Mechanistical studies on the formation and destruction of carbon monoxide (CO), carbon dioxide (CO2), and carbon trioxide (CO3) in interstellar ice analog samples

2010 ◽  
Vol 12 (16) ◽  
pp. 4032 ◽  
Author(s):  
Chris J. Bennett ◽  
Corey S. Jamieson ◽  
Ralf I. Kaiser
Keyword(s):  
Carbon Dioxide ◽  
Carbon Monoxide ◽  
Interstellar Ice ◽  
Carbon Dioxide Co2

S. I. Engine Pollution Control Using Low-Cost Palletized Catalytic Converter

Volume 2 ◽  
2004 ◽  
Author(s):  
Madhuri Jakkaraju ◽  
Vasudha Patri
Keyword(s):  
Carbon Dioxide ◽  
Carbon Monoxide ◽  
Pollution Control ◽  
Noble Metals ◽  
Fossil Fuel ◽  
Catalytic Converter ◽  
Low Cost ◽  
Hydrocarbon Emissions ◽  
Oxides Of Nitrogen ◽  
Carbon Dioxide Co2

I. C. Engines consume large amounts of fossil fuel emitting harmful pollutants like carbon monoxide (CO), unburnt hydrocarbons (UBHC), and oxides of nitrogen (NOx). By using a catalytic converter (CC), the carbon monoxide, hydrocarbon emissions can be transformed into less harmful carbon dioxide (CO2) & water vapor (H2O). Currently available CC’s are using costly noble metals like platinum (pt), palladium (pd), rhodium (rh) etc., hence making them expensive. This paper deals with the use of low-cost palletized silver coated alumina as the catalyst element in a CC. In this study, alumina and silver were used in the ratio of 10:1. All tests have been conducted on a stationary S.I. Engine at a constant speed of 1500 r.p.m with and without CC. Also, the performance of the palletized CC in combination with promoters like Bismuth, Cerium and Lanthanum was tested which have shown better results than silver alone as the coating element. It has been experimentally determined that the CO emissions have dropped from 7.25 (% vol) to 3.03(% vol) and the HC values have reduced from 350 ppm to 190 ppm.

scholarly journals Determination of the optimal composition of mixed fuel based on the environmental performance of a diesel engine

2021 ◽  
Vol 1 (1) ◽  
pp. 14-22
Author(s):  
S.A. Plotnikov ◽  
◽  
Sh.V. Buzikov ◽  
I.S. Kozlov ◽  
◽  
...  
Keyword(s):  
Carbon Dioxide ◽  
Carbon Monoxide ◽  
Diesel Engine ◽  
Environmental Performance ◽  
Environmental Indicators ◽  
Effective Pressure ◽  
Bench Tests ◽  
Mixed Fuel ◽  
Unburned Hydrocarbons ◽  
Carbon Dioxide Co2

The use of rapeseed oil (RO) in tractor engines and other agricultural machinery in its pure form or a mixture of RO with diesel fuel (DF) imposes a number of limitations associated with some dif-ference in physical and chemical properties. Therefore, the most promising is the use of mixed fuel (MF) consisting of DF and RO. The purpose of these studies is to determine the optimal composi-tion of the MF, consisting of DF and RM by optimizing the approximated dependences of the envi-ronmental indicators of a diesel engine. To solve this problem, bench tests of the operation of the D-245.5S diesel engine (4ChN 11.0 / 12.5) were carried out. The following determined environmental performance indicators of a diesel engine are selected: soot (С), nitrogen oxides (NOx), unburned hydrocarbons (CxHy), carbon dioxide (CO2) and carbon monoxide (CO). The studies were carried out on various compositions of MF, consisting of 80% DF and 20% RO, 55% DF and 45% RO, 20% DF and 80% RO by weight, respectively. As a result of the bench tests, two load characteris-tics were obtained, the one at a speed of n = 1400 min-1 corresponding to the value of the maximum torque, and the second at a speed of n = 1800 min-1 corresponding to the value of the rated power, as well as the external speed characteristic of the D-245.5S tractor diesel engine (4ChN 11.0 / 12.5). The analysis of the obtained experimental data revealed the dependence of environmental indicators on the rotational speed of the diesel engine crankshaft, the average effective pressure and the addi-tion of RO in MF by weight. Using the least squares method, the approximated mathematical de-pendences of the ecological indicators of a diesel engine are determined. The analysis of the ob-tained dependencies showed that: the increase in the crankshaft speed n, the proportion of RO in MF and a decrease in the average effective pressure pe, leads to a decrease in soot С to 4.0%, nitro-gen oxides NOx to 100.0 ppm, unburned hydrocarbons CxHy to 1.0 ppm, carbon dioxide, CO2 up to 2%, and an increase in carbon monoxide CO up to 0.16%. As a result of solving the obtained system of equations for the approximated dependences of environmental indicators, the optimal addition of RO to MF of up to 35% by weight was determined.

scholarly journals Performance and exhaust gases of a diesel engine using different magnetic treatments of the fuel

2020 ◽  
Vol 14 (1) ◽  
pp. 6285-6294
Author(s):  
R. Arias Gilart ◽  
M. R. B. Ungaro ◽  
C. E. A. Rodríguez ◽  
J. F. F. Hernández ◽  
M. C. Sofia ◽  
...  
Keyword(s):  
Carbon Dioxide ◽  
Carbon Monoxide ◽  
Diesel Engine ◽  
Compression Ratio ◽  
Engine Speed ◽  
Magnetic Treatment ◽  
Static Magnetic Fields ◽  
Mass Consumption ◽  
Exhaust Gases ◽  
Carbon Dioxide Co2

In this research, different magnetic treatments were applied to diesel fuel using static magnetic fields of 0.36T of magnetic induction. The magnetic conditioners (MCs) were installed in different positions of the fuel lines in the engine and the magnetic treatment of the diesel was also carried out before introducing it into the engine tanks. The study was conducted using a four-stroke, two-cylinder, Lister Petter (LPWS2) engine with a compression ratio of 23.5:1 and a constant engine speed of 1500 rpm. The emissions of carbon monoxide (CO), carbon dioxide (CO2), oxygen (O2), nitrogen oxides and the temperature of the exhaust gases and the mass consumption of fuel were measured. The highest levels of reduction were achieved with the magnetic treatments that locate the MC directly in the engine's pipes. As the number of MC in the engine pipes increases, the emissions of polluting gases decrease. With the treatment that locates one MC in front of each injector, two MC at the entrance of the filter and two MC in the return of fuel were able to increase the O2 emissions by 6.9% and decrease the CO emissions in about 21.3% in the last load of the generator set. With this treatment a decrease in fuel consumption of 4.89% to 80% of engine load was obtained.

scholarly journals Elevated Carbon Monoxide to Carbon Dioxide Ratio in the Exhaled Breath of Mice Treated With a Single Dose of Lipopolysaccharide

2014 ◽  
Vol 1 (2) ◽  
Author(s):  
Arash Ghalyanchi Langeroudi ◽  
Charlotte M. Hirsch ◽  
Azadeh Shojaee Estabragh ◽  
Simone Meinardi ◽  
Donald R. Blake ◽  
...  
Keyword(s):  
Carbon Dioxide ◽  
Carbon Monoxide ◽  
Resistant Mutant ◽  
Heme Oxygenase 1 ◽  
Exhaled Breath ◽  
Adult Mice ◽  
Endogenous Production ◽  
Experimental Mouse ◽  
Carbon Dioxide Co2 ◽  
Different Doses

Background.  Analysis of volatile organic chemicals in breath holds promise for noninvasive diagnosis and monitoring of patients, but investigation of this in experimental mouse models has been limited. Of particular interest is endogenous production of carbon monoxide as a biomarker of inflammation and, more particularly, during sepsis. Methods.  Using a nose-only collection procedure for unanesthetized individual adult mice and sensitive gas chromatography of carbon monoxide (CO) and carbon dioxide (CO2) of sampled breath, we investigated the responses of mice to one-time injections with different doses of purified Escherichia coli lipopolysaccharide. Two strains of mice were examined: BALB/c and C3H, including an endotoxin-resistant mutant (HeJ) as well as the wild type (HOuJ). Results.  The CO to CO2 ratio increased in a dose-responsive manner within hours in treated BALC/c mice but not control mice. The CO/CO2 values declined to the range of control mice within 48–72 h after the injection of lipopolysaccharide. Breath CO/CO2 values correlated with systemic inflammation biomarkers in serum and heme oxygenase-1 gene expression in blood. C3H/HOuJ mice, but not the HeJ mice, had similar increases of the CO/CO2 ratio in response to the endotoxin. Conclusions.  Carbon monoxide concentrations in exhaled breath of at least 2 strains of mice increase in response to single injections of endotoxin. The magnitude of increase was similar to what was observed with a bacteremia model. These findings with an experimental model provide a rationale for further studies of normalized CO concentrations in human breath as an informative biomarker for staging and monitoring of sepsis.

scholarly journals Carbon monoxide, methane and carbon dioxide columns retrieved from SCIAMACHY by WFM-DOAS: year 2003 initial data set

2005 ◽  
Vol 5 (2) ◽  
pp. 1943-1971 ◽  
Author(s):  
M. Buchwitz ◽  
R. de Beek ◽  
S. Noël ◽  
J. P. Burrows ◽  
H. Bovensmann ◽  
...  
Keyword(s):  
Carbon Dioxide ◽  
Carbon Monoxide ◽  
Near Infrared ◽  
Trace Gases ◽  
Central Africa ◽  
South East Asia ◽  
Data Set ◽  
Model Simulations ◽  
Mixing Ratios ◽  
Carbon Dioxide Co2

Abstract. The near-infrared nadir spectra measured by SCIAMACHY on-board ENVISAT contain information on the vertical columns of important atmospheric trace gases such as carbon monoxide (CO), methane (CH4), and carbon dioxide (CO2). The scientific algorithm WFM-DOAS has been used to retrieve this information. For CH4 and CO2 also column averaged mixing ratios (XCH4 and XCO2) have been determined by simultaneous measurements of the dry air mass. All available spectra of the year 2003 have been processed. We describe the algorithm versions used to generate the data (v0.4; for methane also v0.41) and show comparisons of monthly averaged data over land with global measurements (CO from MOPITT) and models (for CH4 and CO2). We show that enhanced concentrations of CO resulting from biomass burning have been detected which are in reasonable agreement with MOPITT. The measured XCH4 is enhanced over India, south-east Asia, and central Africa in September/October 2003 in line with model simulations where they result from surface sources of methane such as rice fields and wetlands. In qualitative agreement with model simulations the XCO2 measurements over the northern hemisphere show the lowest mixing ratios around July due to uptake of CO2 by the growing vegetation of the land biosphere. We also identified potential problems such as a too low inter-hemispheric gradient for CO, a time dependent bias of the methane columns on the order of a few percent, and a few percent too high CO2 over parts of the Sahara.

C3 Production from CO2 Reduction by Concerted *CO Trimerization on Single Atom Catalyst

2022 ◽  
Author(s):  
Ling Chen ◽  
Cheng Tang ◽  
Yao Zheng ◽  
Egill Skúlason ◽  
Yan Jiao
Keyword(s):  
Carbon Dioxide ◽  
Carbon Monoxide ◽  
Co2 Reduction ◽  
Single Atom ◽  
Carbon Dioxide Co2

The direct electroreduction of carbon dioxide (CO2) and carbon monoxide (CO) to C3 products is challenging. The main reason is the competitive C2 production resulting from a traditional sequential C–C...

Use of Carbon Monoxide Combined with Carbon Dioxide for Modified Atmosphere Packaging of Pre- and Postrigor Fresh Pork Sausage To Improve Shelf Life

2007 ◽  
Vol 70 (4) ◽  
pp. 937-942 ◽  
Author(s):  
ANGELA LAURY ◽  
JOSEPH G. SEBRANEK
Keyword(s):  
Carbon Dioxide ◽  
Carbon Monoxide ◽  
Lipid Oxidation ◽  
Shelf Life ◽  
Modified Atmosphere Packaging ◽  
Anaerobic Growth ◽  
Modified Atmosphere ◽  
Pork Sausage ◽  
Carbon Dioxide Co2 ◽  
Cooked Color

Fresh pre- and postrigor pork sausage patties were manufactured in the Iowa State University Meat Laboratory and packaged either in modified atmosphere (MAP) with 0.4% carbon monoxide (CO) and 99.6% carbon dioxide (CO2) or on foam trays overwrapped with oxygen-permeable film (OW). Packages were stored at 2 to 4°C under fluorescent lights for up to 31 days. Aerobic, anaerobic, and psychrotrophic plate counts, raw and cooked color, purge, and lipid oxidation were measured during storage. Results indicated that both pork sausage products in MAP had lower aerobic and psychrotrophic counts and less lipid oxidation throughout storage (P < 0.05). Raw color of both products in MAP was redder than the OW patties (P < 0.05), but the prerigor pork sausage in MAP benefited more from the CO atmosphere in terms of raw color than the postrigor pork sausage in MAP. Cooked color of the prerigor pork sausage in MAP was significantly redder than cooked color of the postrigor pork sausage. Both pork sausage products in MAP were also lighter (L* value) than the OW patties for raw and cooked color. Therefore, the combination of CO and CO2 in MAP was beneficial in extending the shelf life of preand postrigor fresh pork sausage by reducing aerobic and psychrotrophic microbial growth and improving oxidative stability and color, compared to conventional OW packaging. However, increased purge, increased anaerobic growth, and changes in cooking behavior were also observed for the products in MAP during storage (P < 0.05).

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