Nuclear structure, stability, and nucleon pairing are served by alternating up and down quark sequences

2021 ◽  
Author(s):  
Raymond Walsh
Keyword(s):  
Nuclear Structure ◽  
Structure Stability ◽  
Down Quark ◽  
Nucleon Pairing

Development and Psychometric Evaluation of a Revised Sense of Coherence Scale

2018 ◽  
Vol 34 (3) ◽  
pp. 206-215 ◽  
Author(s):  
Rahel Bachem ◽  
Andreas Maercker
Keyword(s):  
Posttraumatic Growth ◽  
Factor Structure ◽  
Sense Of Coherence ◽  
Psychological Health ◽  
Psychometric Evaluation ◽  
Health Indicators ◽  
Structure Stability ◽  
Confirmatory Factor Analyses ◽  
Reliability Factor ◽  
Two Samples

Abstract. The present study introduces a revised Sense of Coherence (SOC) scale, a new conceptualization and operationalization of the resilience indicator SOC. It outlines the scale development and aims for testing its reliability, factor structure, and validity. Literature on Antonovsky’s SOC (SOC-A) was critically reviewed to identify needs for improving the scale. The scale was investigated in two samples. Sample 1 consisted of 334 bereaved participants, Sample 2 of 157 healthy controls. The revised SOC Scale, SOC-A, and theoretically relevant questionnaires were applied. Explorative and confirmatory factor analyses established a three-factor structure in both samples. The revised SOC Scale showed significant but discriminative associations with related constructs, including self-efficacy, posttraumatic growth, and neuroticism. The revised measure was significantly associated with psychological health indicators, including persistent grief, depression, and anxiety, but not to the extent as the previous SOC-A. Stability over time was sufficient. The study provides psychometric support for the revised SOC conceptualization and scale. It has several advantages over the previous SOC-A scale (unique variance, distinct factor structure, stability). The scale could be used for clinical and health psychological testing or research into the growing field of studies on resilience over the life span.

Structure, Stability and Water Adsorption on Ultra-Thin TiO2 Supported on TiN

2019 ◽  
Author(s):  
Jose Julio Gutierrez Moreno ◽  
Marco Fronzi ◽  
Pierre Lovera ◽  
alan O'Riordan ◽  
Mike J Ford ◽  
...  
Keyword(s):  
Density Functional ◽  
Water Adsorption ◽  
Chemical Potential ◽  
Energy Gap ◽  
Molecular Water ◽  
Structure Stability ◽  
Ambient Conditions ◽  
Rutile Structure ◽  
The Stability ◽  
The One

<p></p><p>Interfacial metal-oxide systems with ultrathin oxide layers are of high interest for their use in catalysis. In this study, we present a density functional theory (DFT) investigation of the structure of ultrathin rutile layers (one and two TiO<sub>2</sub> layers) supported on TiN and the stability of water on these interfacial structures. The rutile layers are stabilized on the TiN surface through the formation of interfacial Ti–O bonds. Charge transfer from the TiN substrate leads to the formation of reduced Ti<sup>3+</sup> cations in TiO<sub>2.</sub> The structure of the one-layer oxide slab is strongly distorted at the interface, while the thicker TiO<sub>2</sub> layer preserves the rutile structure. The energy cost for the formation of a single O vacancy in the one-layer oxide slab is only 0.5 eV with respect to the ideal interface. For the two-layer oxide slab, the introduction of several vacancies in an already non-stoichiometric system becomes progressively more favourable, which indicates the stability of the highly non-stoichiometric interfaces. Isolated water molecules dissociate when adsorbed at the TiO<sub>2</sub> layers. At higher coverages the preference is for molecular water adsorption. Our ab initio thermodynamics calculations show the fully water covered stoichiometric models as the most stable structure at typical ambient conditions. Interfacial models with multiple vacancies are most stable at low (reducing) oxygen chemical potential values. A water monolayer adsorbs dissociatively on the highly distorted 2-layer TiO<sub>1.75</sub>-TiN interface, where the Ti<sup>3+</sup> states lying above the top of the valence band contribute to a significant reduction of the energy gap compared to the stoichiometric TiO<sub>2</sub>-TiN model. Our results provide a guide for the design of novel interfacial systems containing ultrathin TiO<sub>2</sub> with potential application as photocatalytic water splitting devices.</p><p></p>

pH-Dependent Thermal Stability of Vibrio cholerae L-asparaginase

2019 ◽  
Vol 26 (10) ◽  
pp. 743-750 ◽  
Author(s):  
Remya Radha ◽  
Sathyanarayana N. Gummadi
Keyword(s):  
Vibrio Cholerae ◽  
Conformational Changes ◽  
Kinetic Studies ◽  
Structural Features ◽  
Structure Stability ◽  
Kcal Mole ◽  
Scanning Calorimetry ◽  
Wide Range ◽  
Ph Dependent ◽  
Ph Range

Background:pH is one of the decisive macromolecular properties of proteins that significantly affects enzyme structure, stability and reaction rate. Change in pH may protonate or deprotonate the side group of aminoacid residues in the protein, thereby resulting in changes in chemical and structural features. Hence studies on the kinetics of enzyme deactivation by pH are important for assessing the bio-functionality of industrial enzymes. L-asparaginase is one such important enzyme that has potent applications in cancer therapy and food industry.Objective:The objective of the study is to understand and analyze the influence of pH on deactivation and stability of Vibrio cholerae L-asparaginase.Methods:Kinetic studies were conducted to analyze the effect of pH on stability and deactivation of Vibrio cholerae L-asparaginase. Circular Dichroism (CD) and Differential Scanning Calorimetry (DSC) studies have been carried out to understand the pH-dependent conformational changes in the secondary structure of V. cholerae L-asparaginase.Results:The enzyme was found to be least stable at extreme acidic conditions (pH< 4.5) and exhibited a gradual increase in melting temperature from 40 to 81 °C within pH range of 4.0 to 7.0. Thermodynamic properties of protein were estimated and at pH 7.0 the protein exhibited ΔG37of 26.31 kcal mole-1, ΔH of 204.27 kcal mole-1 and ΔS of 574.06 cal mole-1 K-1.Conclusion:The stability and thermodynamic analysis revealed that V. cholerae L-asparaginase was highly stable over a wide range of pH, with the highest stability in the pH range of 5.0–7.0.

Water, Water, Here and There

2018 ◽  
Author(s):  
Steven E. Vigdor
Keyword(s):  
Quark Mass ◽  
Mass Difference ◽  
Baryon Number ◽  
Electroweak Phase Transition ◽  
Hydrogen Burning ◽  
Quark Masses ◽  
Grand Unified Theories ◽  
Down Quark ◽  
Unified Theories ◽  
The Stability

Chapter 4 deals with the stability of the proton, hence of hydrogen, and how to reconcile that stability with the baryon number nonconservation (or baryon conservation) needed to establish a matter–antimatter imbalance in the infant universe. Sakharov’s three conditions for establishing a matter–antimatter imbalance are presented. Grand unified theories and experimental searches for proton decay are described. The concept of spontaneous symmetry breaking is introduced in describing the electroweak phase transition in the infant universe. That transition is treated as the potential site for introducing the imbalance between quarks and antiquarks, via either baryogenesis or leptogenesis models. The up–down quark mass difference is presented as essential for providing the stability of hydrogen and of the deuteron, which serves as a crucial stepping stone in stellar hydrogen-burning reactions that generate the energy and elements needed for life. Constraints on quark masses from lattice QCD calculations and violations of chiral symmetry are discussed.

Nuclear Electrons and Nuclear Structure

2018 ◽  
Author(s):  
Roger H. Stuewer
Keyword(s):  
Nuclear Structure ◽  
Beta Decay ◽  
Gamma Rays ◽  
Alpha Particle ◽  
Continuous Distribution ◽  
Alpha Particles ◽  
Light Nuclei ◽  
Coincidence Method ◽  
Wolfgang Pauli ◽  
Beta Particles

Serious contradictions to the existence of electrons in nuclei impinged in one way or another on the theory of beta decay and became acute when Charles Ellis and William Wooster proved, in an experimental tour de force in 1927, that beta particles are emitted from a radioactive nucleus with a continuous distribution of energies. Bohr concluded that energy is not conserved in the nucleus, an idea that Wolfgang Pauli vigorously opposed. Another puzzle arose in alpha-particle experiments. Walther Bothe and his co-workers used his coincidence method in 1928–30 and concluded that energetic gamma rays are produced when polonium alpha particles bombard beryllium and other light nuclei. That stimulated Frédéric Joliot and Irène Curie to carry out related experiments. These experimental results were thoroughly discussed at a conference that Enrico Fermi organized in Rome in October 1931, whose proceedings included the first publication of Pauli’s neutrino hypothesis.

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