Butane detection: W-doped TiO2 nanoparticles for a butane gas sensor with high sensitivity and fast response/recovery

RSC Advances ◽  
2015 ◽  
Vol 5 (117) ◽  
pp. 96539-96546 ◽  
Author(s):  
Xu Liu ◽  
Kaimeng Pan ◽  
Lihong Wang ◽  
Chengjun Dong ◽  
Xuechun Xiao ◽  
...  

Well crystallized W-doped anatase TiO2 nanoparticles synthesized by a simple non-aqueous sol–gel route were applied as a sensing layer for a butane gas sensor and showed good gas response performance for butane gas.

2021 ◽  
Vol 16 (1) ◽  
pp. 1-5
Author(s):  
Chuansheng Wu ◽  
Yuyue Li ◽  
Lingling Qi ◽  
Lingjiang Zhang ◽  
Hao Xu

Hierarchical flower-like WO3 · H2O microspheres assembled by nanosheets were successfully prepared through a simple hydrothermal route. Field emission scanning electron microscopy results indicate that the flower-like WO3 · H2O microspheres are composed of numerous nanosheets, which are interconnected with each other in the sphere shape. In addition, the gas sensing properties of the hierarchical WO3 · H2O microspheres were investigated. It is found that the gas sensor based on the hierarchical WO3 · H2O architectures exhibits excellent gas sensing properties towards H2S gas, including high gas response and fast response/recovery speed.


2017 ◽  
Vol 28 (13) ◽  
pp. 9969-9973 ◽  
Author(s):  
Han Wang ◽  
Shiyuan Wei ◽  
Fengqin Zhang ◽  
Yu Li ◽  
Li Liu ◽  
...  

2017 ◽  
Vol 238 ◽  
pp. 264-273 ◽  
Author(s):  
Yuxiu Li ◽  
Nan Chen ◽  
Dongyang Deng ◽  
Xinxin Xing ◽  
Xuechun Xiao ◽  
...  

Catalysts ◽  
2021 ◽  
Vol 11 (2) ◽  
pp. 235
Author(s):  
Hayette Benkhennouche-Bouchene ◽  
Julien G. Mahy ◽  
Cédric Wolfs ◽  
Bénédicte Vertruyen ◽  
Dirk Poelman ◽  
...  

TiO2 prepared by a green aqueous sol–gel peptization process is co-doped with nitrogen and zirconium to improve and extend its photoactivity to the visible region. Two nitrogen precursors are used: urea and triethylamine; zirconium (IV) tert-butoxide is added as a source of zirconia. The N/Ti molar ratio is fixed regardless of the chosen nitrogen precursor while the quantity of zirconia is set to 0.7, 1.4, 2, or 2.8 mol%. The performance and physico-chemical properties of these materials are compared with the commercial Evonik P25 photocatalyst. For all doped and co-doped samples, TiO2 nanoparticles of 4 to 8 nm of size are formed of anatase-brookite phases, with a specific surface area between 125 and 280 m2 g−1 vs. 50 m2 g−1 for the commercial P25 photocatalyst. X-ray photoelectron (XPS) measurements show that nitrogen is incorporated into the TiO2 materials through Ti-O-N bonds allowing light absorption in the visible region. The XPS spectra of the Zr-(co)doped powders show the presence of TiO2-ZrO2 mixed oxide materials. Under visible light, the best co-doped sample gives a degradation of p-nitrophenol (PNP) equal to 70% instead of 25% with pure TiO2 and 10% with P25 under the same conditions. Similarly, the photocatalytic activity improved under UV/visible reaching 95% with the best sample compared to 50% with pure TiO2. This study suggests that N/Zr co-doped TiO2 nanoparticles can be produced in a safe and energy-efficient way while being markedly more active than state-of-the-art photocatalytic materials under visible light.


2005 ◽  
Vol 486-487 ◽  
pp. 485-488 ◽  
Author(s):  
Hong Quang Nguyen ◽  
Mai Van Trinh ◽  
Jeung Soo Huh

The effect of operating temperature on characteristics of single-walled carbon nanotubes (SWNT) based gas sensor was investigated. SWNT-based sensor was fabricated from SWNT powder (Iljin Nanotech, Korea) by screen-printing method. SWNT powder (30 mg, AP grade) was dispersed into 0.78 gram a-terpineol (Aldrich) by ultrasonic vibration for 1 hour then stirred manually for 1 hour to increase adhesion. From this condensed solution, a thick film of SWNT was printed onto alumina substrates. The film then was sintered at 300oC for 2 hours to remove residual impurities. Upon exposure to some gases such as nitrogen, ammonia or nitric oxide, resistance of the sensor dramatically changes due to gas adsorption. In our experiments, SWNT-based sensor was employed to detect NH3 gas in N2 ambience. After saturated of N2, the sensor exposes to NH3 with various concentrations (from 5 ppm to 100 ppm, diluted by N2 as carrier gas). This sensor exhibits a fast response, high sensitivity but slow recovery at room temperature. By heating at high temperature and increasing the flow-rate of carrier gas, NH3 gas desorbs easily and recovery of the sensor improved. The heating also influenced the characteristics of sensors such as response and reproducibility. Other special changes in electric property of SWNT-based sensor caused by heating are also discussed.


2018 ◽  
Vol 43 (50) ◽  
pp. 22746-22755 ◽  
Author(s):  
Zhijie Li ◽  
Shengnan Yan ◽  
Zhonglin Wu ◽  
Hao Li ◽  
Junqiang Wang ◽  
...  

Author(s):  
Monika Kwoka ◽  
Michal A. Borysiewicz ◽  
Pawel Tomkiewicz ◽  
Anna Piotrowska ◽  
Jacek Szuber

In this paper a novel type of a highly sensitive gas sensor device based on the surface photovoltage effect is described. The developed surface photovoltage gas sensor is based on a reverse Kelvin probe approach. As the active gas sensing electrode the porous ZnO nanostructured thin films are used deposited by the direct current (DC) reactive magnetron sputtering method exhibiting the nanocoral surface morphology combined with an evident surface nonstoichiometry related to the unintentional surface carbon and water vapor contaminations. Among others, the demonstrated SPV gas sensor device exhibits a high sensitivity of 1 ppm to NO2 with a signal to noise ratio of about 50 and a fast response time of several seconds under the room temperature conditions.


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