Size Distributions of Water-Soluble Inorganic Ions in Atmospheric Aerosols During the Meiyu Period in the Yangtze River Delta, China

In order to investigate the chemical composition distributions and pollution characteristics of Total water-soluble inorganic ions (TWSII) in the rain period (Meiyu) in the East Asian summer monsoon season, including the impact of Meiyu on air pollution in the Yangtze River Delta, East China, the gaseous pollutant concentrations, the 9 sizes segregated particles, and water-soluble inorganic ions of aerosols were measured on the north shore of Taihu Lake from June 4 to July 5, 2016. Results show that the mass concentrations of atmospheric particulate matters (PM2.5 and PM10) and main gaseous pollutants (SO2, NO2, CO, and O3) decrease during the Meiyu period, with the largest decline in PM10 and the smallest in CO. TWSII in atmospheric particles are mainly concentrated in fine particles during the Meiyu period. The values of ρ (TWSII) for PM1.1, PM1.1–2.1, and PM2.1–10 before the Meiyu onset are generally greater than those during the Meiyu period. During the first pollution process, the ρ(TWSII) for PM1.1 and PM1.1–2.1 first increase to the peak values, and then decrease during the moderate rainfall period, when the ρ(TWSII) in PM2.1–10 increase to its maximum before the Meiyu onset. The mass concentrations for anions, cations, and total ions at different particle-size sections all exhibit bimodal distributions before and after the Meiyu onset. The mass concentration peaks at a particle size of 1.1–2.1 μm for fine particles, while at 5.8–9.0 μm (before the Meiyu onset) and 9.0–10.0 μm (during the Meiyu period) for coarse particles, respectively. The peak particle size for mass concentration of coarse particles moves toward larger sizes during the Meiyu period. The mass concentrations of SO42− at different particle-size sections show a bimodal distribution before the Meiyu onset and a multi-modal distribution during the Meiyu period. The mass concentrations of NO3− at different particle-size sections show a bimodal distribution before the Meiyu onset and a unimodal distribution during the Meiyu period. The mass concentrations of NH4+ at different particle-size sections present a bimodal distribution before and after the Meiyu onset, with the particle-size for peak concentrations distributing in 1.1–2.1 and 5.8–9.0 μm before the Meiyu onset, and 9.0–10.0 μm during the Meiyu period. The mean value of nitrogen oxidation ratio (NOR) is higher before the Meiyu onset than after, indicating that the secondary conversion of NO2 before the Meiyu onset is enhanced. The sulfur oxidation ratio (SOR) values are greater than NOR values, but the concentrations of NO2 in the same period during the Meiyu period are higher than those of SO2, which indicates that the secondary conversion of SO2 during the Meiyu period on the north bank of Taihu Lake is stronger than that of NO2. During the whole observation, the contribution of stationary sources mainly contributed to the atmospheric particulate matters during the Meiyu period. The contributions of vehicle exhaust and coal combustion to fine particles are more obviously affected by the changes in meteorological conditions during the Meiyu period, and the vehicle emissions contribute more to PM1.1–2.1 than to PM1.1.

Dominant Contributions of Secondary Aerosols and Vehicle Emissions to Water-Soluble Inorganic Ions of PM2.5 in an Urban Site in the Metropolitan Hangzhou, China

Water soluble inorganic ions (WSIIs) are important components in PM2.5 and could strongly affect the acidity and hygroscopicity of PM2.5. In order to achieve the seasonal characteristics and determine the potential sources of WSIIs in PM2.5 in Hangzhou, online systems were used to measure hourly mass concentrations of WSIIs (SO42–, NO3–, NH4+, Cl–, Na+, K+, Ca2+ and Mg2+) as well as PM2.5, NO2 and SO2 at an urban site for one month each season (May, August, October, December) in 2017. Results showed that the hourly mass concentrations of PM2.5 during the whole campaign varied from 1 to 292 μg·m−3 with the mean of 56.03 μg·m−3. The mean mass concentration of WSIIs was 26.49 ± 20.78 μg·m−3, which contributed 48.28% to averaged PM2.5 mass. SNA (SO42–, NO3– and NH4+) were the most abundant ions in PM2.5 and on average, they comprised 41.57% of PM2.5 mass. PM2.5, NO2, SO2 and WSIIs showed higher mass concentrations in December, possibly due to higher energy consumption emissions, unfavorable meteorological factors (e.g., lower wind speed and temperature) and regional transport. Results from PCA models showed that secondary aerosols and vehicle emissions were the dominant sources of WSIIs in the observations. Our findings highlight the importance of stronger controls on precursor (e.g., SO2 and NO2) emissions in Hangzhou, and show that industrial areas should be controlled at local and regional scales in the future.

Inter-comparison of online and offline methods for measuring ambient heavy and trace elements and water-soluble inorganic ions (NO₃⁻, SO₄²⁻, NH₄⁺ and Cl⁻) in PM_2.5 over a heavily polluted megacity, Delhi

Characterizing the chemical composition of ambient particulate matter (PM) provides valuable information on the concentration of secondary species, toxic metals and assists in the validation of abatement techniques. The chemical components of PM can be measured by sampling on filters and analysing them in the laboratory or using real-time measurements of the species. It is important for the accuracy of the PM monitoring networks that measurements from the offline and online methods are comparable and biases are known. The concentrations of water-soluble inorganic ions (NO3−, SO42−, NH4+ and Cl−) in PM2.5 measured from the 24 hrs filter samples using ion chromatography (IC) were compared with the online measurements of inorganics from aerosol mass spectrometer (AMS) with a frequency of 2 mins. Also, the concentrations of heavy and trace elements determined from the 24 hrs filter samples using inductively coupled plasma mass spectroscopy (ICP-MS) were compared with the online measurements of half-hourly heavy and trace metal’s concentrations from Xact 625i ambient metal mass monitor. The comparison was performed over two seasons (summer and winter) characterized by their different metrological conditions at IITD and during winter at IITMD, two sites located in Delhi, NCR, India, one of the heavily polluted urban areas in the world. Collocated deployments of the instruments helped to quantify the differences between online and offline measurements and evaluate the possible reasons for positive and negative biases. The slopes for SO42− and NH4+ were closer to 1:1 line during winter and decreased during summer at both sites. The higher concentrations on the filters were due to the formation of particulate (NH4)2SO4. Filter-based NO3− measurements were lower than online NO3− during summer at IITD and winter at IITMD due to the volatile nature of NO3− from the filter substrate. Offline measured Cl− was consistently higher than AMS derived Cl− during summer and winter at both sites. Based on their comparability characteristics, elements were grouped under 3 categories. The online element data were highly correlated (R2 > 0.8) with the offline measurements for Al, K, Ca, Ti, Zn, Mn, Fe, Ba, and Pb during summer at IITD and winter at both the sites. The higher correlation coefficient demonstrated the precision of the measurements of these elements by both Xact 625i and ICP-MS. Some of these elements showed higher Xact 625i elemental concentrations than ICP-MS measurements by an average of 10–40 % depending on the season and site. The reasons for the differences in the concentration of the elements could be the distance between two inlets for the two methods, line interference between two elements in Xact measurements, sampling strategy, variable concentrations of elements in blank filters and digestion protocol for ICP measurements.

Characteristics of Aerosol and Effect of Aerosol-Radiation-Feedback in Handan, an Industrialized and Polluted City in China in Haze Episodes

In order to investigate the chemical characteristics of aerosol pollution including PM1 and PM2.5 in Handan, the offline sampling campaign was conducted and the concentrations of total water-soluble inorganic ions (TWSI), carbonaceous components (OC and EC) were analyzed. The average concentrations were 88.5 μg/m3 for PM1 and 122 μg/m3 for PM2.5, and the corresponding ratios of PM1 versus PM2.5 on non-pollution, mild-moderate pollution and heavy pollution were 0.67, 0.70 and 0.77, respectively. TWSI and OC accounted for 43.2% and 15.4% in PM1, 41.8% and 16.0% in PM2.5. Secondary components in PM2.5 and PM1 increased with heavy pollution, SNA (SO42−, NO3− and NH4+) was enriched in PM1 but SOC (Secondary Organic Carbon) was more enriched in PM1–2.5. Furthermore, for evaluating the effect of aerosol feedback the WRF-Chem model was applied to identify the aerosol-radiation interaction of aerosol feedback influence on the PM2.5 concentration and various meteorological factors in Handan. The results indicated that the aerosol radiative effects will result in an average 32.62%(36.18 W/m2) decrease in downward short wave flux at ground surface (SWDOWN), an average 17.52% (39.15 m) and 0.16% (0.44 K) decrease in planetary boundary layer height(PBLH) and surface temperature (T2). The wind speed at 10 m (WS) and relative humidity (RH) will be increased by about 4.16%(0.11 m/s) and 1.89% (0.78%), respectively.

Study on the Characteristics of Size-Segregated Particulate Water-Soluble Inorganic Ions and Potentially Toxic Metals during Wintertime in a High Population Residential Area in Beijing, China

Airborne particulate matter (PM) pollution often occurs in the wintertime in northern China, posing a potential threat to human health. To date, there are limited studies about the metals and inorganic ions to link source apportionments and health risk assessments in the different size-segregated PM samples. In this study, our samples were collected by a high-volume air sampler from 26 December 2018 to 11 January 2019 in a high population residential area (Beijing). Water-soluble inorganic ions, metal elements in the different size-segregated PM samples were determined for health risk assessments by inhalation of PM. During the sampling period in Beijing, the average concentrations of PM1.1 and PM1.1–2.0 were 39.67 ± 10.66 μg m−3 and 32.25 ± 6.78 μg m−3. Distinct distribution profiles characterized the different elements. The markers of coal combustion Pb, As, and Se had >52% of their mass concentration in PM1.1. The average mass ratios of (NO3− + NO2−)/SO42−, Cl−/Na+, Cl−/K+, and Cl−/(NO3− + NO2−) were 1.68, 6.58, 6.18, and 0.57, which showed that coal combustion and vehicle emissions were the main anthropogenic sources of PM in Beijing in winter. PM1.1 was the major contributor of Pb, Cd, and As for carcinogenic risks (CR) and hazard quotient (HQ). It was indicated that PM1.1 is more harmful than coarse PM. The toxic elements of Cr (VI) (1.12 × 10−6), V (0.69 × 10−6), and As (0.41 × 10−6) caused higher CR for children than Ni, Cd, Co, and Pb. Meanwhile, Pb (35.30 × 10−6) and Ni (21.07 × 10−6) caused higher CR for adults than As, Cr (VI), V, Co, and Cd, especially PM1.1. This study provides detailed composition data and the first report on human health in a high population residential area in Beijing.

Atmospheric Behaviour of Polycyclic and Nitro-Polycyclic Aromatic Hydrocarbons and Water-Soluble Inorganic Ions in Winter in Kirishima, a Typical Japanese Commercial City

Kirishima is a typical Japanese commercial city, famous for frequent volcanic activity. This is the first study to determine the characteristics of PM2.5-bound polycyclic and nitro-polycyclic aromatic hydrocarbons (PAHs and NPAHs) and water-soluble inorganic ions (WSIIs) in this city. In this study, the non-volcanic eruption period was taken as the target and daily PM2.5 samples were collected from 24 November to 21 December 2016. The daily concentrations in PM2.5 of ƩPAHs, ƩNPAHs, and ƩWSIIs ranged from 0.36 to 2.90 ng/m3, 2.12 to 22.3 pg/m3, and 1.96 to 11.4 μg/m3, respectively. Through the results of the diagnostic ratio analyses of the PAHs, NPAHs, and WSIIs and the backward trajectory analysis of the air masses arriving in Kirishima, the emission sources of PAHs, NPAHs, and WSIIs in PM2.5 in Kirishima were influenced by the coal burning that came from the East Asian continent, although there was no influence from volcanic emission sources during the sampling period. The total benzo[a]pyrene (BaP)-equivalent concentration was lower than many other cities but the health risks in Kirishima were nonetheless notable. These findings are very important for future research on PM samples during the inactive Asian monsoon and volcanic eruption periods, to further understand the characteristics of air pollutants in Kirishima, and to contribute to the improvement in health of residents and a reduction in the atmospheric circulation of air pollutants in East Asia.