A spectroscopic and theoretical study in the near-infrared region of low concentration aliphatic alcohols

2016 ◽  
Vol 18 (19) ◽  
pp. 13666-13682 ◽  
Author(s):  
Krzysztof B. Beć ◽  
Yoshisuke Futami ◽  
Marek J. Wójcik ◽  
Yukihiro Ozaki
Keyword(s):  
Experimental Data ◽  
Perturbation Theory ◽  
Near Infrared ◽  
Theoretical Study ◽  
Infrared Region ◽  
Second Order ◽  
Aliphatic Alcohols ◽  
Low Concentration ◽  
Near Infrared Region ◽  
First Time

The near-infrared (NIR) spectra of low-concentration (5 × 10−3 M) solutions in CCl4 of basic aliphatic alcohols, methanol, ethanol, and 1-propanol were, for the first time, calculated by second-order vibrational perturbation theory computations and were compared with the corresponding experimental data.

Chiral carbazole-based porphyrins showing absorption and circular dichroism in the near-infrared region

2020 ◽  
Vol 24 (01n03) ◽  
pp. 247-251
Author(s):  
Chihiro Maeda ◽  
Tadashi Ema
Keyword(s):  
Circular Dichroism ◽  
Near Infrared ◽  
Infrared Region ◽  
Nir Absorption ◽  
Near Infrared Region ◽  
Induced Aggregation ◽  
First Time ◽  
Circular Dichroïsm

Chiral carbazole-based porphyrins were synthesized for the first time via the incorporation of hydrobenzoin units at the thiophene moieties. They showed absorption and circular dichroism in the near-infrared (NIR) region. The NIR absorption was further red-shifted by solvent-induced aggregation.

Electrochemical and spectroelectrochemical behavior of planar binuclear naphthalocyanines

2011 ◽  
Vol 15 (11n12) ◽  
pp. 1195-1201 ◽  
Author(s):  
Stanislav A. Trashin ◽  
Tatiana V. Dubinina ◽  
Aleksander V. Fionov ◽  
Larisa G. Tomilova
Keyword(s):  
Electrochemical Reduction ◽  
Near Infrared ◽  
Polar Solvent ◽  
Infrared Region ◽  
Neutral Form ◽  
Cation Radicals ◽  
Near Infrared Region ◽  
Intense Absorption ◽  
First Time

The electrochemical and spectroelectrochemical behavior of two planar binuclear naphthalocyanines containing benzene and naphthalene π-conjugated bridges was investigated for the first time. Their intense absorption in the near infrared region was observed even in a low polar solvent such as o-dichlorobenzene after electrochemical reduction at a potential of -0.4 V vs. SCE, which was not enough to reduce the complexes into their first reduction state. These data and EPR studies allow us to conclude that the electrochemically generated form is the true neutral form of the synthesized compounds whereas the suppression of the near-infrared bands is a result of the presence of their cation radicals as one-electron oxidized forms.

Soft salts based on platinum(ii) complexes with high emission quantum efficiencies in the near infrared region for in vivo imaging

2020 ◽  
Vol 56 (78) ◽  
pp. 11681-11684
Author(s):  
Jun Li ◽  
Yun Ma ◽  
Suyi Liu ◽  
Zhu Mao ◽  
Zhenguo Chi ◽  
...  
Keyword(s):  
In Vivo Imaging ◽  
Near Infrared ◽  
Infrared Region ◽  
Salt Complex ◽  
High Emission ◽  
Near Infrared Region ◽  
First Time

A novel soft salt complex-based near infrared probe was successfully developed for application in in vivo imaging for the first time.

Ligand Influence Versus Electronic Configuration of d-metal Ion in Determining the Fate of NIR Emission from LnIII Ions: A Case Study with CuII, NiII and ZnII Complexes.

2021 ◽  
Author(s):  
Abhineet Verma ◽  
Sk Saddam Hossain ◽  
Sailaja S Sunkari ◽  
Joseph Reibenspies ◽  
Satyen Saha
Keyword(s):  
Metal Ion ◽  
Selection Rule ◽  
Near Infrared ◽  
Electronic Configuration ◽  
Infrared Region ◽  
Direct Excitation ◽  
Characteristic Emission ◽  
Nir Emission ◽  
Near Infrared Region

Lanthanides (LnIII) are well known for their characteristic emission in the Near-Infrared Region (NIR). However, direct excitation of lanthanides is not feasible as described by Laporte’s parity selection rule. Here,...

Highly luminescent InP-In(Zn)P/ZnSe/ZnS core/shell/shell colloidal quantum dots with tunable emission synthesized based on growth-doping

2021 ◽  
Author(s):  
Cong Shen ◽  
Yan Qing Zhu ◽  
Zixiao Li ◽  
Jingling Li ◽  
Hong Tao ◽  
...  
Keyword(s):  
Quantum Dots ◽  
Near Infrared ◽  
Infrared Region ◽  
Colloidal Quantum Dots ◽  
High Quality ◽  
Promising Alternative ◽  
Lower Toxicity ◽  
Near Infrared Region ◽  
Inp Quantum Dots ◽  
Tunable Emission

InP quantum dots (QDs) are considered as the most promising alternative to Cd-based QDs with the lower toxicity and emission spectrum tunability ranging from visible to near-infrared region. Although high-quality...

Evaluation of melon drying using hyperspectral imaging technique in the near infrared region

LWT ◽  
2021 ◽  
Vol 143 ◽  
pp. 111092
Author(s):  
Jose Marcelino S. Netto ◽  
Fernanda A. Honorato ◽  
Patrícia M. Azoubel ◽  
Louise E. Kurozawa ◽  
Douglas F. Barbin
Keyword(s):  
Hyperspectral Imaging ◽  
Near Infrared ◽  
Imaging Technique ◽  
Infrared Region ◽  
Near Infrared Region

scholarly journals Retraction: Water-soluble multidentate polymers compactly coating Ag2S quantum dots with minimized hydrodynamic size and bright emission tunable from red to second near-infrared region

Nanoscale ◽  
2020 ◽  
Vol 12 (41) ◽  
pp. 21459-21459
Author(s):  
Charlotte Marshall
Keyword(s):  
Quantum Dots ◽  
Near Infrared ◽  
Infrared Region ◽  
Water Soluble ◽  
Hydrodynamic Size ◽  
Near Infrared Region ◽  
Ag2s Quantum Dots ◽  
Bright Emission

Retraction of ‘Water-soluble multidentate polymers compactly coating Ag2S quantum dots with minimized hydrodynamic size and bright emission tunable from red to second near-infrared region’ by Rijun Gui et al., Nanoscale, 2014, 6, 5467–5473, DOI: 10.1039/C4NR00282B.

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