Highly conductive carbon–CoO hybrid nanostructure arrays with enhanced electrochemical performance for asymmetric supercapacitors

2014 ◽  
Vol 2 (30) ◽  
pp. 11776-11783 ◽  
Author(s):  
Hai Wang ◽  
Chen Qing ◽  
Junling Guo ◽  
A. A. Aref ◽  
Daming Sun ◽  
...  

Highly conductive carbon–CoO nanowire array electrodes on 3D nickel foam were designed with ultrahigh specific capacitance (3282.2 F g−1), approaching the CoO theoretical value. Assembled into an asymmetric supercapacitor, the energy density is ∼58.9 W h kg−1, a record among Co-based supercapacitors.

Energies ◽  
2019 ◽  
Vol 12 (6) ◽  
pp. 1143 ◽  
Author(s):  
Anil Yedluri ◽  
Tarugu Anitha ◽  
Hee-Je Kim

Hierarchical NiMoO4/NiMoO4 nanoflowers were fabricated on highly conductive flexible nickel foam (NF) substrates using a facile hydrothermal method to achieve rapid charge-discharge ability, high energy density, long cycling lifespan, and higher flexibility for high-performance supercapacitor electrode materials. The synthesized composite electrode material, NF/NiMoO4/NiMoO4 with a nanoball-like NF/NiMoO4 structure on a NiMoO4 surface over a NF substrate, formed a three-dimensional interconnected porous network for high-performance electrodes. The novel NF/NiMoO4/NiMoO4 nanoflowers not only enhanced the large surface area and increased the electrochemical activity, but also provided an enhanced rapid ion diffusion path and reduced the charge transfer resistance of the entire electrode effectively. The NF/NiMoO4/NiMoO4 composite exhibited significantly improved supercapacitor performance in terms of a sustained cycling life, high specific capacitance, rapid charge-discharge capability, high energy density, and good rate capability. Electrochemical analysis of the NF/NiMoO4/NiMoO4 nanoflowers fabricated on the NF substrate revealed ultra-high electrochemical performance with a high specific capacitance of 2121 F g−1 at 12 mA g−1 in a 3 M KOH electrolyte and 98.7% capacitance retention after 3000 cycles at 14 mA g−1. This performance was superior to the NF/NiMoO4 nanoball electrode (1672 F g−1 at 12 mA g−1 and capacitance retention 93.4% cycles). Most importantly, the SC (NF/NiMoO4/NiMoO4) device displayed a maximum energy density of 47.13 W h kg−1, which was significantly higher than that of NF/NiMoO4 (37.1 W h kg−1). Overall, the NF/NiMoO4/NiMoO4 composite is a suitable material for supercapacitor applications.


2017 ◽  
Vol 46 (38) ◽  
pp. 12876-12883 ◽  
Author(s):  
Saurabh Singh ◽  
Nanasaheb M. Shinde ◽  
Qi Xun Xia ◽  
Chandu V. V. M. Gopi ◽  
Je Moon Yun ◽  
...  

A NiCoMn-LDH (10%)//rGO asymmetric supercapacitor device with 574 Wh kg−1 energy density at 749.9 W kg−1 power density and 89.4% retention even after 2500 cycles has been explored.


2014 ◽  
Vol 2 (39) ◽  
pp. 16723-16730 ◽  
Author(s):  
Arvinder Singh ◽  
Alexander J. Roberts ◽  
Robert C. T. Slade ◽  
Amreesh Chandra

A high-performance asymmetric supercapacitor was fabricated using MWCNTs/NiS composite and GNPs as electrodes, exhibiting high specific capacitance of ∼181 F g−1 at 1 A g−1 current density and excellent cyclic stability with 92% retention after 1000 cycles at 2 A g−1 current density.


RSC Advances ◽  
2021 ◽  
Vol 11 (27) ◽  
pp. 16161-16172
Author(s):  
Jing Jin ◽  
Jie Ding ◽  
Xing Wang ◽  
Congcong Hong ◽  
Huaping Wu ◽  
...  

A NiCo2O4/MnO2 heterostructure with high mass loading MnO2 microflowers was built on the surface of 3D graphene/nickel foam for the preparation of an asymmetric supercapacitor with splended energy density (45.9 Wh kg−1).


2021 ◽  
Vol 16 (6) ◽  
pp. 891-904
Author(s):  
Xiang-Sen Meng ◽  
Jun Xiang ◽  
Nan Bu ◽  
Yan Guo ◽  
Sroeurb Loy ◽  
...  

In this work, Co3S4/NiCo2S4 nano-arrays electrode with Co3S4 nanocones and NiCo2S4 nanosheets interlaced arrangement are prepared by the promising hydrothermal method. Compared with single Co3S4/NF or NiCo2S4/NF electrode, the prepared Co3S4/NiCo2S4/NF electrode exhibits excellent specific capacitance. At a current density of 2 mA cm−2, the surface capacitance is as high as 9036 mF cm−2, and it still maintains a surface capacitance of 5664 mF cm−2 at a current density of 8 mA cm−2. Co3S4/NiCo2S4/NF||ASC has a high electrochemical performance with a maximum energy density of 0.62 Wh cm−3 and a power density of 15.94 W cm−3. At a current density of 5 mA cm−2, the capacity retention rate is 83.75% after 3000 cycles.


RSC Advances ◽  
2021 ◽  
Vol 11 (50) ◽  
pp. 31557-31565
Author(s):  
Rodrigo Henríquez ◽  
Alifhers S. Mestra-Acosta ◽  
Eduardo Muñoz ◽  
Paula Grez ◽  
Elena Navarrete-Astorga ◽  
...  

This work presents for the first time a CdCO3/CdO/Co3O4@nickel foam based supercapacitor with high both specific capacitance and energy density, a widespread potential window and a long cycle life.


2016 ◽  
Vol 1 (2) ◽  
pp. 150-155 ◽  
Author(s):  
Ruizhi Li ◽  
Zhijun Lin ◽  
Xin Ba ◽  
Yuanyuan Li ◽  
Ruimin Ding ◽  
...  

An integrated (Cu,Ni)O mesoporous nanowire array that delivers a high specific capacitance has been used to construct high-performance aqueous asymmetric supercapacitors of (Cu,Ni)O(+)//AC(−).


RSC Advances ◽  
2015 ◽  
Vol 5 (52) ◽  
pp. 41721-41728 ◽  
Author(s):  
Jia-Jia Li ◽  
Mao-Cheng Liu ◽  
Ling-Bin Kong ◽  
Dan Wang ◽  
Yu-Mei Hu ◽  
...  

Ni3(PO4)2@GO and Fe2O3@GO have been successfully synthesized as electrode materials, and they have been used to assemble an asymmetric supercapacitor (Fe2O3@GO//Ni3(PO4)2@GO), which exhibited a high energy density.


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