scholarly journals Chemical characteristics of hydrologically distinct cryoconite holes in coastal Antarctica

2018 ◽  
Vol 59 (77) ◽  
pp. 69-76 ◽  
Author(s):  
Gautami Samui ◽  
Runa Antony ◽  
Meloth Thamban

ABSTRACTCryoconite holes play a significant role in the nutrient cycling on glaciers and can be regarded as a storehouse of nutrients that are generated through microbial and photochemical activities. In this work, the chemical characteristics of hydrologically connected and isolated cryoconite holes from three geographically distinct regions of coastal Antarctica, namely Larsemann Hills, Amery Ice Shelf and central Dronning Maud Land were studied. Major ions (Na+, K+, Mg2+, Ca2+, Cl−, SO42−and NO3−) and total organic carbon in the hydrologically isolated, closed cryoconite holes showed significantly higher enrichment (6–26 times and 9 times, respectively) over the conservative tracer ion Cl−possibly due to sediment dissolution and microbial synthesis during isolation period. In contrast, depletion of major ions and organic carbon were observed in the open, hydrologically connected holes due to their discharge from the cryoconite holes through interconnected streams. This study suggests that the contribution of cryoconite holes to the nutrient and microbial transport to downstream environments may vary with the extent of hydrological connectivity by virtue of the fact that nutrients and organic carbon which accumulate in the isolated cryoconite holes during isolation could get washed to downstream environments in the event that they get connected through surface or subsurface melt channels.

2018 ◽  
Vol 12 (5) ◽  
pp. 1681-1697 ◽  
Author(s):  
Carmen Paulina Vega ◽  
Elisabeth Isaksson ◽  
Elisabeth Schlosser ◽  
Dmitry Divine ◽  
Tõnu Martma ◽  
...  

Abstract. Major ions were analysed in firn and ice cores located at Fimbul Ice Shelf (FIS), Dronning Maud Land – DML, Antarctica. FIS is the largest ice shelf in the Haakon VII Sea, with an extent of approximately 36 500 km2. Three shallow firn cores (about 20 m deep) were retrieved in different ice rises, Kupol Ciolkovskogo (KC), Kupol Moskovskij (KM), and Blåskimen Island (BI), while a 100 m long core (S100) was drilled near the FIS edge. These sites are distributed over the entire FIS area so that they provide a variety of elevation (50–400 m a.s.l.) and distance (3–42 km) to the sea. Sea-salt species (mainly Na+ and Cl−) generally dominate the precipitation chemistry in the study region. We associate a significant sixfold increase in median sea-salt concentrations, observed in the S100 core after the 1950s, to an enhanced exposure of the S100 site to primary sea-salt aerosol due to a shorter distance from the S100 site to the ice front, and to enhanced sea-salt aerosol production from blowing salty snow over sea ice, most likely related to the calving of Trolltunga occurred during the 1960s. This increase in sea-salt concentrations is synchronous with a shift in non-sea-salt sulfate (nssSO42−) toward negative values, suggesting a possible contribution of fractionated aerosol to the sea-salt load in the S100 core most likely originating from salty snow found on sea ice. In contrast, there is no evidence of a significant contribution of fractionated sea salt to the ice-rises sites, where the signal would be most likely masked by the large inputs of biogenic sulfate estimated for these sites. In summary, these results suggest that the S100 core contains a sea-salt record dominated by the proximity of the site to the ocean, and processes of sea ice formation in the neighbouring waters. In contrast, the ice-rises firn cores register a larger-scale signal of atmospheric flow conditions and a less efficient transport of sea-salt aerosols to these sites. These findings are a contribution to the understanding of the mechanisms behind sea-salt aerosol production, transport and deposition at coastal Antarctic sites, and the improvement of the current Antarctic sea ice reconstructions based on sea-salt chemical proxies obtained from ice cores.


1998 ◽  
Vol 27 ◽  
pp. 275-280 ◽  
Author(s):  
Akira Nishimura ◽  
Toru Nakasone ◽  
Chikara Hiramatsu ◽  
Manabu Tanahashi

Based on sedimenlological and micropaleontological work on three sediment cores collected at about 167° Ε in the western Ross Sea, Antarctica, and accelerator mass spectrometer l4C ages of organic carbon, we have reconstructed environmental changes in the area during the late Quaternary. Since 38 ka BP at latest, this area was a marine environment with low productivity. A grounded ice sheet advanced and loaded the sediments before about 30-25 ka BP. After 25 ka BP, the southernmost site (76°46'S) was covered by floating ice (shelf ice), preventing deposition of coarse terrigenous materials and maintaining a supply of diatom tests and organic carbon until 20 ka BP. The northernmost site (74°33'S) was in a marine environment with a moderate productivity influenced by shelf ice/ice sheet after about 20 ka BP. Since about 10 ka BP, a sedimentary environment similar to the present-day one has prevailed over this area.


2009 ◽  
Vol 55 (192) ◽  
pp. 717-728 ◽  
Author(s):  
Mike Craven ◽  
Ian Allison ◽  
Helen Amanda Fricker ◽  
Roland Warner

AbstractThe Amery Ice Shelf, East Antarctica, undergoes high basal melt rates near the southern limit of its grounding line where 80% of the ice melts within 240 km of becoming afloat. A considerable portion of this later refreezes downstream as marine ice. This produces a marine ice layer up to 200 m thick in the northwest sector of the ice shelf concentrated in a pair of longitudinal bands that extend some 200 km all the way to the calving front. We drilled through the eastern marine ice band at two locations 70 km apart on the same flowline. We determine an average accretion rate of marine ice of 1.1 ± 0.2 m a−1, at a reference density of 920 kg m−3 between borehole sites, and infer a similar average rate of 1.3 ± 0.2 m a−1 upstream. The deeper marine ice was permeable enough that a hydraulic connection was made whilst the drill was still 70–100 m above the ice-shelf base. Below this marine close-off depth, borehole video imagery showed permeable ice with water-filled cavities and individual ice platelets fused together, while the upper marine ice was impermeable with small brine-cell inclusions. We infer that the uppermost portion of the permeable ice becomes impermeable with the passage of time and as more marine ice is accreted on the base of the shelf. We estimate an average closure rate of 0.3 m a−1 between the borehole sites; upstream the average closure rate is faster at 0.9 m a−1. We estimate an average porosity of the total marine ice layer of 14–20%, such that the deeper ice must have even higher values. High permeability implies that sea water can move relatively freely through the material, and we propose that where such marine ice exists this renders deep parts of the ice shelf particularly vulnerable to changes in ocean properties.


2021 ◽  
Author(s):  
Jing Jin ◽  
Antony J. Payne ◽  
William Seviour ◽  
Christopher Bull

<p>The basal melting of the Amery Ice Shelf (AIS) in East Antarctica and its connections with the oceanic circulation are investigated by a regional ocean model. The simulated estimations of net melt rate over AIS from 1976 to 2005 vary from 1 to 2 m/yr depending primarily due to inflow of modified Circumpolar Deep Water (mCDW). Prydz Bay Eastern Costal Current (PBECC) and the eastern branch of Prydz Bay Gyre (PBG) are identified as two main mCDW intrusion pathways. The oceanic heat transport from both PBECC and PBG has significant seasonal variability, which is associated with the Antarctic Slope Current. The onshore heat transport has a long-lasting effect on basal melting. The basal melting is primarily driven by the inflowing water masses though a positive feedback mechanism. The intruding warm water masses destabilize the thermodynamic structure in the sub-ice shelf cavity therefore enhancing the overturning circulations, leading to further melting due to increasing heat transport. However, the inflowing saltier water masses due to sea-ice formation could offset the effect of temperature through stratifying the thermodynamic structure, then suppressing the overturning circulation and reducing the basal melting.</p>


2014 ◽  
Vol 8 (3) ◽  
pp. 1057-1068 ◽  
Author(s):  
Y. Gong ◽  
S. L. Cornford ◽  
A. J. Payne

Abstract. The interaction between the climate system and the large polar ice sheet regions is a key process in global environmental change. We carried out dynamic ice simulations of one of the largest drainage systems in East Antarctica: the Lambert Glacier–Amery Ice Shelf system, with an adaptive mesh ice sheet model. The ice sheet model is driven by surface accumulation and basal melt rates computed by the FESOM (Finite-Element Sea-Ice Ocean Model) ocean model and the RACMO2 (Regional Atmospheric Climate Model) and LMDZ4 (Laboratoire de Météorologie Dynamique Zoom) atmosphere models. The change of ice thickness and velocity in the ice shelf is mainly influenced by the basal melt distribution, but, although the ice shelf thins in most of the simulations, there is little grounding line retreat. We find that the Lambert Glacier grounding line can retreat as much as 40 km if there is sufficient thinning of the ice shelf south of Clemence Massif, but the ocean model does not provide sufficiently high melt rates in that region. Overall, the increased accumulation computed by the atmosphere models outweighs ice stream acceleration so that the net contribution to sea level rise is negative.


2016 ◽  
Author(s):  
Zhaolian Ye ◽  
Jiashu Liu ◽  
Aijun Gu ◽  
Feifei Feng ◽  
Yuhai Liu ◽  
...  

Abstract. Knowledge on aerosol chemistry in densely populated regions is critical for reduction of air pollution, while such studies haven't been conducted in Changzhou, an important manufacturing base and polluted city in the Yangtze River Delta (YRD), China. This work, for the first time, performed a thorough chemical characterization on the fine particular matter (PM2.5) samples, collected during July 2015 to April 2016 across four seasons in Changzhou city. A suite of analytical techniques were employed to characterize organic carbon / elemental carbon (OC / EC), water-soluble organic carbon (WSOC), water-soluble inorganic ions (WSIIs), trace elements, and polycyclic aromatic hydrocarbons (PAHs) in PM2.5; in particular, an Aerodyne soot particle aerosol mass spectrometer (SP-AMS) was deployed to probe the chemical properties of water-soluble organic aerosols (WSOA). The average PM2.5 concentrations were found to be 108.3 μg m−3, and all identified species were able to reconstruct ~ 80 % of the PM2.5 mass. The WSIIs occupied about half of the PM2.5 mass (~ 52.1 %), with SO42−, NO3− and NH4+ as the major ions. On average, nitrate concentrations dominated over sulfate (mass ratio of 1.21), indicating influences from traffic emissions. OC and EC correlated well with each other and the highest OC / EC ratio (5.16) occurred in winter, suggesting complex OC sources likely including both secondarily formed and primarily emitted OA. Concentrations of eight trace elements (Mn, Zn, Al, B, Cr, Cu, Fe, Pb) can contribute up to 6.0 % of PM2.5 during winter. PAHs concentrations were also high in winter (140.25 ng m−3), which were predominated by median/high molecular weight PAHs with 5- and 6-rings. The organic matter including both water-soluble and water-insoluble species occupied ~ 20 % PM2.5 mass. SP-AMS determined that the WSOA had an average atomic oxygen-to-carbon (O / C), hydrogen-to-carbon (H / C), nitrogen-to-carbon (N / C) and organic matter-to-organic carbon (OM / OC) ratios of 0.36, 1.54, 0.11, and 1.74, respectively. Source apportionment of WSOA further identified two secondary OA (SOA) factors (a less oxidized and a more oxidized OA) and two primary OA (POA) factors (a nitrogen enriched hydrocarbon-like traffic OA and a cooking-related OA). On average, the POA contribution overweighed SOA (55 % vs. 45 %), indicating the important role of local anthropogenic emissions to the aerosol pollution in Changzhou. Our measurement also shows the abundance of organic nitrogen species in WSOA, and the source analyses suggest these species likely associated with traffic emissions, which warrants more investigations on PM samples from other locations.


1966 ◽  
Vol 6 (45) ◽  
pp. 335-358 ◽  
Author(s):  
W. Budd

A general survey of the preliminary results of a three-year program of measurements on the Amery Ice Shelf by A.N.A.R.E. are presented, together with theoretical considerations of the velocity and stress distributions and the mass and energy regimes of the ice shelf. In order to explain the observed velocity distribution it has been found necessary to extend Weertman’s theory of ice-shelf creep to an ice shelf bounded at its sides. The resulting theoretical velocity profile applied to the results of the Amery Ice Shelf provides estimates of the average values of the power flow-law parameters for the ice shelf. The energy and mass budget considerations, together with the recorded change in form of the ice front, suggest that the ice-shelf regime is not in a continual state of balance but may fluctuate as the ice shelf changes in form over a period of about forty years.


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