HAZARDOUS SUBSTANCES IN ATMOSPHERIC DISCHARGES OF PIPE FURNACES REFINING PLANTS

The article deals with atmospheric emissions from fuel combustion in tubular furnaces of oil refineries

Review of Top-Down Method to Determine Atmospheric Emissions in Port. Case of Study: Port of Veracruz, Mexico

Indicators of environmental policies in force in Mexico, fossil fuels will continue to be used in industrial sectors, especially marine fuels, such as marine diesel oil, in port systems for some time. Considering this, we have evaluated several methods corresponding to a top-down system for determining fuel consumption and sulfur dioxide atmospheric emissions for the port of Veracruz in 2020 by type of ship on a daily resolution, considering a sulfur content of 0.5% mass by mass in marine fuel. After analyzing seven methods for determining sulfur dioxide atmospheric emission levels, Goldsworthy’s method was found to be the best option to characterize this port. The port system has two maritime zones, one of which is in expansion, which represented 55.66% of fuel consumption and 23.05% of atmospheric emissions according to the typology of vessels. We found that higher fuel consumption corresponded to container vessels, and tanker vessels represented higher atmospheric emission levels in the berthing position. The main differences that we found in the analysis of the seven methods of the top-down system corresponded to the load factor parameter, main and auxiliary engine power, and estimation of fuel consumption by type of vessel.

Eddy Covariance Measurements Highlight Sources of Nitrogen Oxide Emissions Missing from Inventories for Central London

During March–June 2017 emissions of nitrogen oxides were measured via eddy covariance at the British Telecom Tower in central London, UK. Through the use of a footprint model the expected emissions were simulated from the spatially resolved National Atmospheric Emissions Inventory for 2017, and compared with the measured emissions. These simulated emissions were shown to underestimate measured emissions during the day time by a factor of 1.48, but they agreed well overnight. Furthermore, underestimations were spatially mapped and the areas around the measurement site responsible for differences in measured and simulated emissions inferred. It was observed that areas of higher traffic, such as major roads near national rail stations, showed the greatest underestimation by the simulated emissions. These discrepancies are partially attributed to a combination of the inventory not fully capturing traffic conditions in central London, and both spatial and temporal resolution of the inventory not fully describing the high heterogeneity of the urban centre. Understanding of this underestimation may further improved with longer measurement time series ,to better understand temporal variation, and improved temporal scaling factors, to better simulate sub-annual emissions.

Long-term atmospheric emissions for the Coal Oil Point natural marine hydrocarbon seep field, offshore California

In this study, we present a novel approach for assessing nearshore seepage atmospheric emissions through modeling of air quality station data, specifically a Gaussian plume inversion model. A total of 3 decades of air quality station meteorology and total hydrocarbon concentration, THC, data were analyzed to study emissions from the Coal Oil Point marine seep field offshore California. THC in the seep field directions was significantly elevated and Gaussian with respect to wind direction, θ. An inversion model of the seep field, θ-resolved anomaly, THC′(θ)-derived atmospheric emissions is given. The model inversion is for the far field, which was satisfied by gridding the sonar seepage and treating each grid cell as a separate Gaussian plume. This assumption was validated by offshore in situ data that showed major seep area plumes were Gaussian. Plume total carbon, TC (TC = THC + carbon dioxide, CO2, + carbon monoxide), 18 % was CO2 and 82 % was THC; 85 % of THC was CH4. These compositions were similar to the seabed composition, demonstrating efficient vertical plume transport of dissolved seep gases. Air samples also measured atmospheric alkane plume composition. The inversion model used observed winds and derived the 3-decade-average (1990–2021) field-wide atmospheric emissions of 83 400 ± 12 000 m3 THC d−1 (27 Gg THC yr−1 based on 19.6 g mol−1 for THC). Based on a 50 : 50 air-to-seawater partitioning, this implies seabed emissions of 167 000 m3 THC d−1. Based on atmospheric plume composition, C1–C6 alkane emissions were 19, 1.3, 2.5, 2.2, 1.1, and 0.15 Gg yr−1, respectively. The spatially averaged CH4 emissions over the ∼ 6.3 km2 of 25 × 25 m2 bins with sonar values above noise were 5.7 µM m−2 s−1. The approach can be extended to derive emissions from other dispersed sources such as landfills, industrial sites, or terrestrial seepage if source locations are constrained spatially.

Atmospheric emissions of volatile organic compounds from a mine soil treated with sewage sludge and tomato plants (Lycopersicum esculentum L.)

A laboratory study was carried out to investigate the emissions of volatile organic compounds (VOCs) from a mining soil amended with sewage sludge and irrigated with wastewater in comparison to the non-amended soil, with or without tomato plants (Lycopersicum esculentum L.). The study detected a total of nine VOCs emitted from the polluted soil: benzene, toluene, ethylbenzene, p-xylene, m-xylene, o-xylene, styrene, benzene-1,2,4-trimethyl and tetrachloroethylene, among which the most abundant were toluene, m-xylene and styrene (82.2, 4.1 and 3% respectively). The results showed that soil amended with sewage sludge reduced the emission of VOCs (styrene in pots without plants and benzene and xylenes in pots with plants). On the other hand, tomato plants contributed to increase significantly the emissions of all VOCs except styrene in both amended and non-amended soils.

Atmospheric Emissions in Ports Due to Maritime Traffic in Mexico

Atmospheric emissions from vessels at 38 Pacific and Gulf-Caribbean Mexican ports were determined for nitrogen oxides, sulfur dioxide, particulates, carbon monoxide, non-methane volatile organic compounds, and carbon dioxide. The emissions have been estimated using a bottom-up methodology in the maneuver and hoteling phases, by vessel type, from 2005 to 2020. Maritime traffic in Mexico’s Pacific zone contributes approximately with 60% of the country’s total ship emissions, with the remaining 40% in Gulf-Caribbean ports. The highest atmospheric emissions were found at the Manzanillo and Lázaro Cárdenas ports on the Pacific coast, as well as the Altamira and Veracruz ports on the Gulf-Caribbean coast. The contribution of the atmospheric emissions by vessel type at Pacific ports was Container 67%, Bulk Carrier 32%, Tanker 0.8%, and RoRo 0.4%. For Gulf-Caribbean ports it was Container 76%, Bulk Carrier 19%, Tanker 3%, and RoRo 2%. This study incorporates the International Maritime Organization implementations on reductions of sulfur content in marine fuel, from 4.5% mass by mass from 2005 to 2011, to 3.5% from 2012 to 2019, to 0.5% beginning in 2020. Overall, sulfur dioxide emissions were reduced by 89%.

Analysis of the Efficiency of a Batch Boiler and Emissions of Harmful Substances during Combustion of Various Types of Wood

In the paper, the authors focused on the environmental problems of pollution emissions caused by households using batch boilers fired with solid fuels. The aim of this study is to analyse the course of changes in the actual efficiency and emission of a solid fuel updraft boiler, the most popular type of batch boilers used in Poland in recent years. The subject of analysis is the comparison of the values of atmospheric emissions of harmful substances depending on the type of wood burnt in the boiler. The investigation comprises the combustion characteristics of three types of woody biomass (in billets), i.e., pine, birch, and beech. Based on the carried out research of all billets, the beech has the lowest values of CO (3497 mg/m3) and particulate matter (116.9 mg/m3). Despite this, obtained results exceed the current permissible limits based on the standard PN:EN 303-5:2012. The highest efficiency (54.13%) was obtained for birch billets, the lowest for pine (45.13%). The research has shown that the real heating efficiency during the combustion of wood, irrespective of the type of wood being burnt, is low. To summarise, the outdated installations contribute to air pollution several times higher, which indicates the need to replace inefficient heat sources using solid fuels with modern equipment that meets the most stringent standards.