Influence of High Pressure on the Liquidus Curve Shape in Binary Hydrocarbon Mixtures:  Experimental Data, Correlation, and Prediction†

2005 ◽  
Vol 50 (3) ◽  
pp. 1073-1082 ◽  
Author(s):  
Urszula Domańska ◽  
Piotr Morawski
2006 ◽  
Vol 503-504 ◽  
pp. 433-438 ◽  
Author(s):  
Xavier Sauvage

Concentration gradients resulting from long range diffusion during Severe Plastic Deformation (SPD) have been investigated with the 3D Atom Probe technique (3D-AP). First, in a pearlitic steel where alloying elements (Mn, Si and Cr) are partitioned between the ferrite and carbides in the non-deformed state. After processing by High Pressure Torsion (HPT), they are homogeneously distributed in the nanostructure, indicating that long range diffusion occurred along with the dissolution of carbides. 3D-AP data of a Cu-Fe composite processed by HPT show as well a significant interdiffusion of Cu and Fe, probably promoted by additional vacancies. On the basis of these experimental data, and using the theory described for irradiated materials, vacancy fluxes and vacancy production rates were estimated assuming that new vacancies are continuously produced and eliminated on grain boundaries.


2017 ◽  
Vol 2017 ◽  
pp. 1-15
Author(s):  
Salah Al-Enezi

This paper examines the effect of high-pressure carbon dioxide on the foaming process in polystyrene near the glass transition temperature and the foaming was studied using cylindrical high-pressure view cell with two optical windows. This technique has potential applications in the shape foaming of polymers at lower temperatures, dye impregnation, and the foaming of polystyrene. Three sets of experiments were carried out at operating temperatures of 50, 70, and 100°C, each over a range of pressures from 24 to 120 bar. Foaming was not observed when the polymer was initially at conditions below Tg but was observed above Tg. The nucleation appeared to occur randomly leading to subsequent bubble growth from these sites, with maximum radius of 0.02–0.83 mm. Three models were applied on the foaming experimental data. Variable diffusivity and viscosity model (Model C) was applied to assess the experimental data with the WLF equation. The model shows very good agreement by using realistic parameter values. The expansion occurs by diffusion of a dissolved gas from the supersaturated polymer envelope into the bubble.


2019 ◽  
Vol 12 (01) ◽  
pp. 1850105 ◽  
Author(s):  
Hairui Sun ◽  
Pin Lv ◽  
Chao Wang ◽  
Yunxian Liu ◽  
Xiaopeng Jia ◽  
...  

A series of binary-doped CoSb3 with Te and Se/Sn bulk compounds Co4Sb[Formula: see text]TexSny/Sey ([Formula: see text] and 0.6, [Formula: see text] and 0.3), have been successfully prepared via a simple high pressure and high-temperature (HPHT) method. And, the influence of the doping elements on the microstructure of the samples synthesized under diverse pressures and the corresponding TE performance were studied in detail. Comparing with other preparation methods, the synthesis time of HPHT was acutely shortened. The obtained samples contain more grain boundaries, lattice disorder, dislocations and the possible “nanodot”, which have positive effect on reducing thermal conductivity. The experimental data indicate that the absolute values of Seebeck coefficient increases with pressure. What’s more, the thermal conductivities show a monotone decreasing trend as the synthesis pressure rises. The minimum value obtained is 1.93[Formula: see text]Wm[Formula: see text]K[Formula: see text] at normal temperature for Co4Sb[Formula: see text]Te[Formula: see text]Se[Formula: see text] prepared under 3[Formula: see text]GPa.


Author(s):  
Jong-Shang Liu ◽  
Mark C. Morris ◽  
Malak F. Malak ◽  
Randall M. Mathison ◽  
Michael G. Dunn

In order to have higher power to weight ratio and higher efficiency gas turbine engines, turbine inlet temperatures continue to rise. State-of-the-art turbine inlet temperatures now exceed the turbine rotor material capability. Accordingly, one of the best methods to protect turbine airfoil surfaces is to use film cooling on the airfoil external surfaces. In general, sizable amounts of expensive cooling flow delivered from the core compressor are used to cool the high temperature surfaces. That sizable cooling flow, on the order of 20% of the compressor core flow, adversely impacts the overall engine performance and hence the engine power density. With better understanding of the cooling flow and accurate prediction of the heat transfer distribution on airfoil surfaces, heat transfer designers can have a more efficient design to reduce the cooling flow needed for high temperature components and improve turbine efficiency. This in turn lowers the overall specific fuel consumption (SFC) for the engine. Accurate prediction of rotor metal temperature is also critical for calculations of cyclic thermal stress, oxidation, and component life. The utilization of three-dimensional computational fluid dynamics (3D CFD) codes for turbomachinery aerodynamic design and analysis is now a routine practice in the gas turbine industry. The accurate heat-transfer and metal-temperature prediction capability of any CFD code, however, remains challenging. This difficulty is primarily due to the complex flow environment of the high-pressure turbine, which features high speed rotating flow, coupling of internal and external unsteady flows, and film-cooled, heat transfer enhancement schemes. In this study, conjugate heat transfer (CHT) simulations are performed on a high-pressure cooled turbine stage, and the heat flux results at mid span are compared to experimental data obtained at The Ohio State University Gas Turbine Laboratory (OSUGTL). Due to the large difference in time scales between fluid and solid, the fluid domain is simulated as steady state while the solid domain is simulated as transient in CHT simulation. This paper compares the unsteady and transient results of the heat flux on a high-pressure cooled turbine rotor with measurements obtained at OSUGTL.


Author(s):  
Tommaso Bacci ◽  
Tommaso Lenzi ◽  
Alessio Picchi ◽  
Lorenzo Mazzei ◽  
Bruno Facchini

Modern lean burn aero-engine combustors make use of relevant swirl degrees for flame stabilization. Moreover, important temperature distortions are generated, in tangential and radial directions, due to discrete fuel injection and liner cooling flows respectively. At the same time, more efficient devices are employed for liner cooling and a less intense mixing with the mainstream occurs. As a result, aggressive swirl fields, high turbulence intensities, and strong hot streaks are achieved at the turbine inlet. In order to understand combustor-turbine flow field interactions, it is mandatory to collect reliable experimental data at representative flow conditions. While the separated effects of temperature, swirl, and turbulence on the first turbine stage have been widely investigated, reduced experimental data is available when it comes to consider all these factors together.In this perspective, an annular three-sector combustor simulator with fully cooled high pressure vanes has been designed and installed at the THT Lab of University of Florence. The test rig is equipped with three axial swirlers, effusion cooled liners, and six film cooled high pressure vanes passages, for a vortex-to-vane count ratio of 1:2. The relative clocking position between swirlers and vanes has been chosen in order to have the leading edge of the central NGV aligned with the central swirler. In order to generate representative conditions, a heated mainstream passes though the axial swirlers of the combustor simulator, while the effusion cooled liners are fed by air at ambient temperature. The resulting flow field exiting from the combustor simulator and approaching the cooled vane can be considered representative of a modern Lean Burn aero engine combustor with swirl angles above ±50 deg, turbulence intensities up to about 28% and maximum-to-minimum temperature ratio of about 1.25. With the final aim of investigating the hot streaks evolution through the cooled high pressure vane, the mean aerothermal field (temperature, pressure, and velocity fields) has been evaluated by means of a five-hole probe equipped with a thermocouple and traversed upstream and downstream of the NGV cascade.


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