Geochemical discrimination of Silurian mudstones according to depositional process and provenance within the Southern Welsh Basin

1992 ◽  
Vol 129 (5) ◽  
pp. 567-572 ◽  
Author(s):  
T. K. Ball ◽  
J. R. Davies ◽  
R. A. Waters ◽  
J. A. Zalasiewicz
Keyword(s):  
Organic Carbon ◽  
Chemical Elements ◽  
Early Diagenesis ◽  
Heavy Minerals ◽  
Sulphide Mineral ◽  
Sulphide Minerals ◽  
Chalcophile Elements ◽  
Depositional Process ◽  
Bottom Waters ◽  
Geochemical Investigation

AbstractA preliminary geochemical investigation of Silurian (Llandovery) basinal mudstones (turbidites and hemipelagites) from the Southern Welsh Basin is described. Turbidite mudstones show higher concentrations of Fe2O3, MgO, TiO2, MnO, LOI, Zn and Zr than laminated hemipelagites. This is consistent with the observed higher concentrations of chlorite and Ti-bearing minerals in turbidite mudstones. Laminated hemipelagites show higher values of REEs (Ce and La), concentrated within authigenic monazites, and Ni, As, Cu and Pb within sulphide minerals (pyrite and galena) reflecting the influence of primary organic carbon levels and anoxic bottom waters on early diagenesis. Deposition of hemipelagites under oxidizing conditions is reflected in lower concentrations of authigenic sulphide mineral hosted elements compared with laminated hemipelagic lithologies. There is a distinct geochemical difference between mudstones of easterly and southerly provenance in the Southern Welsh Basin. This is shown for both turbidites and hemipelagites. The differences are due to the increased input of illite and the chemical elements associated with this mineral (K2O, A12O3, Rb and Ba). Turbidite mudstones sourced from the south show increased levels of heavy minerals, especially those associated with Ti-rich minerals. There is also an increase in elements associated with detrital monazites: Th and Y. The hemipelagites show higher values of REE and chalcophile elements consistent with their more reduced nature.

scholarly journals Spatial variability of biogenic elements and organic carbon content in the tributaries of Lake Baikal

2020 ◽  
Vol 163 ◽  
pp. 05012
Author(s):  
Ekaterina Sharapova ◽  
Ludmila Efimova ◽  
Irina Denisova ◽  
Aida Ermekova ◽  
Mikhail Lychagin ◽  
...  
Keyword(s):  
Organic Carbon ◽  
Spatial Variability ◽  
Lake Baikal ◽  
Aquatic Vegetation ◽  
Chemical Elements ◽  
Organic Phosphorus ◽  
Biogenic Elements ◽  
Organic Carbon Content ◽  
Mineral Phosphorus ◽  
Erosion Processes

The article considers the features of biogenic elements and organic carbon (Corg) content spatial variability in the Lake Baikal tributaries. The role of hydrological conditions and landscape-geochemical features in the chemical elements flow formation is shown. It was found that organic carbon in the river waters is represented mainly by its dissolved form. In the lower reaches of the Selenga, erosion processes and economic activity in the catchment area increase the proportion of suspended forms of organic carbon and mineral phosphorus. In the river delta under the influence of the sedimentation and the intake of organic matter formed during aquatic vegetation decomposition, the content of dissolved Corg increases with a contemporary decrease in its suspended form. As a result of intensification of production and destruction processes in well-heated areas of the delta, a significant decrease in the concentrations of mineral phosphorus and an increase in organic phosphorus occur.

scholarly journals Chemical and physical fractions of soil organic matter under various management regimes in Roraima, Brazil

2017 ◽  
Vol 38 (4Supl1) ◽  
pp. 2419
Author(s):  
Marden Daniel Espinoza Guardiola ◽  
José Frutuoso Vale Júnior ◽  
Edmilson Evangelista da Silva ◽  
Celeste Queiroz Rossi ◽  
Marcos Gervasio Pereira
Keyword(s):  
Organic Matter ◽  
Soil Organic Matter ◽  
Organic Carbon ◽  
Chemical Elements ◽  
The Other ◽  
Management Systems ◽  
Natural Fertility ◽  
Chemical Attributes ◽  
Pasture Area ◽  
Physical And Chemical

The crop-livestock integration (CLI) and crop-livestock-forest integration (CLFI) management systems, have been shown to be viable approaches for increasing carbon sequestration in soils, resulting in the improvement of physical and chemical soil attributes. The objective of this study was to evaluate the chemical attributes and organic matter in soils under Natural Forest (NF) converted to different uses and managed differently: rotational pasture area (PAST), crop-livestock integration (CLI), and crop-livestock-forest integration (CLIF). The research was conducted at the São Paulo farm, in Iracema, located in the south-central region of the state of Roraima, Brazil. The studied soil type was classified as Ultisol. Soil samples were taken by opening ditches and examining layers at 0.1-m depth intervals from surface to 0.60-m depth. Total organic carbon (TOC), chemical and granulometric fractionation of soil organic matter (SOM), oxidizable fractions, and light organic matter in water were analyzed. Our results showed low levels of the analyzed chemical elements, a characteristic of a soil with low natural fertility. This matches conditions inherent in source material, weathered by high rainfall, a warm and humid climate, and flat topographic relief. In the 0-0.1 m layer, the PAST and CLI systems had the highest TOC contents relative to the other systems studied. At other depths, there were no statistical differences among TOC levels. The highest concentration of C in the particulate fraction (POC) was noted in the surface layer in all management systems. The pasture system had the highest concentration POC in the top 0.10 m. Our results also showed that the upper 0.10 m of soil in NF contained the lowest content of organic carbon associated with mineral (MOC) relative to the managed agrosystems. In addition, humin provided the largest contribution to SOM in all evaluated management systems. The crop-livestock integration (CLI) and crop-livestock integration forest (CLIF) systems, emerged as a strong alternative to carbon incorporation and subsequently the improvement of physical and chemical soil attributes. The objective of this work to evaluate the chemical attributes and organic matter in soils under Natural forest (NF) converted into different use and management systems: pasture (PAST), crop-livestock Integration (CLI) and crop-livestock Integration forest (CLIF). The research was conducted at São Paulo farm in Iracema, located in the Center-South region of the State of Roraima, Brazil. The soil studied was classified as Argissolo Amarelo Distrófico. The samples were taken by the opening of trenches in layers of 0-0.10, 0.10- 0.20, 0.20- 0.40, and 0.40-0.60 m depth. Total organic carbon (TOC), chemical and granulometric fractionation of soil organic matter (SOM), oxidizable fractions and organic matter in water were analyzed. The results showed low levels of the analyzed chemical elements which characterizes soils with low natural fertility, which matches the conditions of the source material, high rainfall and regional temperature, as well as the flat local relief. In the 0-0.1 m layer, the PAST and CLI systems had the highest TOC contents when compared to the other systems studied, in the other depths there were no statistical differences between the TOC levels. The highest amount of C in the particulate fraction (COp) was verified in the surface layer in all evaluated management systems. The pasture area was the system with the greatest contribution of COp to the depth of 0-0.0 m. In relation to the carbon content associated with minerals (COam), the results showed that the depth of 0-0.05 m NF area presented the lowest levels when compared to the other systems. Regarding the humic substances, there was a larger contribution of humin in all evaluated systems.

scholarly journals Volgian–Ryazanian ‘hot shales’ of the Bo Member (Farsund Formation) in the Danish Central Graben, North Sea: stratigraphy, facies and geochemistry

2003 ◽  
Vol 1 ◽  
pp. 403-436 ◽  
Author(s):  
Jon R. Ineson ◽  
Jørgen A. Bojesen-Koefoed ◽  
Karen Dybkjær ◽  
Lars H. Nielsen
Keyword(s):  
Organic Carbon ◽  
North Sea ◽  
Upper Jurassic ◽  
Fine Grained ◽  
Carbon Burial ◽  
Anoxic Environments ◽  
Organic Carbon Burial ◽  
Bottom Waters ◽  
Northern North Sea ◽  
Clay Formation

Upper Jurassic – lowermost Cretaceous marine mudstones represent the most significant source of hydrocarbons in the Central and Northern North Sea. Of particular importance in the Danish sector of the Central Graben is a succession of radioactive ‘hot shales’ referred to the Bo Member, in the upper levels of the Farsund Formation (Kimmeridge Clay Formation equivalent). This mudstone-dominated succession is typically 15–30 m thick and has a total organic carbon (TOC) content of 3–8%, though locally exceeding 15%. Although truncated on some structural highs, the Bo Member is a persistent feature of the Danish Central Graben. Lateral variation in both thickness and organic richness is attributed to intrabasinal structural topography and to the location of sediment input centres. Detailed study of the dinoflagellate cyst biostratigraphy of 10 wells indicates that the onset of enhanced organic carbon burial began in the middle–late Middle Volgian in this portion of the Central Graben. The Bo Member, representing the peak of organic carbon enrichment, is largely of Early Ryazanian age. Core data (Jeppe-1, E-1 wells) indicate that the organic-rich shales of the Bo Member are not wholly of hemipelagic origin, as commonly assumed, but may locally be dominated by fine-grained turbidites. Absence of bioturbation, well-preserved lamination and high TOC values suggest that bottom waters were predominantly anoxic although the presence of in-situ benthic bivalves at discrete horizons in the E-1 well suggests that suboxic conditions prevailed on occasion. The Bo Member is a good to very good source rock, showing very high pyrolysis yields (10–100 kg HC/ton rock) and Hydrogen Index (HI) values in the range 200–600. In particular, the Bo Member is characterised by an abundance of 28,30 bisnorhopane (H28), a compound that is indicative of anoxic environments. These new data from the Danish sector of the Central Graben are compatible with the model of Tyson et al. (1979) in which the accumulation of organic-rich mudstones was controlled primarily by bottom-water anoxia beneath a stratified watermass. A number of factors probably contributed to the development of watermass stratification, both intrinsic such as the tectonic morphology of the graben system and extrinsic including climate and sea-level stand.

ORGANOCHLORINE PESTICIDES IN THE COASTAL SEDIMENT OF CITARUM ESTUARY, JAKARTA BAY: THE IMP ORTANT ROLE OF FINE FRACTION OF THE SEDIMENT AS THEIR AGENT TRANSPORT AND PROCESSES OF THEIR EARLY DIAGENESIS

2009 ◽  
Vol 1 (2) ◽  
Author(s):  
T. Pratono ◽  
H. Razak ◽  
I. Gunawan
Keyword(s):  
Organic Carbon ◽  
Total Organic Carbon ◽  
Fine Fraction ◽  
Aerobic Condition ◽  
Early Diagenesis ◽  
Chemical Processes ◽  
Coastal Sediment ◽  
Sediment Samples ◽  
Transport Agent

DDT (1,1,1-Tricholor-2,2-bis(chlorophenil)ethane) and its two derivatives, DDD (1,1-Dicholor-2,2-bis(chlorophenil)ethane) and DDE (1,1-Tricholor-2,2-bis(chlorophenil)-ethylene) were identified in the coastal sediment of Citarum Estuary, Jakarta Bay.Eight stations of the sediment sampling were designed in order to obtain the changing of their concentration sadjacent to the estuary as possible input. Sediment samples were collected in the surface layer within a less than 5 cm depth. In addition to pesticides, texture of sediment and total organic carbon were analyzed. Generally, fine fractions (silt and clay) were predominant grain-size of the sediment ranging 21–35,8 % and 17,6–65,6 %, respectively, while total organic carbon (TOC) ranged from 0,30–1,49 %. Concentrations of p’,p’-DDT varied from 0,621–1,187ppb, concentrations of p’,p’-DDD ranged from 0,176–2,153 ppb and concentrations of p’,p’-DDE were from 0.181–2,254 ppb. The occurrence of total DDT (ΣDDT+DDD+DDE) tended to correlated positively to the fine fraction indicating as transport agent. DDD and DDE as DDT metabolites were formed by biological and chemical processes within predominantly aerobic condition. Keywords: pesticide, DDT, DDD, DDE, sediment, transport agent, Citarum, Jakarta Bay  

Organic carbon isotope ratios and paleoenvironmental implications for Holocene sediments in Lake Melville, southeastern Labrador

1987 ◽  
Vol 24 (10) ◽  
pp. 1994-2003 ◽  
Author(s):  
F. C. Tan ◽  
G. Vilks
Keyword(s):  
Organic Carbon ◽  
Carbon Isotope ◽  
Sediment Cores ◽  
Isotope Ratios ◽  
Carbon Isotope Ratios ◽  
Organic Carbon Isotope ◽  
Glacial Runoff ◽  
Bottom Waters ◽  
History Of ◽  
Marine Influence

Stable isotope 13C/12C ratios of organic carbon in sediments and in particulate organic carbon (POC) change from typically marine values in Groswater Bay to those of terrestrial soils in Goose Bay along an offshore–onshore transect in Hamilton Inlet, southeastern Labrator. The δ13C values in POC collected from close to the water surface change relatively little in Lake Melville, indicating that the integrity of the runoff plume is maintained as it spreads in Lake Melville. The organic carbon isotope ratios in POC collected from the near-bottom waters are similar to those of surficial sediments.Downcore δ13C values reflect paleo-oceanographic changes in Hamilton Inlet during and since deglaciation. In two sediment cores that reached sufficiently old sediments (10 000 years BP), the δ13C values change toward the bottom of the cores to values similar to those of the terrestrial organic carbon in soils, signifying greater terrestrial influence during deglaciation and during the early Holocene.According to the history of postglacial isostatic readjustment of the area, Lake Melville basin was more open to the marine waters during the early postglacial marine incursion because of deeper channels leading into Lake Melville. As a consequence, evidence for greater marine influence during that time should be found in sediment cores. The lack of evidence for the deposition of marine organic carbon brought in by the marine counterflow waters suggests a proximal glaciomarine environment in the Lake Melville basin. Glacial runoff diluted the basin waters, and it is possible that the whole inner Labrador Shelf was relatively fresh during that time.

scholarly journals Molybdenum Isotope Constraints on the Origin of Vanadium Hyper-Enrichments in Ediacaran–Phanerozoic Marine Mudrocks

Minerals ◽  
2020 ◽  
Vol 10 (12) ◽  
pp. 1075
Author(s):  
Alexandra Kunert ◽  
Johnathan Clarke ◽  
Brian Kendall
Keyword(s):  
Organic Carbon ◽  
Water Exchange ◽  
Time Interval ◽  
Sedimentation Rates ◽  
Molybdenum Isotope ◽  
Wide Range ◽  
Bottom Waters ◽  
Organic Carbon Fluxes ◽  
Particulate Fluxes ◽  
Mo Isotopes

Vanadium is an important redox-sensitive trace metal for paleoenvironmental reconstructions. Modern organic-rich sediments persistently contain sediment V enrichments <500 μg/g, but many ancient marine organic-rich mudrocks record enrichments >500 μg/g. Previous studies propose that ancient V enrichments of these magnitudes (“V hyper-enrichments”) were deposited from hyper-sulfidic bottom-waters with higher H2S levels (≥10 mM) than observed in modern euxinic basins. To test the importance of hyper-sulfidic conditions for generating V hyper-enrichments, we compare V concentrations with Mo isotope (δ98Mo) compositions from mudrock samples ranging in age from Ediacaran to Pleistocene. In the modern ocean, sediments deposited from strongly euxinic bottom waters ([H2S]aq > 11 μM) closely record global seawater δ98Mo because conversion of molybdate to tri- and tetra-thiomolybdate is quantitative. By contrast, large Mo isotope fractionations occur during Mo adsorption to Fe-Mn particulates or because of incomplete formation of the most sulfidic thiomolybdates in weakly euxinic settings ([H2S]aq < 11 μM), which both favor removal of lighter-mass Mo isotopes to sediments. We find multiple examples when mudrocks with V hyper-enrichments are associated with a wide range of δ98Mo for a single time interval, including values at or below oceanic input δ98Mo (0.3–0.7‰). This observation suggests significant isotopic offset from reasonable seawater values (typically ≥1.0‰). Thus, we conclude that hyper-sulfidic conditions were not responsible for many V hyper-enrichments in Ediacaran–Phanerozoic mudrocks. Instead, sediment V hyper-enrichments can be explained by high Fe-Mn particulate fluxes to weakly euxinic sediments or by moderately restricted euxinic settings with strongly euxinic ([H2S]aq > 11 μM but not necessarily > 10 mM) or weakly euxinic (with slow clastic sedimentation rates and high organic carbon fluxes) bottom waters where vigorous water exchange provides a continuous V supply from the open ocean.

Description and ecology of a new Middle Ordovician (Llanvirn) odontopleurid trilobite from the Builth Inlier of Mid-Wales, with a review of the genus Meadowtownella

2011 ◽  
Vol 149 (3) ◽  
pp. 397-411 ◽  
Author(s):  
TIM M. CONWAY ◽  
JOSEPH P. BOTTING
Keyword(s):  
Organic Carbon ◽  
Total Organic Carbon ◽  
Water Column ◽  
Environmental Preferences ◽  
Middle Ordovician ◽  
Framboidal Pyrite ◽  
Bottom Waters ◽  
New Diagnosis ◽  
Stratigraphic Range

AbstractA new odontopleurid trilobite, Meadowtownella serrata, is described from a new Llanvirnian (Darriwilian; Didymograptus murchisoni Biozone) locality in the Builth Inlier, Mid-Wales. This unusually spinose species displays a remarkable array of pygidial spines and extends the stratigraphic range of the genus back into the Abereiddian. Benthic faunas are rare in the predominantly ‘anoxic’ D. murchisoni Biozone of the Welsh Basin, and these beds are an unusual habitat for odontopleurids. Environmental analyses (framboidal pyrite and associated total organic carbon) in this study, together with the distribution of benthic faunas (described and figured) in the section, indicate a likely oxic water column and episodically oxic bottom waters. A new diagnosis for Meadowtownella is presented with a review of the genus, as a clarification of previous work. The greater spinosity of earlier members of the lineage may reflect either changing environmental preferences, or the derivation of Meadowtownella from an original more spinose lineage.

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