Atmospheric Emission Characteristics and Control Policies of Five Precedent-Controlled Toxic Heavy Metals from Anthropogenic Sources in China

To explore the mass concentration levels and health risks of heavy metals in the air in dense traffic environments, PM2.5 samples were collected at three sites in the city of Kunming in April and October 2013, and January and May 2014. Ten heavy metals––V, Cr, Mn, Co, Ni, Cu, Zn, As, Cd and Pb––were analyzed by ICP–MS, and the results showed PM2.5 concentrations significantly higher in spring and winter than in summer and autumn, especially for Zn and Pb. The concentration of heavy metals on working days is significantly higher, indicating that vehicle emissions are significant contributors. An enrichment factor analysis showed that Cr, Mn, Ni, Cu, Zn, As, Cd and Pb come mainly from anthropogenic sources, while V and Co may be both anthropogenic and natural. The correlation and principal component analysis (PCA) showed that Ni, Cu, Zn, Cd and Pb mainly come from vehicles emissions and metallurgical industries; Cr and Mn, from vehicles emissions and road dust; and As, mainly from coal combustion. The health risk assessment shows that the non-carcinogenic risk thresholds of the heavy metals in PM2.5 to children and adult men and women are all less than 1. The carcinogenic risk of Cr for men and women in traffic-intensive areas exceeds 10−4, reaching 1.64 × 10−4 and 1.4 × 10−4, respectively.

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Environmental Chemistry and Ecotoxicology of Hazardous Heavy Metals: Environmental Persistence, Toxicity, and Bioaccumulation

Journal of Chemistry ◽

10.1155/2019/6730305 ◽

2019 ◽

Vol 2019 ◽

pp. 1-14 ◽

Cited By ~ 125

Author(s):

Hazrat Ali ◽

Ezzat Khan ◽

Ikram Ilahi

Keyword(s):

Heavy Metals ◽

Human Health ◽

Environmental Chemistry ◽

Anthropogenic Sources ◽

Health Concern ◽

Food Chains ◽

Toxic Heavy Metals ◽

Environmental Persistence ◽

Metals And Metalloids ◽

Heavy Metals And Metalloids

Heavy metals are well-known environmental pollutants due to their toxicity, persistence in the environment, and bioaccumulative nature. Their natural sources include weathering of metal-bearing rocks and volcanic eruptions, while anthropogenic sources include mining and various industrial and agricultural activities. Mining and industrial processing for extraction of mineral resources and their subsequent applications for industrial, agricultural, and economic development has led to an increase in the mobilization of these elements in the environment and disturbance of their biogeochemical cycles. Contamination of aquatic and terrestrial ecosystems with toxic heavy metals is an environmental problem of public health concern. Being persistent pollutants, heavy metals accumulate in the environment and consequently contaminate the food chains. Accumulation of potentially toxic heavy metals in biota causes a potential health threat to their consumers including humans. This article comprehensively reviews the different aspects of heavy metals as hazardous materials with special focus on their environmental persistence, toxicity for living organisms, and bioaccumulative potential. The bioaccumulation of these elements and its implications for human health are discussed with a special coverage on fish, rice, and tobacco. The article will serve as a valuable educational resource for both undergraduate and graduate students and for researchers in environmental sciences. Environmentally relevant most hazardous heavy metals and metalloids include Cr, Ni, Cu, Zn, Cd, Pb, Hg, and As. The trophic transfer of these elements in aquatic and terrestrial food chains/webs has important implications for wildlife and human health. It is very important to assess and monitor the concentrations of potentially toxic heavy metals and metalloids in different environmental segments and in the resident biota. A comprehensive study of the environmental chemistry and ecotoxicology of hazardous heavy metals and metalloids shows that steps should be taken to minimize the impact of these elements on human health and the environment.

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Quantitative assessment of atmospheric emissions of toxic heavy metals from anthropogenic sources in China: historical trend, spatial distribution, uncertainties, and control policies

Atmospheric Chemistry and Physics ◽

10.5194/acp-15-10127-2015 ◽

2015 ◽

Vol 15 (17) ◽

pp. 10127-10147 ◽

Cited By ~ 149

Author(s):

H. Z. Tian ◽

C. Y. Zhu ◽

J. J. Gao ◽

K. Cheng ◽

J. M. Hao ◽

...

Keyword(s):

Heavy Metals ◽

Nonferrous Metal ◽

Anthropogenic Activities ◽

Ferrous Metal ◽

Anthropogenic Sources ◽

Atmospheric Emissions ◽

Toxic Heavy Metals ◽

Average Growth ◽

Industrial Boilers ◽

Cu And Zn

Abstract. Anthropogenic atmospheric emissions of typical toxic heavy metals have caused worldwide concern due to their adverse effects on human health and the ecosystem. By determining the best available representation of time-varying emission factors with S-shape curves, we establish the multiyear comprehensive atmospheric emission inventories of 12 typical toxic heavy metals (Hg, As, Se, Pb, Cd, Cr, Ni, Sb, Mn, Co, Cu, and Zn) from primary anthropogenic activities in China for the period of 1949–2012 for the first time. Further, we allocate the annual emissions of these heavy metals in 2010 at a high spatial resolution of 0.5° × 0.5° grid with ArcGIS methodology and surrogate indexes, such as regional population and gross domestic product (GDP). Our results show that the historical emissions of Hg, As, Se, Cd, Cr, Ni, Sb, Mn, Co, Cu, and Zn, during the period of 1949–2012, increased by about 22–128 times at an annual average growth rate of 5.1–8.0 %, reaching about 526.9–22 319.6 t in 2012. Nonferrous metal smelting, coal combustion of industrial boilers, brake and tyre wear, and ferrous metal smelting represent the dominant sources of heavy metal emissions. In terms of spatial variation, the majority of emissions are concentrated in relatively developed regions, especially for the northern, eastern, and southern coastal regions. In addition, because of the flourishing nonferrous metal smelting industry, several southwestern and central-southern provinces play a prominent role in some specific toxic heavy metals emissions, like Hg in Guizhou and As in Yunnan. Finally, integrated countermeasures are proposed to minimize the final toxic heavy metals discharge on account of the current and future demand of energy-saving and pollution reduction in China.

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Quantitative assessment of atmospheric emissions of toxic heavy metals from anthropogenic sources in China: historical trend, spatial variation distribution, uncertainties and control policies

Atmospheric Chemistry and Physics Discussions ◽

10.5194/acpd-15-12107-2015 ◽

2015 ◽

Vol 15 (8) ◽

pp. 12107-12166 ◽

Cited By ~ 28

Author(s):

H. Z. Tian ◽

C. Y. Zhu ◽

J. J. Gao ◽

K. Cheng ◽

J. M. Hao ◽

...

Keyword(s):

Heavy Metals ◽

Spatial Variation ◽

Anthropogenic Activities ◽

Anthropogenic Sources ◽

Atmospheric Emissions ◽

Toxic Heavy Metals ◽

Average Growth ◽

Regional Population ◽

Industrial Boilers ◽

Cu And Zn

Abstract. Anthropogenic atmospheric emissions of typical toxic heavy metals have received worldwide concerns due to their adverse effects on human health and the ecosystem. By determining the best available representation of time-varying emission factors with S-shape curves, we established the multiyear comprehensive atmospheric emission inventories of 12 typical toxic heavy metals (Hg, As, Se, Pb, Cd, Cr, Ni, Sb, Mn, Co, Cu and Zn) from primary anthropogenic activities in China for the period of 1949–2012 for the first time. Further, we allocated the annual emissions of these heavy metals in 2010 at a high spatial resolution of 0.5° × 0.5° grid with ArcGIS methodology and surrogate indexes, such as regional population and gross domestic product (GDP). Our results show that the historical emissions of Hg, As, Se, Cd, Cr, Ni, Sb, Mn, Co, Cu and Zn during the period of 1949–2012, have been increased by about 22–128 times at an annual average growth rate of 5.1–8.0%, amounting to about 79 570 t in 2012. Nonferrous metal smelting, coal combustion of industrial boilers, brake and tyre wear, and ferrous metals smelting represent the dominant sources for Hg / Cd, As / Se / Pb / Cr / Ni / Mn / Co, Sb / Cu, and Zn, respectively. In terms of spatial variation, the majority of emissions were concentrated in relatively developed regions, especially for the northern, eastern and southern coastal regions. In addition, because of the flourishing nonferrous metals smelting industry, several southwestern and central-southern provinces play a prominent role in some specific toxic heavy metals emissions, like Hg in Guizhou and As in Yunnan. Finally, integrated countermeasures are proposed to minimize the final toxic heavy metals discharge on accounting of the current and future demand of energy-saving and pollution reduction in China.

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Environmental Impact Assessment of Vehicular Traffic along Major Roads in Delta State of Nigeria, Using Contamination and Enrichment Factors

Archives of Current Research International ◽

10.9734/acri/2021/v21i130227 ◽

2021 ◽

pp. 54-64

Author(s):

H. O. Juwah ◽

O. Z. Tachere

Keyword(s):

Heavy Metals ◽

Control Point ◽

Contamination Factor ◽

Enrichment Factors ◽

Anthropogenic Sources ◽

Sampling Location ◽

Vehicular Traffic ◽

Toxic Heavy Metals ◽

Guinea Grass ◽

The Impact

This research was carried out to evaluate the impact of vehicular traffic, on the soil and grasses growing along major roadsides in Delta state, Nigeria. Soil and Guinea grass samples were collected from three major roads, and a control point in Delta State. The collected samples (plant and soil) were digested according to standard procedures, and their heavy metals (Fe, Cu, Pb and Ni) concentrations were analyzed by using the Atomic Absorption Spectrophotometry. Results obtained indicated that the soil and grass heavy metals concentrations were significantly (p ≤0.05) higher than the control point, and varied across the sampled locations. It was observed from the resulted that, there was heavy metals accumulation in the soil and plants growing along the roadsides. Irrespective of the sampling location, the concentrations of the heavy metals followed this trend Fe ˃Pb ˃Ni ˃ Cu. As revealed by the results, at Ughelli, the contamination factor was in this order Ni > Cu >Fe >Pb; then at Ozoro road, the contamination factor ranking was Ni >Pb >Fe Cu; while at Irri road, the contamination ranked Ni > Cu > Pb > Fe. This showed that Ni had the highest contamination factor, regardless of the road location. As portrayed by the results, the heavy metals enrichment factors were greater than 1. The results revealed that the heavy metals enrichment factors followed this ranking Ni > Cu > Pb in all the locations sampled. These results indicated that the roadsides soil and Guinea grass received their pollution from anthropogenic sources, and vehicular emissions in particular. The results obtained from this study revealed the urgency of the government to decongest vehicular traffic, to prevent accumulation of toxic heavy metals in the ecosystems.

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Assessments of Water-Soluble Inorganic Ions and Heavy Metals in Atmospheric Dustfall and Topsoil in Lanzhou, China

International Journal of Environmental Research and Public Health ◽

10.3390/ijerph17082970 ◽

2020 ◽

Vol 17 (8) ◽

pp. 2970

Author(s):

Yingquan Li ◽

Baowei Zhao ◽

Kaixiang Duan ◽

Juexian Cai ◽

Wujiang Niu ◽

...

Keyword(s):

Heavy Metals ◽

Pollution Prevention ◽

Inorganic Ions ◽

Water Soluble ◽

Anthropogenic Sources ◽

Soil System ◽

Lanzhou City ◽

Atmospheric Particle ◽

Water Soluble Inorganic Ions ◽

And Control

The chemical features of atmospheric dustfall and topsoil in the same region could reflect the processes of the migration, transport, and diffusion of pollutants in the atmospheric-soil system. Samples of atmospheric dustfall and topsoil were collected in Lanzhou City. The contents and correlation of water-soluble inorganic ions (WSIIs) and heavy metals in dustfall and topsoil were analyzed, the sources of heavy metals and WSIIs in dustfall were distinguished, and the potential ecological risks of heavy metals in dustfall and topsoil were evaluated. The highest contents of WSIIs are SO42− (18,594 mg·kg−1) and Ca2+ (10,070 mg·kg−1) in dustfall, and for SO42− (8271 mg·kg−1) and Na+ (1994 mg·kg−1) in topsoil. The concentrations of heavy metals (Pb, Cu, Zn, Cr, Cd, and Ni) in dustfall are considerably higher than those in topsoil. Combustion of biomass and coal, transportation and industrial activities are the major anthropogenic sources of WSIIs and heavy metals in Lanzhou. Pollution of heavy metals except Cr and Ni in dustfall, and Cu, Cr, and Ni in topsoil was up to different degrees, where the pollution of Cd was serious. The risk of Cd in dustfall is high while moderate in topsoil. This research could offer a reference for the atmospheric particle pollution prevention and control in Lanzhou.

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ASSESSMENT OF HEAVY METAL CONCENTRATION IN COCONUT WATER

Recent Research in Science and Technology ◽

10.25081/rrst.2018.10.3370 ◽

1970 ◽

pp. 07-10

Author(s):

MdDidarul Islam, Ashiqur Rahaman, Aboni Afrose

Keyword(s):

Heavy Metals ◽

Heavy Metal ◽

Heavy Metal Concentration ◽

Coconut Water ◽

Toxic Heavy Metals ◽

High Concentration ◽

Toxic Heavy Metal ◽

Low Concentration ◽

Wet Ashing ◽

Aas Method

This study was based on determining concentration of essential and toxic heavy metal in coconut water available at a local Hazaribagh area in Dhaka, Bangladesh. All essential minerals, if present in the drinking water at high concentration or very low concentration, it has negative actions. In this study, fifteen samples and eight heavy metals were analyzed by Atomic Absorption Spectroscopy (AAS) method which was followed by wet ashing digestion method. The concentration obtained in mg/l were in the range of 0.3 to 1.5, 7.77 to 21.2, 0 to 0.71, 0 to 0.9, 0 to 0.2, 0.9 to 17.3, 0.1 to 0.9, 0 to 0.9 and 0 to 0.7 for Fe, Ni, Cu, Cd, Cr, Zn, Pb and Se respectively. From this data it was concluded that any toxic heavy metals like Cd, Cr, Pb and Ni exceed their toxicity level and some essential nutrients were in low concentration in those samples.

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Assessment of micro and macro nutrients in poultry feeds available in Dhaka city, Bangladesh.

Journal of Scientific Agriculture ◽

10.25081/jsa.2017.v1.825 ◽

2017 ◽

Vol 1 ◽

pp. 264

Author(s):

Md Didarul Islam ◽

Ashiqur Rahaman ◽

Fahmida Jannat

Keyword(s):

Heavy Metals ◽

Adverse Effect ◽

The Other ◽

Nutrient Level ◽

Dhaka City ◽

Toxic Heavy Metals ◽

High Concentration ◽

Low Concentration ◽

Feed Formulation ◽

Macro Nutrients

This study was based on to determine the concentration of macro and micro nutrients as well as toxic and nontoxic heavy metals present in the chicken feed available in Dhaka city of Bangladesh. All macro nutrients, if present in the feed at high concentration have some adverse effect, at the same time if this nutrient present in the feed at low concentration this have some adverse effect too. So that this nutrient level should be maintained at a marginal level. On the other side toxic heavy metals if present in the feed at very low concentration those can contaminate the total environment of the ecosystem. In this study six brand samples (starter, grower, finisher and layer) which was collected from different renowned chicken feed formulation industry in Bangladesh. Those samples were prepared for analysis by wet ashing and then metals were determined by Atomic Absorption Spectroscopy. It was found that 27.7 to 68.4, 57.3 to 121.9, 0.21 to 4.1, 0.32 to 2.1, 0.11 to 1.58, 0.28 to 2.11 and 0.28 to 1.78 for zinc, iron, copper, mercury, cadmium, nickel and cobalt respectively. It was found that essential macro and micro nutrients were present in the feed in low concentration on the other side mercury was present in high concentration in the feed samples.

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