Systematic oxygen impurity reduction in smooth N-Polar GaN by chemical potential control

Process chemical potential control (CPC) and dislocation reduction were implemented to control oxygen concentration in N-polar GaN layers grown on sapphire substrates via metal organic chemical vapor deposition (MOCVD). Process CPC offers a systematic and predictive framework for MOCVD experimental design relating the universal thermodynamic parameter, supersaturation directly to oxygen incorporation in N-polar GaN. As process supersaturation was changed from ~30 to 3,400, the formation energy of the oxygen point defect increased, which resulted in a 25-fold decrease in oxygen incorporation. Reducing dislocations by approximately a factor of 4 (to ~10^9 cm^-3) allowed for further reduction of oxygen incorporation to the low-10^17 cm^-3 range. Smooth N-polar GaN layers with low oxygen content were achieved by a two-step process, whereas first a 1 µm thick smooth N-polar layer with high oxygen concentration was grown, followed by low oxygen concentration layer grown at high supersaturation.

Rhombic Calcite Microcrystals as a Textural Proxy for Meteoric Diagenesis

Numerous Phanerozoic limestones are characterized by diagenetic calcite microcrystals formed during mineralogical stabilization of metastable carbonate sediments in various diagenetic environments. Laboratory experiments show that calcite precipitating under conditions similar to those that characterize meteoric settings (impurity-free, low supersaturation, high fluid:solid ratio) exhibits the rhombic form, whereas calcite precipitating under conditions similar to those that prevail in marine burial settings (impurity-rich, high supersaturation, low fluid:solid ratio) exhibits non-rhombic forms. This prediction is tested here using new and previously published textural and geochemical data from the rock record. These data show that the vast majority of Phanerozoic limestones characterized by rhombic microcrystals also exhibit petrographic and/or geochemical evidence (depleted 𝛿13C, 𝛿18O, and trace elements) indicative of meteoric diagenesis. In contrast, non-rhombic forms are associated with marine burial conditions, suggesting that rhombic calcite microcrystals may provide a valuable textural proxy for meteoric diagenesis in Phanerozoic limestones.

3D Modeling of Supersaturated H2O/H2O2 on Early Mars Climate during the Noachia

<p>The climate of Mars during its first billion years is one of the most intriguing question in our understanding of the Solar System. The planet was host of a large amount of liquid water flowing on the surface throughout the Noachian era, approximatively 4Gya. Geomorphological observations is the main evidence for liquid water since valley networks and lakes are still visible on the surface, although dry nowadays.</p> <p>Different studies have tried to reproduce the conditions that may have occured on the planet, trying to find an atmospheric process or composition that could solve the Faint Young Sun Paradox. Theses modeling studies, through the use of 3-dimensional Global Climate Models struggled to warm sufficiently the past climate of Mars, even considering different greenhouse gases, the role of clouds, meteoritic impact or even volcanism (XXX). However, the presence of H2 could be an interesting solution for a sustainable warming as some recent studies suggest (Turbet and Forget, 2021). Another recent study (Ito et al. 2020) suggested that H2O2 might be a convincing candidate but has to be in high supersaturation ratio in the atmosphere, even though it only used a simplified 1D model and relatively high supersaturation levels.</p> <p>We try here to explore more in detail the scenario of supersaturated H2O2 and H2O, that also might be a specy able to provide a sufficient global warming under supersaturated conditions or through the formation of high altitude clouds. Since H2O is the major source of H2O2 in the atmosphere, it is important to assess whether the H2O content in the atmosphere is enough to provide high quantities of H2O2. We also try to constrain the theoritical supersaturation level of H2O/H2O2 that will allow the warming of the climate above 273K, but with a detailled 3D GCM simulation. Even if we do not tackle the question whether the supersaturation hypothesis is realistic or not, these results give a better understanding of  what would be Early Mars' climate under such conditions.</p>

Role of Thermodynamics and Kinetics in the Composition of Ternary III-V Nanowires

We explain the composition of ternary nanowires nucleating from a quaternary liquid melt. The model we derive describes the evolution of the solid composition from the nucleated-limited composition to the kinetic one. The effect of the growth temperature, group V concentration and Au/III concentration ratio on the solid-liquid dependence is studied. It has been shown that the solid composition increases with increasing temperature and Au concentration in the droplet at the fixed In/Ga concentration ratio. The model does not depend on the site of nucleation and the geometry of monolayer growth and is applicable for nucleation and growth on a facet with finite radius. The case of a steady-state (or final) solid composition is considered and discussed separately. While the nucleation-limited liquid-solid composition dependence contains the miscibility gap at relevant temperatures for growth of InxGa1−xAs NWs, the miscibility gap may be suppressed completely in the steady-state growth regime at high supersaturation. The theoretical results are compared with available experimental data via the combination of the here described solid-liquid and a simple kinetic liquid-vapor model.

Drop Size Distribution Broadening Mechanisms in a Bin Microphysics Eulerian Model

In this study, processes that broaden drop size distributions (DSDs) in Eulerian models with two-moment bin microphysics are analyzed. Numerous tests are performed to isolate the effects of different physical mechanisms that broaden DSDs in two- and three-dimensional Weather Research and Forecasting Model simulations of an idealized ice-free cumulus cloud. Sensitivity of these effects to modifying horizontal and vertical model grid spacings is also examined. As expected, collision–coalescence is a key process broadening the modeled DSDs. In-cloud droplet activation also contributes substantially to DSD broadening, whereas evaporation has only a minor effect and sedimentation has little effect. Cloud dilution (mixing of cloud-free and cloudy air) also broadens the DSDs considerably, whether or not it is accompanied by evaporation. This mechanism involves the reduction of droplet concentration from dilution along the cloud’s lateral edges, leading to locally high supersaturation and enhanced drop growth when this air is subsequently lifted in the updraft. DSD broadening ensues when the DSDs are mixed with those from the cloud core. Decreasing the horizontal and vertical model grid spacings from 100 to 30 m has limited impact on the DSDs. However, when these physical broadening mechanisms (in-cloud activation, collision–coalescence, dilution, etc.) are turned off, there is a reduction of DSD width by up to ~20%–50% when the vertical grid spacing is decreased from 100 to 30 m, consistent with effects of artificial broadening from vertical numerical diffusion. Nonetheless, this artificial numerical broadening appears to be relatively unimportant overall for DSD broadening when physically based broadening mechanisms in the model are included for this cumulus case.

Distribution Characteristics of Aerosol Size and CCN during the Summer on Mt. Tian and Their Influencing Factors

The aerosol size distribution and cloud condensation nuclei (CCN) number concentration were measured using a wide-range particle spectrometer (WPS) and a cloud condensation nuclei counter (CCNC) on Mt. Tian from 31 July to 9 September, 2019. Combined with meteorological data, distribution characteristics of aerosol size and CCN and their influencing factors were analyzed. The results indicated that the mean aerosol number concentration was 5475.6 ± 5636.5 cm−3. The mean CCN concentrations were 183.7 ± 114.5 cm−3, 729.8 ± 376.1 cm−3, 1630.5 ± 980.5 cm−3, 2162.5 ± 1345.3 cm−3, and 2575.7 ± 1632.9 cm−3 at supersaturation levels of 0.1%, 0.2%, 0.4%, 0.6%, and 0.8%, respectively. The aerosol number size distribution is unimodal, and the dominant particle size is 30–60 nm. Affected by the height of the boundary layer and the valley wind, the diurnal variation in aerosol number concentration shows a unimodal distribution with a peak at 17:00, and the CCN number concentration showed a bimodal distribution with peaks at 18:00 and 21:00. The particle size distribution and supersaturation have a major impact on the activation of the aerosol into CCN. At 0.1% supersaturation (S), the 300–500 nm particles are most likely to activate to CCN. Particles of 100–300 nm are most easily activated at 0.2% (S), while particles of 60–80 nm are most likely activated at high supersaturation (≥0.4%). The concentrations of aerosol and CCN are higher in the northerly wind. Ambient relative humidity (RH) has little relationship with the aerosol activation under high supersaturation. According to N = CSk fitting the CCN spectrum, C = 3297 and k = 0.90 on Mt. Tian, characteristic of the clean continental type.

Prospects of Bulk Growth of 3C-SiC Using Sublimation Growth

Free standing 3C-SiC wafers with a dimeter of 50 mm and a thickness of ca. 0.8 mm have been grown on a regular base using 3C-SiC CVD seed transfer from Si wafers to a poly-SiC-carrier and a sublimation epitaxy configuration. Up to the thickness of almost 1 mm, stable growth conditions of the cubic polytype have been achieved. The high supersaturation was kept stable by the proper design of the hot zone that enables a high axial temperature gradient at the growth interface. The Sirich gas phase was realized by the application of a Tantalum getter that was integrated into the graphitebased growth cell. Furthermore, an adaption of the growth setup allowed the growth of 3C material with a diameter of 95 mm and bulk material up to 3 mm on 25 mm diameter. Computer simulations were used to determine the supersaturation of the growth setup for different source-to-seed distances. The minimum supersaturation necessary for stable growth of cubic SiC was found to be higher 0.1 for seed already containing the required 3C polytype.

Investigation of the effect of isothermal heat treatments on mechanical properties of thermo-mechanically rolled S700MC steel grade

The effect of isothermal heat treatments (1 hour at 200, 400, 600 and 800°C) on mechanical properties of thermo-mechanically rolled S700MC steel has been investigated by extensive mechanical characterizations. Treatments at 600°C increase yield and tensile strength and decrease impact energy. Below 600°C the steel retains its bainitic structure. Precipitation kinetics simulations indicate that this secondary hardening effect arises from the nucleation of fine (Nb,Ti)C particles, indicating that the bainitic structure is unstable above 600°C due to its high supersaturation with respect to C, Nb and Ti. These results can help to optimize the operating practices for post-weld heat treatments.