
Ismadi Ismadi ◽  
Sutanto Sutanto
Keyword(s):  
Raman Spectroscopy ◽  
Graphene Oxide ◽  
Palm Kernel ◽  
Energy Dispersive Spectrum ◽  
Energy Dispersive ◽  
Synthesis And Characterization ◽  
Palm Kernel Shell ◽  
Shell Waste ◽  
Ft Ir ◽  
Co Precipitation

SYNTHESIS AND CHARACTERIZATION: COMPOSITE OF GRAPHENE OXIDE BASED PALM KERNEL SHELL WASTE WITH Fe3O4. In this study, GO-Fe3O4 were fabricated by co-precipitation technique and the graphene oxide (GO) were synthesized from an agricultural biomass, palm kernel shell, via Hummer’s method. Field Emission Scanning Electron Microscopy and Energy Dispersive Spectrum (FESEM-EDS), Fourier Transform Infra-Red (FT-IR) spectroscopy, X-Ray Diffractometer (XRD), and Raman spectroscopy were used to analysis the successful attachment of Fe3O4 onto the surface of GO. Morphology observation showed that Fe3O4 were heterogeneously deposited on the surface of GO. FT-IR spectra shows peak that incorporated to oxygenated functional groups and sharp peak at 586 cm-1 confirmed to lattice absorption of Fe3O4. The percentage of composition of GO-Fe3O4 was characterized by energy dispersive spectroscopy and the results also confirmed in XRD exhibits similar properties with JCPDS 19-0629 for magnetite more dominant than GO. From Raman spectroscopy analysis shows that 1343.82 cm-1 (D-band) and 1584.62 cm-1 (G-band) and 2698 cm-1 (2D-band) indicates GO and GO-Fe3O4 were successfully synthesized.

scholarly journals Investigation of the Local Structure of Vanadium Silicalite Catalyst (VS-1) Using XAFS, FT-IR and Photoluminescence Spectroscopic Methods

1999 ◽  
Vol 38 (S1) ◽  
pp. 47 ◽  
Author(s):  
Shinya Higashimoto ◽  
Masaya Matsuoka ◽  
Hiromi Yamashita ◽  
Masakazu Anpo
Keyword(s):  
Local Structure ◽  
Spectroscopic Methods ◽  
Ft Ir

Side Chain Influence on Main Chain Orientation of PPV-Type Oligomers

1999 ◽  
Vol 598 ◽  
Author(s):  
Ruth Müllner ◽  
Laurence Noirez ◽  
Egbert Zojer ◽  
Franz Stelzer ◽  
Günther Leising
Keyword(s):  
Magnetic Field ◽  
Neutron Diffraction ◽  
Main Chain ◽  
Side Chain ◽  
Phenylene Vinylene ◽  
Spectroscopic Methods ◽  
Polarized Optical Microscopy ◽  
Chain Orientation ◽  
H Nmr ◽  
Ft Ir

ABSTRACTOligo (p-phenylene vinylene)s OPV were synthesized having cyanobiphenyloxy-groups bonded to the vinylene double bonds via alkylene spacers. A Pd(0)-reaction was used to synthesize the oligomers starting with the dibromo-substituted benzene and the alkenyloxy-biphenyl-nitrile. The orientation of the mesogens by a magnetic field and their influence on the orientation of the main chain was investigated by means of neutron diffraction ND. Data on the photophysics of the oligomers were gained using several spectroscopic methods such as UV/VIS, polarized optical microscopy POM, SEC, 1H-NMR, FT-IR.

Hybrid Nanocomposites Based on Metal Oxides and Polysiloxanes with Controlled Morphology

2007 ◽  
Vol 1007 ◽  
Author(s):  
Sorin Ivanovici ◽  
Christoph Rill ◽  
Claudia Feldgitscher ◽  
Guido Kickelbick
Keyword(s):  
Metal Oxides ◽  
Sol Gel ◽  
Hybrid Nanocomposites ◽  
Hybrid Nanoparticles ◽  
Spectroscopic Methods ◽  
Metal Alkoxides ◽  
Transmission Electron ◽  
Sol Gel Process ◽  
Ft Ir ◽  
Controlled Morphology

ABSTRACTHybrid materials based on polysiloxanes and metal oxides (SiO2, TiO2, ZrO2) were prepared by hydrosilation of allyl acetoacetate (AAA) modified metal alkoxides (M(OR)4; M = Ti, Zr; R = ethyl, isopropyl) or vinyl triethoxysilane with poly(dimethylsiloxane-co-hydrosiloxane) (PDMS-co-PMHS). The obtained compounds acted as single-source precursors in the sol-gel process. Various spectroscopic methods showed the complete functionalization of the polysiloxane chains with the complexes. When alcohols were used as solvents in the sol-gel process, hybrid nanoparticles were obtained, as observed by dynamic light scattering (DLS) measurements, transmission electron microscopy (TEM), and spectroscopic methods such as NMR and FT-IR.

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