scholarly journals Oriented ZnO nanoflowers obtained after calcination of electrospinning poly(vinyl alcohol)/zinc oxide/zinc acetate composite mats

Author(s):  
Anchan Khankhean ◽  
Wantana Kuratsameethong ◽  
Somtop Santibenchakul ◽  
Apirat Laobuthee ◽  
Masataka Sugimoto ◽  
...  
Polymers ◽  
2019 ◽  
Vol 11 (5) ◽  
pp. 922 ◽  
Author(s):  
Francesca Luzi ◽  
Alessandro Di Michele ◽  
Luigi Torre ◽  
Debora Puglia

Poly(vinyl alcohol-co-ethylene) (EVOH) films containing zinc oxide nanorods (ZnO Nrods) at 0.1, 0.5, and 1 wt%, were realized by solvent casting. The effect of ZnO Nrods content on morphological, thermal, optical, mechanical, and oxygen permeability properties were analyzed. In addition, moisture content and accelerated-aging test studies were performed, with the intention to determine the influence of zinc oxide nanofillers on the functional characteristics of realized packaging systems. Tensile properties showed increased values for strength and deformation-at-break in EVOH-based formulations reinforced with 0.1 and 0.5 wt% of zinc oxide nanorods. Results from the colorimetric and transparency investigations underlined that the presence of ZnO Nrods in EVOH copolymer did not induce evident alterations. In addition, after the accelerated-aging test, the colorimetric test confirmed the possibility for these materials to be used in the packaging sector. This behavior was induced by the presence of zinc oxide nanofillers that act as a UV block that made them useful as an efficient absorber of UV radiation.


Author(s):  
Eva Trumsina ◽  
Zane Zelca ◽  
Silvija Kukle

In the market a wide variety of products are find that contains/releases metal nanoparticles, therefore topical become researches on it impacts on the environment and human health. In the textile industry important step is the development of testing methodology to monitor the quantity of nanoparticles that get into the environment from nanoparticles containing textile materials. In the study analyzed the method based on the use of conductometer for textiles testing with nano-size metal oxides content to determine the persistence of nanoparticles/ions in the water after textile soaking/washing. Compared results acquired in the experiments with nanofibre webs manufactured by electrospinning from pure polyvinyl alcohol (PVA) and PVA/ZnO composite. The nanofibre webs were soaked in distilled water and obtained samples of water tested with conductometer. The results of the experiments confirm that measurements taken with the conductometer are fairly stable and repeatable; the equipment is suitable for measurements in distilled water for nanoparticles/ions detection. The measurements of the solution’s specific electric conductance allows to pinpoint the nanoparticles/ions concentration, but for this purpose, must be created the database that contains the resources needed for the calculations and methodology for sample preparation.


2018 ◽  
Vol 759 ◽  
pp. 81-85
Author(s):  
Tongsai Jamnongkan ◽  
Supranee Kaewpirom ◽  
Amnuay Wattanakornsiri ◽  
Rattanaphol Mongkholrattanasit

Recently, the composited nanofiber attraction has been growing from researchers across the world due to its exciting opportunities for use in biomedical applications. In this study, we fabricated electrospun fibers from poly (vinyl alcohol) (PVA) composited with Zinc Oxide (ZnO) nanoparticle for potential use in biomedical applications. From the experimental results, there was not any chemical bonding between the ZnO nanoparticles and the PVA molecules. The effect of concentration of ZnO nanoparticles in PVA solution on the diameter of electrospun fibers was found that the diameter of electrospun fibers increased with raising the concentration of suspended ZnO nanoparticles in solution. This is probably because the effect of nanoparticles on the diameter of electrospun fibers was through their effect on the viscosity of solution. In addition, we found that the diameter of electrospun fibers depended on the solution and processing parameters.


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