Theoretical oxygen potential change of quaternary solid solution, Ay2+Bz3+U1−y−zO2+x, by configurational entropy calculation

2000 ◽  
Vol 282 (2-3) ◽  
pp. 232-238 ◽  
Author(s):  
Takeo Fujino ◽  
Nobuaki Sato
Metals ◽  
2021 ◽  
Vol 11 (3) ◽  
pp. 417
Author(s):  
Wenkui Yang ◽  
Jian Yang ◽  
Yanqiu Shi ◽  
Zhijun Yang ◽  
Fubin Gao ◽  
...  

In this paper, the influence of the Fe2O3 addition amount on the dephosphorization of hot metal at 1623 K with the slag of the low basicity (CaO/SiO2) of about 1.5 was investigated by using high-temperature laboratorial experiments. With increasing the Fe2O3 addition amount from 5 to 30 g, the contents of [C], [Si], [Mn] and [P] in the hot metal at the end of dephosphorization are decreased and the corresponding removal ratios increase. In dephosphorization slags, the phosphorus mainly exists in the form of the nCa2SiO4–Ca3(PO4)2 solid solution in the phosphorus-rich phase and the value of coefficient n decreases from 20 to 1. Furthermore, the oxygen potential and activity at the interface between the slag and hot metal are increased. When the oxygen potential and the oxygen activity at the interface are greater than 0.72 × 10−12 and 7.1 × 10−3, respectively, the dephosphorization ratio begins to increase rapidly. When the Fe2O3 addition amount is increased to 30 g, the ratio of the Fe2O3 addition amount to theoretical calculation consumption is around 175%, and the dephosphorization ratio reaches the highest value of 83.3%.


2020 ◽  
Vol 58 (1) ◽  
pp. 71-83
Author(s):  
Elahe Mansouri Gandomani ◽  
Nematollah Rashidnejad-Omran ◽  
Amir Emamjomeh ◽  
Pietro Vignola ◽  
Tahereh Hashemzadeh

ABSTRACT Turquoise, CuAl6(PO4)4(OH)8·4H2O, belongs to the turquoise group, which consists of turquoise, chalcosiderite, aheylite, faustite, planerite, and UM1981-32-PO:FeH. In order to study turquoise-group solid solutions in samples from the Neyshabour and Meydook mines, 17 samples were selected and investigated using electron probe microanalysis. In addition, their major elements were compared in order to evaluate the feasibility of distinguishing the provenance of Persian turquoises. The electron microprobe data show that the studied samples are not constituted of pure turquoise (or any other pure endmember) and belong, from the chemical point of view, to turquoise-group solid solutions. In a turquoise–planerite–chalcosiderite–unknown mineral quaternary solid solution diagram, the chemical compositions of the analyzed samples lie along the turquoise–planerite line with minor involvement of chalcosiderite and the unknown mineral. Among light blue samples with varying hues and saturations from both studied areas, planerite is more abundant among samples from Meydook compared with samples from Neyshabour. Nevertheless, not all the light blue samples are planerite. This study demonstrates that distinguishing the deposit of origin for isochromatic blue and green turquoises, based on electron probe microanalysis method and constitutive major elements, is not possible.


2014 ◽  
Vol 447 (1-3) ◽  
pp. 115-124 ◽  
Author(s):  
Ségolène Berzati ◽  
Stéphane Vaudez ◽  
Renaud C. Belin ◽  
Jacques Léchelle ◽  
Yves Marc ◽  
...  

2015 ◽  
Vol 51 (71) ◽  
pp. 13678-13681 ◽  
Author(s):  
Tiantian Hong ◽  
Zhifeng Liu ◽  
Weiguo Yan ◽  
Bo Wang ◽  
Xueqi Zhang ◽  
...  

We report a novel quaternary solid solution (Ag–Cu–Sb–S or ACSS) serving as a photo-absorber material in the photoelectrochemical field for the first time, and ZnO/ACSS nanoarrays exhibited a photocurrent density of 4.45 mA cm−2.


2018 ◽  
Vol 1 (6) ◽  
pp. 2455-2460 ◽  
Author(s):  
J. Halim ◽  
J. Palisaitis ◽  
J. Lu ◽  
J. Thörnberg ◽  
E. J. Moon ◽  
...  

2008 ◽  
Vol 1125 ◽  
Author(s):  
Lindsay C. Shuller ◽  
Niravun Pavenayotin ◽  
Rodney C. Ewing ◽  
Udo Becker

ABSTRACTDensity functional theory and Monte(Carlo methods were used to investigate the solid( solution behavior of actinide dioxides (AcO2). The end(members of interest include: ZrO2, ThO2, UO2, NpO2, and PuO2; all have the isometric fluorite structure. Ab initio and subsequent Monte( Carlo simulations are used to calculate the excess enthalpy of mixing (ΔHexcess), excess Gibbs free energy of mixing (ΔGexcess), and excess configurational entropy (ΔSexcess) for the above solid(solution series. From ΔGexcess, phase diagrams are derived and miscibility gaps identified. All of the binaries of the aforementioned end(members were studied; however, this paper focuses on the U1(xZrxO2 and Np1(xUxO2 binaries. About 25 at.% Zr can be in solid solution with the UO2 matrix above 1500 K, while Np is completely miscible in the UO2 matrix. Partial cation ordering was observed at all temperatures for the U1(xZrxO2 binary. The Np1(xUxO2 binary approaches perfect cation disorder at high temperatures (2000 K). The cation ordering scheme is not identified in this study because the number of cation(cation interaction parameters was limited by the single unit cell from the ab initio calculations.


1997 ◽  
Vol 247 ◽  
pp. 116-120 ◽  
Author(s):  
Kwangheon Park ◽  
Myung-Seung Yang ◽  
Hyun-Soo Park

2000 ◽  
Vol 55 (7) ◽  
pp. 627-637 ◽  
Author(s):  
P. Schmidt ◽  
H. Oppermann

Abstract Pseudoternary System Bi2O3/Bi2Se3/Bi2Te3, Phase Diagram, Thermodynamic Data The phase diagram of the pseudoternary system Bi2O3/Bi2Se3/Bi2Te3 is found to include a quaternary solid solution Bi2O2 (TexSe1-x) and ternary, intermetallic mixed crystals Bi2(TexSe1-x)3. Using thermodynamic modeling of the solid solutions it is possible to calcu­ late complex heterogeneous equilibria between all phases of this phase diagram. As a result we can thermodynamically describe the observed phase relations:Bi2(TexSe1-x)3 ⊿H°m(298) = 0; ⊿S°m(298) = R[xlnx + (1-x)ln(1-x)]Bi2O2(TexSe1-x) ⊿H°m(298) = Ω · x(1-x); O⊿S°m(298) = R/4 [xlnx + (1-x)ln(1-x)]Ω = 0,6 kcal/mol


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