Luminescence, energy-transfer and tunable color properties of single-component Tb3+ and/or Sm3+ doped NaGd(WO4)2 phosphors with UV excitation for use as WLEDs

RSC Advances ◽  
2014 ◽  
Vol 4 (102) ◽  
pp. 58708-58716 ◽  
Author(s):  
Yan Liu ◽  
Guixia Liu ◽  
Xiangting Dong ◽  
Jinxian Wang ◽  
Wensheng Yu

Tb3+ and/or Sm3+ codoped NaGd(WO4)2 microcrystals were prepared and energy transfer mechanisms of WO42− → Sm3+ and Tb3+ → Sm3+ were studied. The color-tunable emissions are investigated, for nUV-LED applications.

Crystals ◽  
2020 ◽  
Vol 10 (4) ◽  
pp. 285 ◽  
Author(s):  
M. Kowalczyk ◽  
T.F. Ramazanova ◽  
V.D. Grigoryeva ◽  
V.N. Shlegel ◽  
M. Kaczkan ◽  
...  

The spectroscopic properties of Eu3+ doped Bi12GeO20 (BGO) sillenite bulk crystals that were grown by the low-thermal-gradient Czochralski technique (LTG Cz) were investigated. The absorption spectra and the emission properties have been measured at room temperature (300 K) and at 10 K. Luminescence was observed both due to the direct Eu3+ ion excitation, as well as under UV excitation due to the energy transfer between Bi3+ and Eu3+ ions. Bi3+ → Eu3+ energy transfer mechanisms in Eu3+:BGO doped host were investigated. The Ωλ parameters, as well as radiative lifetimes, were calculated based upon the Judd-Ofelt formalism. The branching ratios and electric dipole transition probabilities were also determined, based upon the obtained experimental results. Luminescence has been observed from the 5D0,1,2 levels of Eu3+, with emissions from the 5D0 level being the strongest. The strongest observed luminescence band corresponds to the 5D0 → 7F0 transition at 578.7 nm. Reasons for the strong presence of the theoretically forbidden 5D0 → 7F0 emission were investigated.


RSC Advances ◽  
2016 ◽  
Vol 6 (34) ◽  
pp. 28887-28894 ◽  
Author(s):  
Ruiyu Mi ◽  
Jian Chen ◽  
Yan-gai Liu ◽  
Minghao Fang ◽  
Lefu Mei ◽  
...  

The PL spectra of ScPO4:0.03Tb3+, yEu3+ (y = 0–0.05) phosphors under N-UV excitation (λex = 370 nm) and the tunable luminescence.


RSC Advances ◽  
2015 ◽  
Vol 5 (119) ◽  
pp. 97995-98003 ◽  
Author(s):  
Yan Liu ◽  
Yanxia Liu ◽  
Guixia Liu ◽  
Xiangting Dong ◽  
Jinxian Wang

A series of novel, color-tunable, single-component NaLa(WO4)2:Er3+,Eu3+ phosphors were prepared by a one-step hydrothermal method. The energy transfer mechanism was studied, and color-tunable emissions in NaLa(WO4)2 are realized.


Processes ◽  
2021 ◽  
Vol 9 (2) ◽  
pp. 312
Author(s):  
Yusuf Tutel ◽  
Gökhan Sevinç ◽  
Betül Küçüköz ◽  
Elif Akhuseyin Yildiz ◽  
Ahmet Karatay ◽  
...  

Meso-substituted borondipyrromethene (BODIPY)-porphyrin compounds that include free base porphyrin with two different numbers of BODIPY groups (BDP-TTP and 3BDP-TTP) were designed and synthesized to analyze intramolecular energy transfer mechanisms of meso-substituted BODIPY-porphyrin dyads and the effect of the different numbers of BODIPY groups connected to free-base porphyrin on the energy transfer mechanism. Absorption spectra of BODIPY-porphyrin conjugates showed wide absorption features in the visible region, and that is highly valuable to increase light-harvesting efficiency. Fluorescence spectra of the studied compounds proved that BODIPY emission intensity decreased upon the photoexcitation of the BODIPY core, due to the energy transfer from BODIPY unit to porphyrin. In addition, ultrafast pump-probe spectroscopy measurements indicated that the energy transfer of the 3BDP-TTP compound (about 3 ps) is faster than the BDP-TTP compound (about 22 ps). Since the BODIPY core directly binds to the porphyrin unit, rapid energy transfer was seen for both compounds. Thus, the energy transfer rate increased with an increasing number of BODIPY moiety connected to free-base porphyrin.


2021 ◽  
Vol 9 (9) ◽  
pp. 3257-3263
Author(s):  
Jianwei Liu ◽  
Zhimin Ma ◽  
Zewei Li ◽  
Yan Liu ◽  
Xiaohua Fu ◽  
...  

Two isomers pDCzPyCN and oDCzPyCN are designed and synthesized. Amazingly, oDCzPyCN manifest white afterglow at room temperature. This is the first time that single-component white afterglow has finally been realized.


2021 ◽  
Vol 6 (2) ◽  
Author(s):  
Bo Jin ◽  
Sean Symon ◽  
Simon J. Illingworth

Materials ◽  
2021 ◽  
Vol 14 (7) ◽  
pp. 1740
Author(s):  
Konrad Jakubowski ◽  
Manfred Heuberger ◽  
Rudolf Hufenus

The increasing interest in luminescent waveguides, applied as light concentrators, sensing elements, or decorative illuminating systems, is fostering efforts to further expand their functionality. Yarns and textiles based on a combination of distinct melt-spun polymer optical fibers (POFs), doped with individual luminescent dyes, can be beneficial for such applications since they enable easy tuning of the color of emitted light. Based on the energy transfer occurring between differently dyed filaments within a yarn or textile, the collective emission properties of such assemblies are adjustable over a wide range. The presented study demonstrates this effect using multicolor, meltspun, and photoluminescent POFs to measure their superimposed photoluminescent emission spectra. By varying the concentration of luminophores in yarn and fabric composition, the overall color of the resulting photoluminescent textiles can be tailored by the recapturing of light escaping from individual POFs. The ensuing color space is a mean to address the needs of specific applications, such as decorative elements and textile illumination by UV down-conversion.


2021 ◽  
Author(s):  
Peng Du ◽  
Laihui Luo ◽  
Yafei Hou ◽  
Weiping Li

Rational control of thermal quenching performance is crucial for achieving high quality luminescent thermometer. Herein, we report the Tb3+/Yb3+-coactivated Y2Mo3O12 (YMO) negative thermal expansion (NTE) microparticles with color-tunable emissions. Irradiated...


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