A sublattice-model isotherm for the competitive coadsorption of hydrogen and bromide on a Pt(100)electrode

2010 ◽  
Vol 12 (1) ◽  
pp. 143-148 ◽  
Author(s):  
N. Garcia-Araez ◽  
M. T. M Koper
Keyword(s):  
Sublattice Model ◽  
Model Isotherm

Pemanfaatan Cangkang Pensi (Corbicula Moltkiana) sebagai Bahan Penyerap Zat Warna Rhodamin B Dalam Larutan

2019 ◽  
Vol 2 (2) ◽  
Author(s):  
Rahmiana Zein ◽  
Mutia Khuratul Aini ◽  
Hermansyah Aziz
Keyword(s):  
Rhodamine B ◽  
Sem Analysis ◽  
Spectra Analysis ◽  
Biosorption Capacity ◽  
Biosorption Process ◽  
Langmuir Isotherm Model ◽  
Ft Ir ◽  
Cationic Exchange ◽  
Rhodamin B ◽  
Model Isotherm

Biosorpsi zat warna Rhodamine B menggunakan cangkang Pensi (Corbicula moltkiana) telah dikaji. Percobaan dilakukan dengan system batch guna memperoleh kondisi optimum biosorspi zat warna. Kapasitas biosorpsi zat warna pada pH 2 adalah 0.9958 mg/g, dengan konsentrasi larutan mula-mula 150 mg/L waktu kontak 105 menit, massa biosorben 0.1 g, ukuran partikel 32 µm dan temperature pengeringan biosorben pada 75oC. Model isotherm Langmuir menunjukkan bahwa proses penyerapan berlangsung secara kimia dan biosorpsi homogeny dari adsorbat (Rhodamine B) pada permukaan biosorben membentuk lapisan tunggal dengan nilai R2 0.9966. Analisis XRF menunjukkan bahwa penurunan kadar unsur logam pada cangkang Pensi membuktikan bahwa proses biosorpsi berlangsung dengan pertukaran kation. Hasil analisis spektrum FT-IR membuktikan adanya interaksi antaramolekul Rhodamin B dengan gugus fungsi pada cangkang Pensi. Analisis dengan SEM memperlihatkan bahwa pori-pori cangkang Pensi telah terisi penuh oleh molekul Rhodamin B. Kondisi optimum biosorpsi telah diaplikasikan pada limbah kerupuk merah dengan kapasitas penyerapan sebesar 0,2835 mg/g.   The biosorption of Rhodamine B dyes by Pensi (Corbicula moltkiana) shell has been investigated. The experiment was conducted in batch sistem in order to obtain the optimum conditions of dye biosorption. Biosorption capacity of dye was 0.9958 mg/g at pH 2, initial concentration 150 mg/L, contact time 105 minutes, biosorbent mass 0.1 gram, particle size 32 µ m and biosorbent drying temperature was at 75oC. The Langmuir Isotherm model showed chemisorption and homogeneous biosorption process of adsorbates onto the biosorbent surface formed monolayer dye molecules on the biosorbent surface with R2 value was 0.9966. XRF analysis showed that reduction of metals unsure quantity of pensi shell indicated biosorption process was occupied through cationic exchange. The result of FTIR spectra analysis indicated an interaction between Rhodamin B molecules and functional group of pensi shell. SEM analysis showed that the pensi shell pores were completely filled by Rhodamine B molecules. The optimum condition of biosorption has been aplicated in red chips wastewater industry with biosorption capacity was 0.2835 mg/g.

On the magnetic three-sublattice model with two equivalent sublattices

1994 ◽  
Vol 203 (1-2) ◽  
pp. 29-53 ◽  
Author(s):  
J.H.P. Colpa ◽  
J.H.V.J. Brabers
Keyword(s):  
Sublattice Model

Analysis of a magnetization process based on a two sublattice model

1992 ◽  
Vol 71 (7) ◽  
pp. 3434-3438 ◽  
Author(s):  
Zhi‐dong Zhang ◽  
Tong Zhao ◽  
X. K. Sun ◽  
Y. C. Chuang
Keyword(s):  
Magnetization Process ◽  
Sublattice Model

scholarly journals Thermodynamic reassessment of the Mn-Ni-Si system

2015 ◽  
Vol 51 (2) ◽  
pp. 125-132 ◽  
Author(s):  
B. Hu ◽  
Y. Du ◽  
J.J. Yuan ◽  
Z.F. Liu ◽  
Q.P. Wang
Keyword(s):  
Experimental Data ◽  
Phase Diagram ◽  
Phase Diagrams ◽  
Thermodynamic Parameters ◽  
Ternary Phase ◽  
Sublattice Model ◽  
Diagram Approach ◽  
Measured Phase

Iased on the new experimental data available in the literature, the Mn-Ni-Si system has been reassessed using the CALPHAD (CALculation of PHAse Diagram) approach. Compared with the previous modeling, the ?8 and ?12 ternary phases were treated as the same phase according to the new experimental data. The Mn3Si phase was described with two sublattice model (Mn, Ni)3(Si)1. The reported new ternary phase ? was not considered in the present work. Comprehensive comparisons between the calculated and measured phase diagrams showed that a set of thermodynamic parameters of the Mn-Ni-Si system obtained in this work was more accurate than the previous one.

scholarly journals Kesetimbangan Adsorpsi Zat Warna Methyl Violet Oleh Karbon Aktif Berbasis Limbah Daun Nanas (Ananas comosus L)

METANA ◽  
2018 ◽  
Vol 14 (2) ◽  
pp. 31
Author(s):  
Lanjar Lanjar ◽  
Fatma Indah Riayanti ◽  
Widi Astuti
Keyword(s):  
Electron Microscopy ◽  
Scanning Electron Microscopy ◽  
Fourier Transform ◽  
Surface Area ◽  
Methyl Violet ◽  
Fourier Transform Infrared ◽  
Ananas Comosus ◽  
Ftir Spectrometer ◽  
Model Isotherm ◽  
Scanning Electron

Industri tekstil semakin berkembang seiring dengan pertumbuhan penduduk di Indonesia. Selain memberikan manfaat, industri tekstil  memberikan dampak negatif bagi lingkungan akibat penggunaan zat warna sintetis, salah satunya yaitu methyl violet. Apabila limbah tersebut dibuang ke perairan akan menyebabkan rusaknya ekologi lingkungan dan ancaman bagi kesehatan manusia, karena sebagian besar zat warna bersifat sukar terurai (non-bidegradable) dan karsinogenik (Brono, 2010). Salah satu metode yang terbukti efektif untuk menghilangkan zat warna adalah adsorpsi menggunakan karbon aktif. Pada penelitian ini karbon aktif dibuat dari limbah daun nanas dengan aktivator ZnCl2 dan pemanasan gelombang mikro. Selanjutnya, karbon aktif tersebut dikarakteriasi morfologi permukaan menggunakan Scanning Electron Microscopy (SEM), luas permukaan menggunakan Surface Area Analyzer, dan analisis gugus fungsi menggunakan Fourier Transform Infrared (FTIR) spectrometer, dan digunakan untuk menjerap methyl violet di larutan. Hasil penelitian menunjukkan bahwa karbon aktif dari limbah daun nanas yang teraktivasi ZnCl2 menghasilkan pori yang lebih besar dibandingkan dengan karbon tanpa aktivasi serta memiliki gugus fungsi yang dapat menjerap methyl violet. Kondisi optimum untuk adsorpsi adalah pH 5, waktu kontak 90 menit, dan konsentrasi awal 500 mg/L. Model kesetimbangan yang sesuai yaitu menggunakan model isotherm freundlich.

MAGNETIC RESONANCE AND MAGNETIZATION IN THE TRIANGULAR ANTIFERROMAGNET CsCuCl3

1993 ◽  
Vol 07 (01n03) ◽  
pp. 1013-1015 ◽  
Author(s):  
W. PALME ◽  
H. KRIEGELSTEIN ◽  
G. GOJKOVIC ◽  
B. LÜTHI
Keyword(s):  
Magnetic Resonance ◽  
High Field ◽  
Sublattice Model ◽  
Detailed Model ◽  
Magnetization Measurements ◽  
Resonance Modes

Magnetic resonance and magnetization measurements are presented and discussed. It is shown that a previously used triangular three spin sublattice model can explain some experiments. However for the newly discovered high field resonance modes and magnetization experiments parallel to the c - axis a more detailed model with additional interactions is needed.

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