Longitudinal scattering coefficient obtained by hydroacoustic measurement and by conservative tracer

The objective of the present work was to determine the value of the longitudinal dispersion coefficient (DL) of the Chicamtoltina stream (Alta Gracia) by means of two different techniques, in order to compare the values obtained. The first technique consisted of applying a developed formula that includes a detailed description of hydrodynamic parameters obtained by gauging with a hydroacoustic instrument, while the second technique consisted of injecting a conservative tracer, using the same approach as the non-ideal chemical reactor theory of flow with dispersion. This work was carried out at low flow conditions (dry period) and at high flow conditions (wet period). It was found that, either for high flow or low flow, the values of the dispersion coefficient obtained by both techniques have good agreement, fitting better in the dry period than in the wet period. Due to the fact that frequent gauging campaigns are carried out in this stream, it is concluded that with similar flow characteristics and morphology of the section, the gauging data can be used to determine the DL coefficient, in order to incorporate reliable data that can be applied to pollutant transport models.

Nonlinear Sorption of Organic Contaminant during Two-Dimensional Transport in Saturated Sand

Multi-dimensional transport studies are necessary in order to better explain the fate of contaminants in groundwater. In this study, a two-dimensional transport experiment with organic contaminants in saturated sand was conducted to investigate the migration of the organic contaminant plume in multi-dimensional flow conditions. The transport test was conducted using toluene as a model organic contaminant in a saturated sand box under steady flow conditions. The initial plume was generated via injection at a point source. After 24 h, the plume distribution was delineated by interpolating toluene concentrations in the porewater samples. The mass centers of the toluene and the conservative tracer were almost coincident, but the size of the toluene plume was significantly reduced in longitudinal as well as transversal directions. The appropriateness of several types of sorption models were compared to describe the toluene sorption in two-dimensional transport system using numerical modeling. Among the sorption models, the Langmuir model was found to be the most appropriate to describe the sorption of toluene during two-dimensional transport. The results showed that two-dimensional experiments are better than one-dimensional column experiments in identifying the adsorption characteristics that occur during transport in saturated aquifers.

Preselection of a sorption model based on a column test: the algorithm and an example of its application

In order to describe the contamination of saturated porous media, it is necessary to find an appropriate mathematical model that includes processes occurring in aquifers, such as advection, dispersion, diffusion, and various kinds of sorption. The identification of parameters of those processes is possible through laboratory column experiments, which result in records of breakthrough curves for a conservative tracer and a reactive tracer. An algorithm leading to the preliminary selection of the mathematical model that best describes transport processes of the reactive tracer in the experimental column is proposed in this article. A study published previously presented a sensitivity analysis for an arbitrarily adopted variability of the transport parameters. The analysis involved examining changes in the shape of breakthrough curves caused by the alteration of each parameter value. Specially defined indicators called descriptors were proposed to quantitatively describe the breakthrough curves. Then, formulas were proposed to determine the percentage deviations of descriptors of the breakthrough curve obtained for the reactive tracer in relation to the descriptors of the breakthrough curve of the conservative tracer. In the work described in this article, the deviations are analyzed and an algorithm is proposed that allows the preselection of the most suitable sorption model out of the five discussed simple (one-site) and six hybrid (two-site) models. The algorithm can facilitate and accelerate the interpretation of column experiments of contaminant transport in a porous medium. An example is provided to illustrate the usability of the proposed algorithm.

Comparison of Two Ensemble-Kalman Filter Based Methods for Estimating Aquifer Parameters from Real 3-D Hydraulic and Tracer Tomographic Tests

Pumping and tracer tests are site-investigation techniques frequently used to determine hydraulic conductivity. Tomographic test layouts, in which multiple tests with different combinations of injection and observation wells are performed, gain a better insight into spatial variability. While hydraulic tomography has repeatedly been applied in the field, tracer tomography lags behind. In a previous publication, we presented a synthetic study to investigate whether the ensemble Kalman Filter (EnKF) or the Kalman Ensemble Generator (KEG) performs better in inverting hydraulic- and tracer-tomographic data. In this work, we develop an experimental method for solute-tracer tomography using fluorescein as a conservative tracer. We performed hydraulic- and tracer-tomographic tests at the Lauswiesen site in Germany. We analyzed transient drawdown and concentration data with the EnKF and steady-state hydraulic heads and mean tracer arrival times with the KEG, obtaining more stable results with the KEG at lower computational costs. The spatial distribution of the estimated hydraulic conductivity field agreed with earlier descriptions of the aquifer at the site. This study narrows the gap between numerical studies and field applications for aquifer characterization at high resolution, showing the potential of combining ensemble-Kalman filter based methods with data collected from hydraulic and solute-tracer tomographic experiments.

GEOCHEMICAL ASSESSMENT OF TRACE METALS IN SOIL, STREAM WATER AND SELECTED FOOD CROPS AT KIBI GOLDFIELDS ENVIRONMENT, GHANA

This study assesses environmental receptors impacted by alluvial gold mining at Kibi Goldfields Limited in the Eastern region of Ghana to establish trace metals contamination risk. Specific objectives are to determine concentrations of (1) As, Cr, Ni and Pb in soils, drainage and food crops, using X-ray fluorescence, (2) Cl- in drainage using standard methods. Mean concentrations of As, Cr and Ni in soils are higher at impacted sites than control sites; while Pb and As concentrations in drainage exceeds the maximum contamination guideline values in drinking water. Using Cl- as a conservative tracer, As and Pb are adsorbing from water, while Cr and Ni are desorbing into water. In the food crops, bioaccumulation factors of As and Ni are profound at the impacted site than control sites; Except Cr in cocoyam at impacted sites, translocation factors are negligible in the food crops. Cr bioaccumulates in in cocoyam and plantain at the control site, while Ni bioaccumulates in only plantain at the impacted sites. Overall, the metal contamination is of concern in the receptors, except Pd in plants. Results from this study can be used for trace metals risk assessment in the environment.

Reactive Silica Traces Manure Spreading in Alluvial Aquifers Affected by Nitrate Contamination: A Case Study in a High Plain of Northern Italy

In the northern sector of the Po River Plain (Italy), widespread intensive agriculture and animal farming are supported by large amounts of water from Alpine lakes and their emissaries. Flood irrigation and excess fertilization with manure affect both the hydrology and the chemical quality of surface and groundwater, resulting in diffuse nitrogen pollution. However, studies analyzing the mechanisms linking agricultural practices with vertical and horizontal nitrogen paths are scarce in this area. We investigated groundwater quality and quantity in an unconfined, coarse-grained alluvial aquifer adjacent to the Mincio River (a tributary of the Po River), where steep summer gradients of nitrate (NO3−) concentrations are reported. The effects of manure on solutes’ vertical transport during precipitation events in fertilized and in control soils were simulated under laboratory conditions. The results show high SiO2 and NO3− leaching in fertilized soils. Similarly, field data are characterized by high SiO2 and NO3− concentrations, with a comparable spatial distribution but a different temporal evolution, suggesting their common origin but different processes affecting their concentrations in the study area. Our results show that SiO2 can be used as a conservative tracer of manure spreading, as it does not undergo biogeochemical processes that significantly alter its concentrations. On the contrary, nitrate displays large short-term variations related to aquifer recharge (i.e., flood irrigation and precipitation). In fact, aquifer recharge may promote immediate solubilization and stimulate nitrification, resulting in high NO3− concentrations up to 95.9 mg/L, exceeding the Water Framework Directive (WFD) thresholds. When recharge ends, anoxic conditions likely establish in the saturated zone, favoring denitrification and resulting in a steep decrease in NO3− concentrations.

Cs batch sorption and column transport experiments on sand from the Yamin plain, Israel – Experimental results and modelling

<p>The Yanim plain hosts the national Israeli radioactive waste disposal site. The site is located on the Miocene aged Hazeva formation, comprised of loose sand, sandstone and dispersed clay layers. The current research examines the sorption capacity of the local sand to solutions doped with Cs ions. The sand contains ~95% quartz and ~5% of various clays, carbonates, and oxides. Batch sorption experiments were conducted at a liquid to solid ratio of 10. Two end-member solutions were used, fresh (MQ) and concentrated (Na-Nitrate solution). Both solutions were doped with 0.1, 1, 10, 100 and 1000 ppm of Cs (as a nitrate). For the MQ experiments Kd values ranged between ~2 and ~1300, where the highest Kds were registered for the 1 ppm doping level, and the smallest Kds were for the 1000 ppm doping level. For the concentrated solution Kd values ranged between ~0 and ~1.5, where the highest Kds were for the 1 ppm doping level, for all other doping levels Kds were <1. Freundlich and Langmuir isotherm calculations revealed a significantly better correlation on a linearized Freundlich isotherm, indicating a multi-layer and multi-site sorption model, with a similar slope for both solutions, indicating a common sorption mechanism. Column transport experiments (L=25cm, r=2cm, φ=30%, 1PV=180cc) have shown minimal retardation of the Cs in the concentrated solution flow experiments (R= ~2). A second, probably colloid-related peak, showed an early breakthrough with respect to a conservative color tracer.  On the other hand, when MQ was run in the column no breakthrough was observed within 10 column pore volumes. In one fresh experiment a very small colloid related peak was found with breakthrough similar to the conservative tracer. We used the CXTFIT model to calculated the dispersity (λ [L]) and normalized velocity (V) of the measured tracer. For the conservative tracer the values were λ=0.13 cm and V=0.9 cm. For Cs transport in the concentrated solution λ=0.22 cm and V=1.6. Thus, it may be concluded that even in similar doping levels in the same matrix the solution chemistry will play a major role in contaminant retardation. Thus, rain episodes which abruptly change the solution chemistry, can significantly affect solute and colloid mobility.</p>

Understanding the relative importance of vertical and horizontal flow in ice-wedge polygons

Ice-wedge polygons are common Arctic landforms. The future of these landforms in a warming climate depends on the bidirectional feedback between the rate of ice-wedge degradation and changes in hydrological characteristics. This work aims to better understand the relative roles of vertical and horizontal water fluxes in the subsurface of polygonal landscapes, providing new insights and data to test and calibrate hydrological models. Field-scale investigations were conducted at an intensively instrumented location on the Barrow Environmental Observatory (BEO) near Utqiaġvik, AK, USA. Using a conservative tracer, we examined controls of microtopography and the frost table on subsurface flow and transport within a low-centered and a high-centered polygon. Bromide tracer was applied at both polygons in July 2015 and transport was monitored through two thaw seasons. Sampler arrays placed in polygon centers, rims, and troughs were used to monitor tracer concentrations. In both polygons, the tracer first infiltrated vertically until encountering the frost table and was then transported horizontally. Horizontal flow occurred in more locations and at higher velocities in the low-centered polygon than in the high-centered polygon. Preferential flow, influenced by frost table topography, was significant between polygon centers and troughs. Estimates of horizontal hydraulic conductivity were within the range of previous estimates of vertical conductivity, highlighting the importance of horizontal flow in these systems. This work forms a basis for understanding complexity of flow in polygonal landscapes.