scholarly journals Numerical Study on the Autoignition of Biogas in Moderate or Intense Low Oxygen Dilution Nonpremixed Combustion Systems

2018 ◽  
Vol 32 (8) ◽  
pp. 8768-8780 ◽  
Author(s):  
Aromal Vasavan ◽  
Philip de Goey ◽  
Jeroen van Oijen
2015 ◽  
Vol 19 (1) ◽  
pp. 21-34 ◽  
Author(s):  
Amir Mardani ◽  
Sadegh Tabejamaat

In this paper, turbulent non-premixed CH4+H2 jet flame issuing into a hot and diluted co-flow air is studied numerically. This flame is under condition of the moderate or intense low-oxygen dilution (MILD) combustion regime and related to published experimental data. The modelling is carried out using the EDC model to describe turbulence-chemistry interaction. The DRM-22 reduced mechanism and the GRI2.11 full mechanism are used to represent the chemical reactions of H2/methane jet flame. The flame structure for various O2 levels and jet Reynolds numbers are investigated. The results show that the flame entrainment increases by a decrease in O2 concentration at air side or jet Reynolds number. Local extinction is seen in the upstream and close to the fuel injection nozzle at the shear layer. It leads to the higher flame entertainment in MILD regime. The turbulence kinetic energy decay at centre line of jet decreases by an increase in O2 concentration at hot Co-flow. Also, increase in jet Reynolds or O2 level increases the mixing rate and rate of reactions.


Author(s):  
Wanhui Zhao ◽  
Lei Zhou ◽  
Wenjin Qin ◽  
Haiqiao Wei

Large eddy simulation of n-heptane spray flames is conducted to investigate the multiple-stage ignition process under extreme (low-temperature, low oxygen, and high-temperature, high-density) conditions. At low oxygen concentrations, the first-stage ignition initiates in the fuel-rich region and then moves to stoichiometric equivalence ratio regions by decreasing the initial temperature. It is also clear that at high temperatures, high oxygen concentrations, or high densities, the reactivity of the mixture is enhanced, where high values of progress variable are observed. Analysis of key intermediate species, including acetylene (C2H2), formaldehyde (CH2O), and hydroxyl (OH) in the mixture fraction and temperature space provides valuable insights into the complex combustion process of the n-heptane spray flames under different initial conditions. The results also suggest that C2H2 appears over a wider range in the mixture fraction space at higher temperature or oxygen concentration condition, implying that it mainly forms at the fuel-rich regions. The initial oxygen concentration of the ambient gas has great influence on the formation and oxidization of C2H2, and the maximum temperature depends on the initial oxygen concentration. OH is mainly formed at the stoichiometric equivalence ratio region, which moves to high-temperature regions very quickly especially at higher oxygen concentrations. Finally, analysis of the premixed and nonpremixed combustion regimes in n-heptane spray flames is also conducted, and both premixed and nonpremixed combustion coexist in spray flames.


Energies ◽  
2020 ◽  
Vol 13 (2) ◽  
pp. 288 ◽  
Author(s):  
Marco-Osvaldo Vigueras-Zuniga ◽  
Maria-Elena Tejeda-del-Cueto ◽  
José-Alejandro Vasquez-Santacruz ◽  
Agustín-Leobardo Herrera-May ◽  
Agustin Valera-Medina

Ammonia, a chemical that contains high hydrogen quantities, has been presented as a candidate for the production of clean power generation and aerospace propulsion. Although ammonia can deliver more hydrogen per unit volume than liquid hydrogen itself, the use of ammonia in combustion systems comes with the detrimental production of nitrogen oxides, which are emissions that have up to 300 times the greenhouse potential of carbon dioxide. This factor, combined with the lower energy density of ammonia, makes new studies crucial to enable the use of the molecule through methods that reduce emissions whilst ensuring that enough power is produced to support high-energy intensive applications. Thus, this paper presents a numerical study based on the use of novel reaction models employed to characterize ammonia combustion systems. The models are used to obtain Reynolds Averaged Navier-Stokes (RANS) simulations via Star-CCM+ with complex chemistry of a 70%–30% (mol) ammonia–hydrogen blend that is currently under investigations elsewhere. A fixed equivalence ratio (1.2), medium swirl (0.8), and confined conditions are employed to determine the flame and species propagation at various operating atmospheres and temperature inlet values. The study is then expanded to high inlet temperatures, high pressures, and high flowrates at different confinement boundary conditions. The results denote how the production of NOx emissions remains stable and under 400 ppm, whilst higher concentrations of both hydrogen and unreacted ammonia are found in the flue gases under high power conditions. The reduction of heat losses (thus higher temperature boundary conditions) has a crucial impact on further destruction of ammonia post-flame, with a raise in hydrogen, water, and nitrogen through the system, thus presenting an opportunity of combustion efficiency improvement of this blend by reducing heat losses. Final discussions are presented as a method to raise power whilst employing ammonia for gas turbine systems.


Author(s):  
Christian H. Beck ◽  
Rainer Koch ◽  
Hans-Jörg Bauer

The influence of incomplete liquid fuel prevaporization on the emissions of nitric oxides in a swirl stabilized model gas turbine combustor is investigated experimentally and numerically. The design of the model combustor enables the variation of the degree of prevaporization. This is achieved by using two liquid fuel injectors. One injector is located far upstream of the combustor and generates a fully prevaporized and premixed air fuel mixture. The second injector is located at the combustor inlet. Consequently, the liquid fuel mass flow split between the two injectors determines the fraction of nonprevaporized fuel present in the reaction zone. The NO∕NO2 measurements were performed with a chemoluminescence analyzer. In accordance to the findings of other researchers, the present experimental study revealed that the influence of prevaporization on nitric oxide emissions is of significance for practical applications. The experimental studies were accompanied by numerical studies of partially prevaporized lean combustion in an abstracted configuration. The purpose of this numerical study is to gain a detailed understanding of the influence of droplet slip on droplet flame position and peak temperature. The droplet slip velocity was found to have a significant impact on the peak temperature of the droplet flame and, therefore, NO formation rates within the droplet flame. The combustion system used for the experimental investigation was characterized regarding droplet slip velocities with an extended laser Doppler anemometry technique. The comparison between numerical and experimental results shows that the droplet slip velocities in the macroscopic reaction zone are within the transition range from an envelope to a wake flame. It is concluded that small-scale mixing effects play a significant role in the formation of nitric oxides in spray combustion systems with incomplete prevaporization.


Author(s):  
K Bhadraiah ◽  
V Raghavan

A numerical investigation of the characteristics of laminar co-flow methane–oxygen diffusion flames has been carried out. The temperature and nitric oxide (NO) distributions in unconfined and partly confined flames are studied in detail. Radial confinements of different diameters and with a length of 150 times the fuel jet diameter have been considered to allow atmospheric nitrogen entry only from the top. A numerical model with a 43-step chemical kinetics mechanism and an optically thin radiation sub-model is employed to carry out simulations. The numerical model has been validated using the experimental data available in the literature. The effect of oxygen flowrate on temperature distributions is studied thoroughly. Confined flame extents are compared with the corresponding unconfined flame extents with the help of OH contours. The effect of confinement diameter on temperature and NO distributions is analysed in detail. At low oxygen flowrates, the extents of confined flames are higher than those of an unconfined flame. At a higher oxygen flowrate, the extent of unconfined flame becomes higher. The confined flames are in general hotter than the unconfined flames. However, at the highest oxygen flowrate and for an intermediate confinement diameter, the flame has the lowest maximum temperature. The amount of NO produced in confined flames is higher than the unconfined flames, due to air entrainment from the top of the confining tube, which increases the residence time for nitrogen transport and its oxidation. At the highest oxygen flowrate considered, numerical predictions show that for a given confinement length, there is an optimum confinement diameter which results in a minimum net production of NO among all the flames.


2016 ◽  
Vol 19 (1) ◽  
Author(s):  
MARIUS-ION STĂNILĂ ◽  
VALENTIN NEDEFF

Flameless combustion, or moderate or intense low oxygen dilution combustion, is an advanced technology that meets all the conditions for being an important actor in the researchers’ efforts to develop low level of polluting emissions and high thermic efficiency combustion systems. Because all the factors that contribute to the emerge of this kind of combustion are not completely understood, there is the suspicion that this type of combustion could be achieved only by overheating the combustion air, which generates the limitation of this technology’s application area. After all the last years conducted research, it came to the conclusion that the requirements for this combustion are less severe than they were believed to be. The recent research is conducted towards the use of this type of combustion for all type of fuels, gas, liquid and solid.


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