scholarly journals Impact of size control of graphene oxide nanosheets for enhancing electrical and mechanical properties of carbon nanotube–polymer composites

RSC Advances ◽  
2017 ◽  
Vol 7 (48) ◽  
pp. 30221-30228 ◽  
Author(s):  
Jeonghwan Kim ◽  
Sang Woo Kim ◽  
Hongseok Yun ◽  
Bumjoon J. Kim

The size effects of GOs on the dispersion behavior of multi-walled carbon nanotubes (MWCNTs) were evaluated, and the GOs were exploited to develop conducting film and polymer-CNT composites with excellent electrical and mechanical properties.

2017 ◽  
Vol 51 (12) ◽  
pp. 1693-1701 ◽  
Author(s):  
EA Zakharychev ◽  
EN Razov ◽  
Yu D Semchikov ◽  
NS Zakharycheva ◽  
MA Kabina

This paper investigates the structure, length, and percentage of functional groups of multi-walled carbon nanotubes (CNT) depending on the time taken for functionalization in HNO3 and H2SO4 mixture. The carbon nanotube content and influence of functionalization time on mechanical properties of polymer composite materials based on epoxy matrix are studied. The extreme dependencies of mechanical properties of carbon nanotube functionalization time of polymer composites were established. The rise in tensile strength of obtained composites reaches 102% and elastic modulus reaches 227% as compared to that of unfilled polymer. The composites exhibited best mechanical properties by including carbon nanotube with 0.5 h functionalization time.


RSC Advances ◽  
2015 ◽  
Vol 5 (125) ◽  
pp. 103365-103372 ◽  
Author(s):  
Lei Liu ◽  
Dong Wang ◽  
Yuan Hu

Negative graphene oxide was combined with positive chitosan-modified multi-walled carbon nanotubes in aqueous solution and then thermally reduced to fabricate a multi-walled carbon nanotube/graphene (MWCNT/G) hybrid material.


2016 ◽  
Vol 3 (01) ◽  
Author(s):  
Holia Onggo ◽  
Rike Yudianti ◽  
Endang Ruchiat

Carbon nanotube-rayon composite filaments was fabricated by spinning and coagulation of the mixture of 100mL functionalized carbon nanotube dispersion (containing 0.72 g FCNT) and cellulose xanthate in NaOH solution using viscose process. In the process, CNT was functionalized using mixture of acidic solution ( H2SO4/HNO3, 3:1 v/v). Influence of functionalized (FCNT) and non-functionalized carbon nanotubes (nFCNT) on the fabrication of rayon nanocomposite filament was studied. Physical and morphological properties of the nanocomposite filaments were characterized by single filament tenacity tester, photo micrograph, scanning electron microscope (SEM) and transmission electron microscope (TEM). Filterability and mechanical properties of FCNT-rayon nanocomposite filament greatly improved by reducing clogging constant from 1689 to 153 and increasing tenacity from 2.72 to 3.01 g/denier and decreasing elongation from 57.1 to 36.5% respectively compared with those of nFCNT-rayon nanocomposite filament.Keywords: functionalized multi-walled carbon nanotubes, nanocomposite filament, mechanical properties, filterability, dispersion  ABSTRAKRayon nanocomposite filaments telah dibuat melalui proses pemilinan (spinning) dan koagulasi (coagulation) dari campuran 100 mL larutan functionalized carbon nanotube dispersion (FCNT=0,72 g), selulosa santat dalam larutan NaOH melalui proses viskosa. CNT di functionalisasi (FCNT) menggunakan campuran larutan asam (H2SO4/HNO3, 3:1 v/v). Pengaruh fungsionalisasi CNT pada pembuatan rayon nanocomposite filaments dipelajari dengan cara membandingkannya dengan CNT tanpa fungsionalisasi (nFCNT). Sifat fisik dan morfologi dari rayon-nanocomposite filaments dikarakterisasi menggunakan tenacity tester, photo micrograph, scanning electron microscope (SEM) dan transmission electron microscope (TEM). Viskosa FCNT memiliki daya saring (Kw) cukup baik yaitu 155, sedangkan viskosa nFCNT  memiliki daya saring 1689 (tidak baik). Kekuatan mekanik dari FCNT-rayon nanocomposite filaments berturut turut adalah 3,01 g/denier (tenacity), dan 36,5% (elongation), lebih baik dibandingkan dengan nFCNT-rayon nanocomposite filament: 2,72 g/denier (tenacity) dan 57,1% (elongation).Kata kunci: fungsionalisasi multi-walled carbon nanotubes, rayon-nanocomposite filament, sifat mekanik, daya saring, dispersi


RSC Advances ◽  
2014 ◽  
Vol 4 (75) ◽  
pp. 39645-39650 ◽  
Author(s):  
Li Fu ◽  
Guosong Lai ◽  
Peter J. Mahon ◽  
James Wang ◽  
Deming Zhu ◽  
...  

A simple one-step electro-deposition method was employed for the synthesis of silver dendritic structures with the aid of graphene oxide (GO) modified multi-walled carbon nanotubes (MWCNTs) which are dispersed in an AgNO3 solution.


2016 ◽  
Vol 70 (6) ◽  
Author(s):  
Agnieszka Piegat ◽  
Anna Jędrzejewska ◽  
Robert Peƚech ◽  
Iwona Peƚech

AbstractThe influence of the chemical modification of carbon nanotubes on the mechanical, thermal and electrical properties of poly(butylene terephthalate)-based composites was investigated. Polymer composites based on poly(butylene terephthalate) were obtained via in situ polymerisation or extrusion. Commercially available multi-walled carbon nanotubes (Nanocyl NC7000) at different loadings (mass %: 0.05, 0.25, 1, 2) were used as fillers. The functionalisation process took place under a chlorine atmosphere followed by a reaction with sodium hydroxide. The effect of carbon nanotube modification was analysed according to the changes in the polymer thermal and mechanical properties. An addition of modified carbon nanotubes in the amount of 0.05 mass % improved the mechanical properties of the composites in terms of both Young’s modulus and tensile strength by 5–10 % and 17–30 % compared with composites with unmodified carbon nanotubes and neat poly(butylene terephthalate), respectively. The in situ method of composite preparation was a more effective technique for enhancing the matrix–filler interactions, although a significantly lower amount of fillers were used than in the extrusion method.


2017 ◽  
Vol 4 (5) ◽  
pp. 17-00029-17-00029 ◽  
Author(s):  
Keiichi SHIRASU ◽  
Itaru TAMAKI ◽  
Takamichi MIYAZAKI ◽  
Go YAMAMOTO ◽  
Raman BEKAREVICH ◽  
...  

2018 ◽  
Vol 38 (8) ◽  
pp. 731-738
Author(s):  
Yifan Huang ◽  
Weicheng Jiao ◽  
Yue Niu ◽  
Guomin Ding ◽  
Rongguo Wang

Abstract The aim of the paper is to develop a novel nanocomposite with high mechanical properties. The mechanical properties are improved by aligning the Fe3O4/multi-walled carbon nanotubes (MWCNTs) into a highly oriented manner in epoxy resin (EP) via a low magnetic field. Fe3O4 nanoparticles were tethered onto the surface of MWCNTs by a novel water-in-oil (W/O) method without heating at high temperatures or the protection of inert gas. Then, the modified magnetic MWCNTs (m-MWCNTs) were added into EP and aligned in a low magnetic field (100 mT). A method was presented to estimate the minimum magnetic field strength for aligning the m-MWCNTs. Besides, the morphology and microstructures of the fabricated m-MWCNTs and m-MWCNTs/EP highly ordered nanocomposites were characterized. Finally, the mechanical properties measurements were performed. The results of the experiments showed that this method was very efficient in aligning m-MWCNTs embedded in polymer matrix leading to a highly ordered composite for improving mechanical properties.


2015 ◽  
Vol 3 (21) ◽  
pp. 5573-5579 ◽  
Author(s):  
Yuling Li ◽  
Mingjun Li ◽  
Minglei Pang ◽  
Shengyu Feng ◽  
Jie Zhang ◽  
...  

The specific surface area is a key factor that determines both the electrical and mechanical properties of silicone rubber/MWCNTs.


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