A novel bifunctional thermo-sensitive poly(lactic acid)@poly(butylene succinate) core–shell fibrous separator prepared by a coaxial electrospinning route for safe lithium-ion batteries

2017 ◽  
Vol 5 (44) ◽  
pp. 23238-23242 ◽  
Author(s):  
Xiaoyu Jiang ◽  
Lifen Xiao ◽  
Xinping Ai ◽  
Hanxi Yang ◽  
Yuliang Cao

A thermally induced shutdown separator of PLA@PBS is successfully fabricated by a facile coaxial electrospinning process for safe lithium ion batteries.

2018 ◽  
Vol 98 ◽  
pp. 483-491 ◽  
Author(s):  
Hamad F. Alharbi ◽  
Monis Luqman ◽  
Khalil Abdelrazek Khalil ◽  
Yasser A. Elnakady ◽  
Omar H. Abd-Elkader ◽  
...  

2015 ◽  
Vol 3 (13) ◽  
pp. 7112-7120 ◽  
Author(s):  
Haoran Zhang ◽  
Xianying Qin ◽  
Junxiong Wu ◽  
Yan-Bing He ◽  
Hongda Du ◽  
...  

Core–shell silicon/carbon (Si/C) fibers with an internal honeycomb-like carbon framework are prepared based on the coaxial electrospinning technique.


2019 ◽  
Vol 473 ◽  
pp. 352-358 ◽  
Author(s):  
Meng Zhang ◽  
Xinxin Huang ◽  
Hailin Xin ◽  
Dongzhi Li ◽  
Yong Zhao ◽  
...  

Nanomaterials ◽  
2021 ◽  
Vol 11 (12) ◽  
pp. 3454
Author(s):  
Li Zeng ◽  
Hongxue Xi ◽  
Xingang Liu ◽  
Chuhong Zhang

Silicon (Si) is expected to be a high-energy anode for the next generation of lithium-ion batteries (LIBs). However, the large volume change along with the severe capacity degradation during the cycling process is still a barrier for its practical application. Herein, we successfully construct flexible silicon/carbon nanofibers with a core–shell structure via a facile coaxial electrospinning technique. The resultant Si@C nanofibers (Si@C NFs) are composed of a hard carbon shell and the Si-embedded amorphous carbon core framework demonstrates an initial reversible capacity of 1162.8 mAh g−1 at 0.1 A g−1 with a retained capacity of 762.0 mAh g−1 after 100 cycles. In addition, flexible LIBs assembled with Si@C NFs were hardly impacted under an extreme bending state, illustrating excellent electrochemical performance. The impressive performances are attributed to the high electric conductivity and structural stability of the porous carbon fibers with a hierarchical porous structure, indicating that the novel Si@C NFs fabricated using this electrospinning technique have great potential for advanced flexible energy storage.


JOM ◽  
2020 ◽  
Vol 72 (8) ◽  
pp. 3037-3045
Author(s):  
Shenggao Wang ◽  
Tao Wang ◽  
Yan Zhong ◽  
Quanrong Deng ◽  
Yangwu Mao ◽  
...  

2021 ◽  
Vol 491 ◽  
pp. 229577
Author(s):  
Zhiguang Cao ◽  
Yuebei Yang ◽  
Junling Qin ◽  
Zixue Su

Polymers ◽  
2021 ◽  
Vol 13 (15) ◽  
pp. 2531
Author(s):  
Rodion Kopitzky

Sugar beet pulp (SBP) is a residue available in large quantities from the sugar industry, and can serve as a cost-effective bio-based and biodegradable filler for fully bio-based compounds based on bio-based polyesters. The heterogeneous cell structure of sugar beet suggests that the processing of SBP can affect the properties of the composite. An “Ultra-Rotor” type air turbulence mill was used to produce SBP particles of different sizes. These particles were processed in a twin-screw extruder with poly(lactic acid) (PLA) and poly(butylene succinate) (PBS) and fillers to granules for possible marketable formulations. Different screw designs, compatibilizers and the use of glycerol as a thermoplasticization agent for SBP were also tested. The spherical, cubic, or ellipsoidal-like shaped particles of SBP are not suitable for usage as a fiber-like reinforcement. In addition, the fineness of ground SBP affects the mechanical properties because (i) a high proportion of polar surfaces leads to poor compatibility, and (ii) due to the inner structure of the particulate matter, the strength of the composite is limited to the cohesive strength of compressed sugar-cell compartments of the SBP. The compatibilization of the polymer–matrix–particle interface can be achieved by using compatibilizers of different types. Scanning electron microscopy (SEM) fracture patterns show that the compatibilization can lead to both well-bonded particles and cohesive fracture patterns in the matrix. Nevertheless, the mechanical properties are limited by the impact and elongation behavior. Therefore, the applications of SBP-based composites must be well considered.


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