A review of the palaeoenvironments and biota of the Windyfield chert

2003 ◽  
Vol 94 (4) ◽  
pp. 325-339 ◽  
Author(s):  
Stephen R. Fayers ◽  
Nigel H. Trewin

ABSTRACTThe Windyfield chert site is located 700 m NE of the original Rhynie chert locality at Rhynie, Aberdeenshire, Scotland. Originally identified by concentrations of surface float material, a drilling and trenching programme of the area in 1997 revealed a chert ‘pod’ in situ interbedded with fluvial/lacustrine sandstones and hydrothermally altered shales. Chert morphologies identified from float blocks and trench material range from tabular beds to lenticular pods displaying massive, nodular, laminated and brecciated fabrics, and geyserite splash textures. A suite of floral and faunal associations, when combined with distinctive macro- and microscopic chert textures, has been used to interpret depositional conditions. Palaeoenvironments ranged from terrestrial laminated, brecciated and vegetated sinter sheets to low-temperature pools and marginal aquatic settings. The flora comprises six higher land plant species, nematophytes, charophytes, various fungi and probable cyanobacteria. Arthropods include branchiopod crustaceans, a euthycarcinoid, trigonotarbid arachnids, centipedes, eoarthropleurids and a possible hexapod. The biota of the Windyfield chert is closely comparable to that found in the Rhynie chert. Together, the Windyfield and Rhynie cherts contain the most diverse associated fossil arthropod fauna of terrestrial and freshwater origin from rocks of comparable age anywhere in the world.

Author(s):  
F. H. Louchet ◽  
L. P. Kubin

Experiments have been carried out on the 3 MeV electron microscope in Toulouse. The low temperature straining holder has been previously described Images given by an image intensifier are recorded on magnetic tape.The microtensile niobium samples are cut in a plane with the two operative slip directions [111] and lying in the foil plane. The tensile axis is near [011].Our results concern:- The transition temperature of niobium near 220 K: at this temperature and below an increasing difference appears between the mobilities of the screw and edge portions of dislocations loops. Source operation and interactions between screw dislocations of different slip system have been recorded.


Author(s):  
D. A. Smith

The nucleation and growth processes which lead to the formation of a thin film are particularly amenable to investigation by transmission electron microscopy either in situ or subsequent to deposition. In situ studies have enabled the observation of island nucleation and growth, together with addition of atoms to surface steps. This paper is concerned with post-deposition crystallization of amorphous alloys. It will be argued that the processes occurring during low temperature deposition of one component systems are related but the evidence is mainly indirect. Amorphous films result when the deposition conditions such as low temperature or the presence of impurities (intentional or unintentional) preclude the atomic mobility necessary for crystallization. Representative examples of this behavior are CVD silicon grown below about 670°C, metalloids, such as antimony deposited at room temperature, binary alloys or compounds such as Cu-Ag or Cr O2, respectively. Elemental metals are not stable in the amorphous state.


Catalysts ◽  
2021 ◽  
Vol 11 (5) ◽  
pp. 618
Author(s):  
Huan Du ◽  
Zhitao Han ◽  
Xitian Wu ◽  
Chenglong Li ◽  
Yu Gao ◽  
...  

Er-modified FeMn/TiO2 catalysts were prepared through the wet impregnation method, and their NH3-SCR activities were tested. The results showed that Er modification could obviously promote SO2 resistance of FeMn/TiO2 catalysts at a low temperature. The promoting effect and mechanism were explored in detail using various techniques, such as BET, XRD, H2-TPR, XPS, TG, and in-situ DRIFTS. The characterization results indicated that Er modification on FeMn/TiO2 catalysts could increase the Mn4+ concentration and surface chemisorbed labile oxygen ratio, which was favorable for NO oxidation to NO2, further accelerating low-temperature SCR activity through the “fast SCR” reaction. As fast SCR reaction could accelerate the consumption of adsorbed NH3 species, it would benefit to restrain the competitive adsorption of SO2 and limit the reaction between adsorbed SO2 and NH3 species. XPS results indicated that ammonium sulfates and Mn sulfates formed were found on Er-modified FeMn/TiO2 catalyst surface seemed much less than those on FeMn/TiO2 catalyst surface, suggested that Er modification was helpful for reducing the generation or deposition of sulfate salts on the catalyst surface. According to in-situ DRIFTS the results of, the presence of SO2 in feeding gas imposed a stronger impact on the NO adsorption than NH3 adsorption on Lewis acid sites of Er-modified FeMn/TiO2 catalysts, gradually making NH3-SCR reaction to proceed in E–R mechanism rather than L–H mechanism. DRIFTS.


2021 ◽  
Vol 11 (1) ◽  
Author(s):  
Markéta Mejdová ◽  
Jiří Dušek ◽  
Lenka Foltýnová ◽  
Lenka Macálková ◽  
Hana Čížková

AbstractThe study estimates the parameters of the photosynthesis–irradiance relationship (PN/I) of a sedge-grass marsh (Czech Republic, Europe), represented as an active “green” surface—a hypothetical “big-leaf”. Photosynthetic parameters of the “big-leaf” are based on in situ measurements of the leaf PN/I curves of the dominant plant species. The non-rectangular hyperbola was selected as the best model for fitting the PN/I relationships. The plant species had different parameters of this relationship. The highest light-saturated rate of photosynthesis (Asat) was recorded for Glyceria maxima and Acorus calamus followed by Carex acuta and Phalaris arundinacea. The lowest Asat was recorded for Calamagrostis canescens. The parameters of the PN/I relationship were calculated also for different growth periods. The highest Asat was calculated for the spring period followed by the summer and autumn periods. The effect of the species composition of the local plant community on the photosynthetic parameters of the “big-leaf” was addressed by introducing both real (recorded) and hypothetical species compositions corresponding to “wet” and “dry” hydrological conditions. We can conclude that the species composition (or diversity) is essential for reaching a high Asat of the “big-leaf ”representing the sedge-grass marsh in different growth periods.


1988 ◽  
Vol 20 (3) ◽  
pp. 149-163 ◽  
Author(s):  
Carol Braester ◽  
Rudolf Martinell

Nearly one fifth of all water used in the world is obtained from groundwater. The protection of water has become a high priority goal. During the last decades pollution of water has become more and more severe. Today groundwater is more and more used in comparison with surface water. Recently we have seen accidents, which can pollute nearly all surface water very quickly. Generally the groundwater is easier to protect, as well as cheaper to purify, and above all it is of better quality than the surface water. During the past two decades, alternatives to the traditional method of treating the water in filters have been developed, that is in situ water treatment i.e. the VYREDOX and NITREDOX methods. The most common problem regarding groundwater is too high content of iron and manganese, which can be reduced with the VYREDOX method. In some areas today there are severe problems with pollution by hydrocarbons and nitrate as well, and with modification of the VYREDOX treatment method it is used for hydrocarbon and nitrate treatment as well. The method to reduce the nitrate and nitrite is known as the NITREDOX method.


2021 ◽  
Vol 13 (8) ◽  
pp. 4591
Author(s):  
Shuanglei Huang ◽  
Daishe Wu

The tremendous input of ammonium and rare earth element (REE) ions released by the enormous consumption of (NH4)2SO4 in in situ leaching for ion-adsorption RE mining caused serious ground and surface water contamination. Anaerobic ammonium oxidation (anammox) was a sustainable in situ technology that can reduce this nitrogen pollution. In this research, in situ, semi in situ, and ex situ method of inoculation that included low-concentration (0.02 mg·L−1) and high-concentration (0.10 mg·L−1) lanthanum (La)(III) were adopted to explore effective start-up strategies for starting up anammox reactors seeded with activated sludge and anammox sludge. The reactors were refrigerated for 30 days at 4 °C to investigate the effects of La(III) during a period of low-temperature. The results showed that the in situ and semi in situ enrichment strategies with the addition of La(III) at a low-concentration La(III) addition (0.02 mg·L−1) reduced the length of time required to reactivate the sludge until it reached a state of stable anammox activity and high nitrogen removal efficiency by 60–71 days. The addition of La(III) promoted the formation of sludge floc with a compact structure that enabled it to resist the adverse effects of low temperature and so to maintain a high abundance of AnAOB and microbacterial community diversity of sludge during refrigeration period. The addition of La(III) at a high concentration caused the cellular percentage of AnAOB to decrease from 54.60 ± 6.19% to 17.35 ± 6.69% during the enrichment and reduced nitrogen removal efficiency to an unrecoverable level to post-refrigeration.


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