Aqueous systems at high temperature. XVIII. Activity coefficient behavior of calcium hydroxide in aqueous sodium nitrate to the critical temperature of water

1967 ◽  
Vol 71 (8) ◽  
pp. 2641-2650 ◽  
Author(s):  
LeRoy B. Yeatts ◽  
William L. Marshall
Keyword(s):  
High Temperature ◽  
Critical Temperature ◽  
Activity Coefficient ◽  
Calcium Hydroxide ◽  
Sodium Nitrate ◽  
Aqueous Systems ◽  
Aqueous Sodium

ALLEGHENY STAINLESS TYPE 405

Alloy Digest ◽  
1985 ◽  
Vol 34 (7) ◽  
Keyword(s):  
Fracture Toughness ◽  
Corrosion Resistance ◽  
High Temperature ◽  
Critical Temperature ◽  
Physical Properties ◽  
Tensile Properties ◽  
Heat Treating ◽  
Ductile Material ◽  
Air Cooling ◽  
Temperature Performance

Abstract ALLEGHENY STAINLESS Type 405, unlike most other 12% chromium steels, is not subject to appreciable hardening through air cooling from high temperatures. This is an advantageous characteristic in those applications where a soft, ductile material is required after rapid cooling from above the critical temperature. The nonhardening tendency of Type 405 also retards the formation of hardening cracks where welding is employed. Its uses include annealing boxes and baffles where hardening during cooling would be undesirable. This datasheet provides information on composition, physical properties, hardness, elasticity, and tensile properties as well as fracture toughness. It also includes information on high temperature performance and corrosion resistance as well as heat treating and machining. Filing Code: SS-461. Producer or source: Allegheny Ludlum Corporation.

scholarly journals Demonstration of Phase Change Thermal Energy Storage in Zinc Oxide Microencapsulated Sodium Nitrate

2021 ◽  
Vol 11 (13) ◽  
pp. 6234
Author(s):  
Ciprian Neagoe ◽  
Ioan Albert Tudor ◽  
Cristina Florentina Ciobota ◽  
Cristian Bogdanescu ◽  
Paul Stanciu ◽  
...  
Keyword(s):  
Zinc Oxide ◽  
Thermal Properties ◽  
High Temperature ◽  
Energy Storage ◽  
Phase Change ◽  
Thermal Energy ◽  
Sodium Nitrate ◽  
Thermal Energy Storage ◽  
Metal Corrosion ◽  
Scanning Calorimetry

Microencapsulation of sodium nitrate (NaNO3) as phase change material for high temperature thermal energy storage aims to reduce costs related to metal corrosion in storage tanks. The goal of this work was to test in a prototype thermal energy storage tank (16.7 L internal volume) the thermal properties of NaNO3 microencapsulated in zinc oxide shells, and estimate the potential of NaNO3–ZnO microcapsules for thermal storage applications. A fast and scalable microencapsulation procedure was developed, a flow calorimetry method was adapted, and a template document created to perform tank thermal transfer simulation by the finite element method (FEM) was set in Microsoft Excel. Differential scanning calorimetry (DSC) and transient plane source (TPS) methods were used to measure, in small samples, the temperature dependency of melting/solidification heat, specific heat, and thermal conductivity of the NaNO3–ZnO microcapsules. Scanning electron microscopy (SEM) and chemical analysis demonstrated the stability of microcapsules over multiple tank charge–discharge cycles. The energy stored as latent heat is available for a temperature interval from 303 to 285 °C, corresponding to onset–offset for NaNO3 solidification. Charge–self-discharge experiments on the pilot tank showed that the amount of thermal energy stored in this interval largely corresponds to the NaNO3 content of the microcapsules; the high temperature energy density of microcapsules is estimated in the range from 145 to 179 MJ/m3. Comparison between real tank experiments and FEM simulations demonstrated that DSC and TPS laboratory measurements on microcapsule thermal properties may reliably be used to design applications for thermal energy storage.

scholarly journals Evaluation on the Bond Capacity of the Fire-Protected FRP Bonded to Concrete Under High Temperature

2021 ◽  
Vol 15 (1) ◽  
Author(s):  
Soo-yeon Seo ◽  
Jong-wook Lim ◽  
Su-hyun Jeong
Keyword(s):  
High Temperature ◽  
Critical Temperature ◽  
Temperature Variation ◽  
Fire Resistance ◽  
Fire Protection ◽  
Element Analysis ◽  
External Temperature ◽  
Near Surface ◽  
Board Type ◽  
The Face

AbstractTo figure out the change in the reinforcing effect of FRP system used for the retrofit of RC beam when it is exposed to high temperature, it is required to evaluate not only the behavior of the entire beam, but also the bond performance at anchorage zone through a bond test according to the increase of external temperature. Moreover, the study to find various fire-protection methods is necessary to prevent the epoxy from reaching the critical temperature during an exposure to high temperature. In this manner, the fire-resistance performances of externally bonded (EB) FRP and near-surface-mounted (NSM) FRP to concrete block were evaluated by high-temperature exposure tests after performing a fire-protection on the surface in this paper. Board-type insulation with mortar was considered for the fire-protection of FRP system. After the fire-protection of the FRPs bonded to concrete blocks, an increasing exposure temperature was applied to the specimens with keeping a constant shear bond stress between concrete and the FRP. Based on the result, the temperature when the bond strength of the FRP disappears was evaluated. In addition, a finite element analysis was performed to find a proper method for predicting the temperature variation of the epoxy which is fire-protected with board-type insulation during the increase of external temperature. As a result of the test, despite the same fire-protection, NSM specimens were able to resist 1.54–2.08 times higher temperature than EB specimens. In the design of fire-protection of FRP system with the board-type insulation, it is necessary to consider the transfer from sides as well as the face with FRP. If there is no insulation of FP boards on the sides, the epoxy easily reaches its critical temperature by the heat penetrated to the sides, and increasing the thickness of the FP board alone for the face with FRP does not increase the fire-resistance capacity. As a result of the FE analysis, the temperature variation at epoxy can be predicted using the analytical approach with the proper thermal properties of FP mortar and board.

scholarly journals Cooper Pair-Like Systems at High Temperature and their Role on Fluctuations Near the Critical Temperature

1998 ◽  
Vol 12 (29n31) ◽  
pp. 3216-3219 ◽  
Author(s):  
M. Ausloos ◽  
S. Dorbolo
Keyword(s):  
Phase Transition ◽  
Electrical Resistivity ◽  
High Temperature ◽  
Critical Temperature ◽  
Oxygen Diffusion ◽  
Cooper Pair ◽  
Anomalous Behavior ◽  
Anomalous Effect ◽  
Linear Temperature ◽  
Ybco Sample

A logarithmic behavior is hidden in the linear temperature regime of the electrical resistivity R(T) of some YBCO sample below 2T c where "pairs" break apart, fluctuations occur and "a gap is opening". An anomalous effect also occurs near 200 K in the normal state Hall coefficient. In a simulation of oxygen diffusion in planar 123 YBCO, an anomalous behavior is found in the oxygen-vacancy motion near such a temperature. We claim that the behavior of the specific heat above and near the critical temperature should be reexamined in order to show the influence and implications of fluctuations and dimensionality on the nature of the phase transition and on the true onset temperature.

Hydrolysis of Zinc Ion and Solubility of Zinc Oxide in High-Temperature Aqueous Systems

1997 ◽  
Vol 127 (3) ◽  
pp. 292-299 ◽  
Author(s):  
Yukiko Hanzawa ◽  
Daisuke Hiroishi ◽  
Chihiro Matsuura ◽  
Kenkichi Ishigure ◽  
Masashi Nagao ◽  
...  
Keyword(s):  
Zinc Oxide ◽  
High Temperature ◽  
Zinc Ion ◽  
Aqueous Systems ◽  
Hydrolysis Of

Studies on the freezing of pure liquids I. Critical supercooling in molten alkali halides

1960 ◽  
Vol 259 (1298) ◽  
pp. 325-340 ◽  
Keyword(s):  
High Temperature ◽  
Critical Temperature ◽  
Melting Point ◽  
Alkali Halide ◽  
Alkali Halides ◽  
Solid Particles ◽  
High Supersaturation ◽  
Chamber Temperature ◽  
Reduced Temperature ◽  
Heater Coil

A high-temperature cloud chamber is described in which a bead of alkali halide is supported on a heater coil mounted in the roof. By passing the current through the coil the temperature of the bead may be momentarily raised by several hundred degrees, producing salt vapour at high supersaturation. Condensation ensues in the presence of the inert supporting gas, and clouds of droplets or solid particles appear depending on the chamber temperature. Light scattered from the clouds under strong illumination is examined with a telescope, and the presence of crystalline particles is detected by their capacity to scintillate, or ‘twinkle’. It is found that twinkling in clouds of alkali halides appears sharply as the temperature is lowered below the melting point, defining a critical temperature of solidification for each salt. Reasons are given for regarding this temperature as the freezing threshold of molten salt droplets, for which supercoolings of about 150 °C are indicated. A reduced temperature, given by the ratio of the freezing threshold to the melting point, has the value of approximately 0.8 for all the alkali halides examined.

Anodic dissolution of cobalt in aqueous sodium nitrate solution at high current densities

2014 ◽  
Vol 66 (6) ◽  
pp. 549-556 ◽  
Author(s):  
M. Schneider ◽  
N. Schubert ◽  
S. Höhn ◽  
A. Michaelis
Keyword(s):  
Anodic Dissolution ◽  
Sodium Nitrate ◽  
Nitrate Solution ◽  
High Current ◽  
Aqueous Sodium ◽  
Current Densities ◽  
Sodium Nitrate Solution

scholarly journals Torque magnetometry on single-crystal high-temperature superconductors near the critical temperature: A scaling approach

2000 ◽  
Vol 62 (1) ◽  
pp. 631-639 ◽  
Author(s):  
J. Hofer ◽  
T. Schneider ◽  
J. M. Singer ◽  
M. Willemin ◽  
H. Keller ◽  
...  
Keyword(s):  
High Temperature ◽  
Critical Temperature ◽  
Single Crystal ◽  
High Temperature Superconductors ◽  
Torque Magnetometry
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