Promotional effect of copper(ii) on an activated carbon supported low content bimetallic gold–cesium(i) catalyst in acetylene hydrochlorination

RSC Advances ◽  
2015 ◽  
Vol 5 (123) ◽  
pp. 101427-101436 ◽  
Author(s):  
Jia Zhao ◽  
Shanchuan Gu ◽  
Xiaolong Xu ◽  
Tongtong Zhang ◽  
Xiaoxia Di ◽  
...  

Cu-added low content AuCs/AC worked as highly active, stable and cost-effective catalyst for acetylene hydrochlorination. Our findings suggest that the AuCuCs/AC catalyst can be envisioned as a viable alternative to commercial toxic HgCl2for acetylene hydrochlorination.

2020 ◽  
Author(s):  
Qiang Zhang ◽  
Xiaohong Liu ◽  
Jiannan Luo ◽  
Cunhua Ma ◽  
Caixia Xu

Heterogeneous catalysts based on mercury are found to be highly active for the acetylene hydration reaction with very high yield of acetaldehyde, but serious harm of toxicity limits its application....


2018 ◽  
Vol 8 (11) ◽  
pp. 2901-2908 ◽  
Author(s):  
Yuanyuan Zhai ◽  
Jia Zhao ◽  
Xiaoxia Di ◽  
Shuxia Di ◽  
Bolin Wang ◽  
...  

Non-mercuric catalysts in acetylene hydrochlorination reaction have been gained much attention.


RSC Advances ◽  
2015 ◽  
Vol 5 (9) ◽  
pp. 6925-6931 ◽  
Author(s):  
Jia Zhao ◽  
Tongtong Zhang ◽  
Xiaoxia Di ◽  
Jiangtao Xu ◽  
Jinhui Xu ◽  
...  

In the challenging acetylene hydrochlorination to vinyl chloride over Au-based catalysts, Au–CsIcatalysts are substantially more active and stable than their monometallic counterparts.


2002 ◽  
Vol 2 (1) ◽  
pp. 233-240 ◽  
Author(s):  
J. Cromphout ◽  
W. Rougge

In Harelbeke a Water Treatment Plant with a capacity of 15,000 m3/day, using Schelde river water has been in operation since April 1995. The treatment process comprises nitrification, dephosphatation by direct filtration, storage into a reservoir, direct filtration, granular activated carbon filtration and disinfection. The design of the three-layer direct filters was based on pilot experiments. The performance of the plant during the five years of operation is discussed. It was found that the removal of atrazin by activated carbon depends on the water temperature.


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