Advanced N-doped mesoporous molybdenum disulfide nanosheets and the enhanced lithium-ion storage performance

2016 ◽  
Vol 4 (4) ◽  
pp. 1440-1445 ◽  
Author(s):  
Si Qin ◽  
Weiwei Lei ◽  
Dan Liu ◽  
Ying Chen

With the increasing interest in two-dimensional van der Waals materials, molybdenum disulfide (MoS2) has emerged as a promising material for electronic and energy storage devices.

2020 ◽  
Author(s):  
Yamin Zhang ◽  
Zhongpu Wang ◽  
Deping Li ◽  
Qing Sun ◽  
Kangrong Lai ◽  
...  

<p></p><p>Porous carbon has attracted extensive attentions as the electrode material for various energy storage devices considering its advantages like high theoretical capacitance/capacity, high conductivity, low cost and earth abundant inherence. However, there still exists some disadvantages limiting its further applications, such as the tedious fabrication process, limited metal-ion transport kinetics and undesired structure deformation at harsh electrochemical conditions. Herein, we report a facile strategy, with calcium gluconate firstly reported as the carbon source, to fabricate ultrathin porous carbon nanosheets. <a>The as-prepared Ca-900 electrode delivers excellent K-ion storage performance including high reversible capacity (430.7 mAh g<sup>-1</sup>), superior rate capability (154.8 mAh g<sup>-1</sup> at an ultrahigh current density of 5.0 A g<sup>-1</sup>) and ultra-stable long-term cycling stability (a high capacity retention ratio of ~81.2% after 4000 cycles at 1.0 A g<sup>-1</sup>). </a>Similarly, when being applied in Zn-ion capacitors, the Ca-900 electrode also exhibits an ultra-stable cycling performance with ~90.9% capacity retention after 4000 cycles at 1.0 A g<sup>-1</sup>, illuminating the applicable potentials. Moreover, the origin of the fast and smooth metal-ion storage is also revealed by carefully designed consecutive CV measurements. Overall, considering the facile preparation strategy, unique structure, application flexibility and in-depth mechanism investigations, this work will deepen the fundamental understandings and boost the commercialization of high-efficient energy storage devices like potassium-ion/sodium-ion batteries, zinc-ion batteries/capacitors and aluminum-ion batteries.</p><br><p></p>


Materials ◽  
2021 ◽  
Vol 14 (14) ◽  
pp. 4000
Author(s):  
Eunhwan Kim ◽  
Juyeon Han ◽  
Seokgyu Ryu ◽  
Youngkyu Choi ◽  
Jeeyoung Yoo

For decades, improvements in electrolytes and electrodes have driven the development of electrochemical energy storage devices. Generally, electrodes and electrolytes should not be developed separately due to the importance of the interaction at their interface. The energy storage ability and safety of energy storage devices are in fact determined by the arrangement of ions and electrons between the electrode and the electrolyte. In this paper, the physicochemical and electrochemical properties of lithium-ion batteries and supercapacitors using ionic liquids (ILs) as an electrolyte are reviewed. Additionally, the energy storage device ILs developed over the last decade are introduced.


Author(s):  
Yunping Wu ◽  
Wei Wei ◽  
Tianyi Ding ◽  
Sheng Chen ◽  
Rui Zhai ◽  
...  

Two-dimensional (2D) heterostructures combine the advantageous features of different 2D materials and represent advanced electrode architectures for development of efficient energy storage devices. However, the common 2D heterostructures made by...


Physchem ◽  
2021 ◽  
Vol 1 (1) ◽  
pp. 26-44
Author(s):  
Chiara Ferrara ◽  
Riccardo Ruffo ◽  
Piercarlo Mustarelli

Extended interphases are playing an increasingly important role in electrochemical energy storage devices and, in particular, in lithium-ion and lithium metal batteries. With this in mind we initially address the differences between the concepts of interface and interphase. After that, we discuss in detail the mechanisms of solid electrolyte interphase (SEI) formation in Li-ion batteries. Then, we analyze the methods for interphase characterization, with emphasis put on in-situ and operando approaches. Finally, we look at the near future by addressing the issues underlying the lithium metal/electrolyte interface, and the emerging role played by the cathode electrolyte interphase when high voltage materials are employed.


RSC Advances ◽  
2019 ◽  
Vol 9 (60) ◽  
pp. 35045-35049
Author(s):  
Xu Chen ◽  
Jian Zhou ◽  
Jiarui Li ◽  
Haiyan Luo ◽  
Lin Mei ◽  
...  

High-performance lithium ion batteries are ideal energy storage devices for both grid-scale and large-scale applications.


2020 ◽  
Vol 11 ◽  
pp. 662-670
Author(s):  
Matangi Sricharan ◽  
Bikesh Gupta ◽  
Sreejesh Moolayadukkam ◽  
H S S Ramakrishna Matte

MoO3 is a versatile two-dimensional transition metal oxide having applications in areas such as energy storage devices, electronic devices and catalysis. To efficiently utilize the properties of MoO3 arising from its two-dimensional nature exfoliation is necessary. In this work, the exfoliation of MoO3 is carried out in 2-butanone for the first time. The achieved concentration of the dispersion is about 0.57 mg·mL−1 with a yield of 5.7%, which are the highest values reported to date. These high values of concentration and yield can be attributed to a favorable matching of energies involved in exfoliation and stabilization of MoO3 nanosheets in 2-butanone. Interestingly, the MoO3 dispersion in 2-butanone retains its intrinsic nature even after exposure to sunlight for 24 h. The composites of MoO3 nanosheets were used as an electrode material for supercapacitors and showed a high specific capacitance of 201 F·g−1 in a three-electrode configuration at a scan rate of 50 mV·s−1.


Nanoscale ◽  
2022 ◽  
Author(s):  
Zhiyu Zhou ◽  
Zexiang Chen ◽  
Yang Zhao ◽  
Huifang Lv ◽  
Hualiang Wei ◽  
...  

In recent years and following the progress made in lithium-ion battery technology, substantial efforts have been devoted to developing practical lithium-sulfur (Li–S) batteries for next-generation commercial energy storage devices. The...


2020 ◽  
Vol 142 (46) ◽  
pp. 19570-19578
Author(s):  
Minghao Yu ◽  
Naisa Chandrasekhar ◽  
Ramya Kormath Madam Raghupathy ◽  
Khoa Hoang Ly ◽  
Haozhe Zhang ◽  
...  

2021 ◽  
Vol 1 (3) ◽  
pp. 49-56
Author(s):  
S.M. Zuyev ◽  
◽  
R.A. Maleyev ◽  
YU.M. Shmatkov ◽  
M.YU. Khandzhalov ◽  
...  

This article provides a comparative analysis of various energy storage devices. A detailed review and analysis of molecular energy storage units is carried out, their main characteristics and parame-ters, as well as their application areas, are determined. The main types of molecular energy storage are determined: electric double layer capacitors, pseudo capacitors, hybrid capacitors. Comparison of the characteristics of various batteries is given. The parameters of various energy storage devices are presented. The analysis of molecular energy storage devices and accumulators is carried out. Ttheir advantages and disadvantages are revealed. It has been shown that molecular energy storage or double layer electrochemical capacitors are ideal energy storage systems due to their high specific energy, fast charging and long life compared to conventional capacitors. The article presents oscillograms of a lithium-ion battery with a voltage of 10.8 V at a pulsed load current of 2A of a laptop with and without a molecular energy storage device, as well as oscil-lograms of a laptop with DVD lithium-ion battery with a voltage of 10.8 V with a parallel shutdown of a molecular energy storage device with a capacity of 7 F and without it. The comparative analysis shows that when the molecular energy storage unit with a 7 F capacity is switched on and off, transient processes are significantly improved and there are no supply voltage dips. The dependenc-es of the operating time of a 3.6 V 600 mAh lithium-ion battery at a load of 2 A for powering mo-bile cellular devices with and without a molecular energy storage are given. It is shown that when the molecular energy storage device is switched on, the battery operation time increases by almost 20%.


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