Characterization of alkali-activated thermally treated incinerator bottom ash

2008 ◽  
Vol 28 (10) ◽  
pp. 1955-1962 ◽  
Author(s):  
X.C. Qiao ◽  
M. Tyrer ◽  
C.S. Poon ◽  
C.R. Cheeseman
Author(s):  
L. L. Sutter ◽  
G. R. Dewey ◽  
J. F. Sandell

Municipal waste combustion typically involves both energy recovery as well as volume reduction of municipal solid waste prior to landfilling. However, due to environmental concerns, municipal waste combustion (MWC) has not been a widely accepted practice. A primary concern is the leaching behavior of MWC ash when it is stored in a landfill. The ash consists of a finely divided fly ash fraction (10% by volume) and a coarser bottom ash (90% by volume). Typically, MWC fly ash fails tests used to evaluate leaching behavior due to high amounts of soluble lead and cadmium species. The focus of this study was to identify specific lead bearing phases in MWC fly ash. Detailed information regarding lead speciation is necessary to completely understand the leaching behavior of MWC ash.


Materials ◽  
2021 ◽  
Vol 14 (11) ◽  
pp. 2911
Author(s):  
Margarida Gonçalves ◽  
Inês Silveirinha Vilarinho ◽  
Marinélia Capela ◽  
Ana Caetano ◽  
Rui Miguel Novais ◽  
...  

Ordinary Portland Cement is the most widely used binder in the construction sector; however, a very high carbon footprint is associated with its production process. Consequently, more sustainable alternative construction materials are being investigated, namely, one-part alkali activated materials (AAMs). In this work, waste-based one-part AAMs binders were developed using only a blast furnace slag, as the solid precursor, and sodium metasilicate, as the solid activator. For the first time, mortars in which the commercial sand was replaced by two exhausted sands from biomass boilers (CA and CT) were developed. Firstly, the characterization of the slag and sands (aggregates) was performed. After, the AAMs fresh and hardened state properties were evaluated, being the characterization complemented by FTIR and microstructural analysis. The binder and the mortars prepared with commercial sand presented high compressive strength values after 28 days of curing-56 MPa and 79 MPa, respectively. The mortars developed with exhausted sands exhibit outstanding compressive strength values, 86 and 70 MPa for CT and CA, respectively, and the other material’s properties were not affected. Consequently, this work proved that high compressive strength waste-based one-part AAMs mortars can be produced and that it is feasible to use another waste as aggregate in the mortar’s formulations: the exhausted sands from biomass boilers.


2021 ◽  
Vol 11 (9) ◽  
pp. 3840 ◽  
Author(s):  
Alex Maldonado-Alameda ◽  
Jofre Mañosa ◽  
Jessica Giro-Paloma ◽  
Joan Formosa ◽  
Josep Maria Chimenos

Alkali-activated binders (AABs) stand out as a promising alternative to replace ordinary Portland cement (OPC) due to the possibility of using by-products and wastes in their manufacturing. This paper assessed the potential of weathered bottom ash (WBA) from waste-to-energy plants and PAVAL® (PV), a secondary aluminium recycling process by-product, as precursors of AABs. WBA and PV were mixed at weight ratios of 98/2, 95/5, and 90/10. A mixture of waterglass (WG) and NaOH at different concentrations (4 and 6 M) was used as the alkaline activator solution. The effects of increasing NaOH concentration and PV content were evaluated. Alkali-activated WBA/PV (AA-WBA/PV) binders were obtained. Selective chemical extractions and physicochemical characterization revealed the formation of C-S-H, C-A-S-H, and (N,C)-A-S-H gels. Increasing the NaOH concentration and PV content increased porosity and reduced compressive strength (25.63 to 12.07 MPa). The leaching potential of As and Sb from AA-WBA/PV exceeded the threshold for acceptance in landfills for non-hazardous waste.


Materials ◽  
2020 ◽  
Vol 13 (4) ◽  
pp. 855
Author(s):  
Qi Sun ◽  
Xueda Wei ◽  
Tianlong Li ◽  
Lu Zhang

A new type of cemented paste backfill (CPB) was prepared by using the bottom ash (BA) from a thermal power plant as an aggregate, alkali-activated slag as a binder, and an air-entraining agent as an admixture. Based on the central composite design (CCD) response surface method, the mix ratio was optimized, and scanning electron microscopy-energy dispersive spectroscopy (SEM-EDS) was performed on the optimal mix ratio. ImageJ software was utilized to determine the porosity of the experimental samples at various curing ages. The results indicate that the optimal mix ratio of the aggregate-binder ratio is 3.28, the alkali dosage is 3%, the solid content is 67.44%, and the air-entraining agent dosage is 0.1%. As the curing age increases, the porosity of CPB gradually decreases. A calcium aluminosilicate hydrate (C-A-S-H) gel is the main hydration product of alkali-activated slag. At the beginning of the hydration reaction, the slag gradually dissolves, and the C-A-S-H product binds the BA together. At 14 d, complete calcium hydroxide (CH) crystals appeared in the hydration product. Finally, the degree of C-A-S-H crystallization increased further to form a dense structure.


2021 ◽  
pp. 106287
Author(s):  
Fanzhen Meng ◽  
Jie Song ◽  
Louis Ngai Yuen Wong ◽  
Zaiquan Wang ◽  
Chuanqing Zhang

Materials ◽  
2021 ◽  
Vol 14 (8) ◽  
pp. 1927
Author(s):  
Lei Jin ◽  
Guodong Huang ◽  
Yongyu Li ◽  
Xingyu Zhang ◽  
Yongsheng Ji ◽  
...  

Setting time and mechanical properties are key metrics needed to assess the properties of municipal solid waste incineration (MSWI) bottom ash alkali-activated samples. This study investigated the solidification law, polymerization, and strength development mechanism in response to NaOH and liquid sodium silicate addition. Scanning electron microscopy and X-ray diffraction were used to identify the formation rules of polymerization products and the mechanism of the underlying polymerization reaction under different excitation conditions. The results identify a strongly alkaline environment as the key factor for the dissolution of active substances as well as for the formation of polymerization products. The self-condensation reaction of liquid sodium silicate in the supersaturated state (caused by the loss of free water) is the major reason for the rapid coagulation of alkali-activated samples. The combination of both NaOH and liquid sodium silicate achieves the optimal effect, because they play a compatible coupling role.


2016 ◽  
Vol 57 (51) ◽  
pp. 24688-24696 ◽  
Author(s):  
Jae-Ho Shim ◽  
Joo-Young Jeong ◽  
Jin-Young Park ◽  
Jin-Suk Ryu ◽  
Joo-Yang Park

2008 ◽  
Vol 396-398 ◽  
pp. 131-134 ◽  
Author(s):  
Ourania Menti Goudouri ◽  
Xanthippi Chatzistavrou ◽  
Eleana Kontonasaki ◽  
Nikolaos Kantiranis ◽  
Lambrini Papadopoulou ◽  
...  

Thermal treatment of bioactive glasses can affect their microstructure and thus their bioactivity. The aim of this study was the characterization of the thermally treated sol-gel-derived bioactive glass 58S at characteristic temperatures and the dependence of its bioactive behavior on the specific thermal treatment. The thermal behavior of the bioactive glass was studied by thermal analysis (TG/DTA). Fourier Transform Infrared Spectroscopy (FTIR) and X-ray Diffractometry (XRD) were used for the characterization of the bioactive glass. The bioactive behavior in Simulated Body Fluid (SBF) was examined by Scanning Electron Microscopy (SEM-EDS) and FTIR. The major crystal phases after thermal treatment were Calcium Silicates, Wollastonite and Pseudowollastonite, while all thermally treated samples developed apatite after 48 hours in SBF. A slight enhancement of bioactivity was observed for the samples heated at the temperature range 910-970oC.


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