All-polymer solar cells based on a novel narrow-bandgap polymer acceptor with power conversion efficiency over 10%

2019 ◽  
Vol 7 (27) ◽  
pp. 16190-16196 ◽  
Author(s):  
Jingnan Wu ◽  
Yuan Meng ◽  
Xia Guo ◽  
Lei Zhu ◽  
Feng Liu ◽  
...  
Keyword(s):  
Power Conversion Efficiency ◽  
Conversion Efficiency ◽  
Polymer Solar Cells ◽  
Short Circuit ◽  
Power Conversion ◽  
Short Circuit Current ◽  
Short Circuit Current Density ◽  
Open Circuit ◽  
Narrow Bandgap ◽  
Polymer Acceptor

A new narrow bandgap polymer acceptor (PN1) based on a fused-ring small molecule acceptor as the core building block was designed and developed. The optimal all-polymer solar cell based on the blend of PM6 and PN1 achieved an outstanding power conversion efficiency of 10.5% with a high open-circuit voltage of 1.0 V, a short circuit current density of 15.2 mA cm−2 and a fill factor of 0.69.

scholarly journals Donor-Acceptor Polymer Based on Planar Structure of Alkylidene-Fluorene Derivative: Correlation of Power Conversion Efficiency among Polymer and Various Acceptor Units

Polymers ◽  
2020 ◽  
Vol 12 (12) ◽  
pp. 2859
Author(s):  
Eui Jin Lee ◽  
Ho Jun Song
Keyword(s):  
Power Conversion Efficiency ◽  
Conversion Efficiency ◽  
Short Circuit ◽  
Power Conversion ◽  
Average Molecular Weight ◽  
Coupling Reaction ◽  
Short Circuit Current ◽  
Open Circuit ◽  
Planar Structure ◽  
Quinoxaline Derivatives

This study synthesized a novel polymer, poly(alkylidene fluorene-alt-diphenylquinoxaline) (PAFDQ), based on a planar alkylidene-fluorene and a highly soluble quinoxaline derivative through the Suzuki coupling reaction. We designed a novel molecular structure based on alkylidene fluorene and quinoxaline derivatives due to compact packing property by the planar structure of alkyidene fluorene and efficient intra-molecular charge transfer by quinoxaline derivatives. The polymer was largely dissolved in organic solvents, with a number average molecular weight and polydispersity index of 13.2 kg/mol and 2.74, respectively. PAFDQ showed higher thermal stability compared with the general fluorene structure owing to its rigid alkylidene-fluorene structure. The highest occupied and lowest unoccupied molecular orbital levels of PAFDQ were −5.37 eV and −3.42 eV, respectively. According to X-ray diffraction measurements, PAFDQ exhibited the formation of an ordered lamellar structure and conventional edge-on π-stacking. The device based on PAFDQ/Y6-BO-4Cl showed the best performance in terms of short circuit current (9.86 mA/cm2), open-circuit voltage (0.76 V), fill factor (44.23%), and power conversion efficiency (3.32%). Moreover, in the PAFDQ/Y6-BO-4Cl-based film, the phase separation of donor-rich and acceptor-rich phases, and the connected dark domains, was observed.

Effect of Crystallinity on the Performance of P3HT/PC70BM/n-Dodecylthiol Polymer Solar Cells

2013 ◽  
Vol 136 (2) ◽  
Author(s):  
Nidal Abu-Zahra ◽  
Mahmoud Algazzar
Keyword(s):  
Solar Cells ◽  
Power Conversion Efficiency ◽  
Conversion Efficiency ◽  
Polymer Solar Cells ◽  
Short Circuit ◽  
Power Conversion ◽  
Crystallization Rate ◽  
Short Circuit Current ◽  
Scanning Calorimetry ◽  
Avrami Model

In this research, n-dodecylthiol was added to P3HT/PC70BM polymer solar cells (PSCs) to improve the crystallinity of P3HT and enhance the phase separation of P3HT/PC70BM. Crystallinity of P3HT:PC70BM doped with 0–5% by volume of n-dodecylthiol was measured using X-ray diffraction (XRD) and differential scanning calorimetry (DSC) techniques. Both methods showed improvement in crystallinity, which resulted in improving the power conversion efficiency (PCE) of polymer solar cells by 33%. In addition, annealing at 150 °C for 30 min showed further improvement in crystallinity with n-dodecylthiol concentration up to 2%. The highest power conversion efficiency of 3.21% was achieved with polymer crystallites size L of 11.2 nm, after annealing at 150 °C for 30 min under a vacuum atmosphere. The smaller crystallite size suggests a shorter path of the charge carriers between P3HT backbones, which could be beneficial to getting a higher short circuit current in the devices made with the additive. Kinetics study of P3HT:PC70BM crystallinity using Avrami model showed a faster crystallization rate (1/t0.5) at higher temperatures.

Plasmonic-enhanced polymer photovoltaic cells based on Au nanoparticles with wide absorption spectra of 300–1000 nm

2014 ◽  
Vol 2 (43) ◽  
pp. 9303-9310 ◽  
Author(s):  
Yupei Zhang ◽  
Jingyu Hao ◽  
Xue Li ◽  
Shufen Chen ◽  
Lianhui Wang ◽  
...  
Keyword(s):  
Solar Cells ◽  
Power Conversion Efficiency ◽  
Absorption Spectra ◽  
Conversion Efficiency ◽  
Au Nanoparticles ◽  
Polymer Solar Cells ◽  
Short Circuit ◽  
Power Conversion ◽  
Photovoltaic Cells ◽  
Short Circuit Current

Mixed Au nanoparticles (NPs) with wide absorption spectra of 300–1000 nm and three absorption peaks of 520, 600, and 770 nm are assembled onto the ITO anode in polymer solar cells to significantly improve the power conversion efficiency and short-circuit current by factors of 24.2% and 18.6%.

scholarly journals Enhanced Power Conversion Efficiency of P3HT : PC71BM Bulk Heterojunction Polymer Solar Cells by Doping a High-Mobility Small Organic Molecule

2015 ◽  
Vol 2015 ◽  
pp. 1-8 ◽  
Author(s):  
Hanyu Wang ◽  
Xiao Wang ◽  
Pu Fan ◽  
Xin Yang ◽  
Junsheng Yu
Keyword(s):  
Solar Cells ◽  
Power Conversion Efficiency ◽  
Conversion Efficiency ◽  
Polymer Solar Cells ◽  
Short Circuit ◽  
Power Conversion ◽  
Photovoltaic Performance ◽  
Acid Methyl Ester ◽  
High Mobility ◽  
Short Circuit Current

The effect of molecular doping with TIPS-pentacene on the photovoltaic performance of polymer solar cells (PSCs) with a structure of ITO/ZnO/poly(3-hexylthiophene-2,5-diyl) (P3HT) : [6,6]-phenyl C71-butyric acid methyl ester (PC71BM) : TIPS-pentacene/MoOx/Ag was systematically investigated by adjusting TIPS-pentacene doping ratios ranged from 0.3 to 1.2 wt%. The device with 0.6 wt% TIPS-pentacene exhibited the enhanced short-circuit current and fill factor by 1.23 mA/cm2and 7.8%, respectively, resulting in a maximum power conversion efficiency of 4.13%, which is one-third higher than that of the undoped one. The photovoltaic performance improvement was mainly due to the balanced charge carrier mobility, enhanced crystallinity, and matched cascade energy level alignment in TIPS-pentacene doped active layer, resulting in the efficient charge separation, transport, and collection.

CoPc/CdS Hybrid Photovoltaic Device

2010 ◽  
Vol 93-94 ◽  
pp. 570-573 ◽  
Author(s):  
P. Keeratithivakorn ◽  
B. Tunhoo ◽  
T. Thiwawong ◽  
J. Nukeaw
Keyword(s):  
Power Conversion Efficiency ◽  
Layer Thickness ◽  
Conversion Efficiency ◽  
Short Circuit ◽  
Power Conversion ◽  
Cadmium Sulphide ◽  
Short Circuit Current ◽  
Open Circuit ◽  
Organic Layer ◽  
Photovoltaic Properties

The organic-inorganic hybrid photovoltaic (PV) cells based on cadmium sulphide (CdS) and cobalt phthalocyanine (CoPc) films have been fabricated and characterized their PV performance. This investigated the effects of the organic and inorganic layer thickness on the photovoltaic properties, these thickness was controlled at various values such as 10, 30 and 50 nm. However, the performance of the hybrid photovoltaic cells was depending on the organic layer thickness. The optimize results of PV cell with CoPc 10 nm and CdS 30 nm showed an open-circuit voltage (Voc) = 0.536 V, a short-circuit current density (Jsc) = 0.1020 mA/cm2, a fill factor FF = 0.281 and a power conversion efficiency (η) = 0.01536 % under the AM1.5 conditions. Efficiency is enhanced by 22 times with the addition of a buffer layer, bathocuproine (BCP) 5 nm, the power conversion efficiency (η) value from 0.01536 to 0.34571%.

scholarly journals High performance tandem organic solar cells via a strongly infrared-absorbing narrow bandgap acceptor

2021 ◽  
Vol 12 (1) ◽  
Author(s):  
Zhenrong Jia ◽  
Shucheng Qin ◽  
Lei Meng ◽  
Qing Ma ◽  
Indunil Angunawela ◽  
...  
Keyword(s):  
Solar Cells ◽  
Power Conversion Efficiency ◽  
Conversion Efficiency ◽  
Organic Solar Cells ◽  
High Performance ◽  
Short Circuit ◽  
Power Conversion ◽  
High Power Conversion Efficiency ◽  
Device Structure ◽  
Narrow Bandgap

AbstractTandem organic solar cells are based on the device structure monolithically connecting two solar cells to broaden overall absorption spectrum and utilize the photon energy more efficiently. Herein, we demonstrate a simple strategy of inserting a double bond between the central core and end groups of the small molecule acceptor Y6 to extend its conjugation length and absorption range. As a result, a new narrow bandgap acceptor BTPV-4F was synthesized with an optical bandgap of 1.21 eV. The single-junction devices based on BTPV-4F as acceptor achieved a power conversion efficiency of over 13.4% with a high short-circuit current density of 28.9 mA cm−2. With adopting BTPV-4F as the rear cell acceptor material, the resulting tandem devices reached a high power conversion efficiency of over 16.4% with good photostability. The results indicate that BTPV-4F is an efficient infrared-absorbing narrow bandgap acceptor and has great potential to be applied into tandem organic solar cells.

scholarly journals Simulation of a perovskite sandwich solar cell with the p-CZTS / p-CH3NH3PbCI3 / p-CZTS absorber layers

2021 ◽  
Vol 877 (1) ◽  
pp. 012001
Author(s):  
Marwah S Mahmood ◽  
N K Hassan
Keyword(s):  
Solar Cell ◽  
Conversion Efficiency ◽  
Current Density ◽  
Short Circuit ◽  
Perovskite Solar Cells ◽  
Short Circuit Current ◽  
Short Circuit Current Density ◽  
Open Circuit ◽  
Current Voltage ◽  
Cell Capacitance

Abstract Perovskite solar cells attract the attention because of their unique properties in photovoltaic cells. Numerical simulation to the structure of Perovskite on p-CZTS/p-CH3NH3PbCI3/p-CZTS absorber layers is performed by using a program solar cell capacitance simulator (SCAPS-1D), with changing absorber layer thickness. The effect of thickness p-CZTS/p-CH3NH3PbCI3/p-CZTS, layers at (3.2μm, 1.8 μm, 1.1 μm) respectively are studied. The obtained results are short circuit current density (Jsc ), open circuit voltage (V oc), fill factor (F. F) and power conversion efficiency (PCE) equal to (28 mA/cm2, 0.83 v, 60.58 % and 14.25 %) respectively at 1.1 μm thickness. Our findings revealed that the dependence of current - voltage characteristics on the thickness of the absorbing layers, an increase in the amount of short circuit current density with an increase in the thickness of the absorption layers and thus led to an increase in the conversion efficiency and improvement of the cell by increasing the thickness of the absorption layers.

Effect of temperature on organic Schottky barrier cells

1981 ◽  
Vol 59 (6) ◽  
pp. 727-732 ◽  
Author(s):  
Rafik O. Loutfy ◽  
Cheng-Kuo Hsiao
Keyword(s):  
Solar Cells ◽  
Power Conversion Efficiency ◽  
Schottky Barrier ◽  
Conversion Efficiency ◽  
Organic Solar Cells ◽  
Short Circuit ◽  
Power Conversion ◽  
Open Circuit ◽  
Effect Of Temperature ◽  
Photovoltaic Properties

The effect of temperature on the photovoltaic properties of indium/metal-free phthalocyanine Schottky barrier solar cells was investigated in the range 260–350 K. In general, the short circuit photocurrent, Jsc, and fill factor, ff, increased with increasing temperature (in contrast to inorganic photocells). The device series resistance and open circuit photovoltage, Voc, decreased (similar to inorganic photocells) as temperature was raised. An increase in the overall power conversion efficiency, η, has been observed with increase of temperature. In the case of x-H2Pc, the power conversion efficiency increased by 2.5 times due to a temperature rise of 60 °C above ambient. Thus, for operation at temperatures above ambient, organic solar cells may offer a significant advantage over inorganic cells.Analysis of the variation of the photovoltage with temperature showed that the decrease in Voc is mainly due to variation injunction impedance, which is controlled by thermionic current at high temperature and ionized impurity at low temperature.

A naphthodithiophene-based nonfullerene acceptor for high-performance polymer solar cells with a small energy loss

2020 ◽  
Vol 8 (19) ◽  
pp. 6513-6520 ◽  
Author(s):  
Xingliang Dong ◽  
Qing Guo ◽  
Qi Liu ◽  
Lei Zhu ◽  
Xia Guo ◽  
...  
Keyword(s):  
High Performance ◽  
Open Circuit Voltage ◽  
Polymer Solar Cells ◽  
Short Circuit ◽  
Short Circuit Current ◽  
Short Circuit Current Density ◽  
Open Circuit ◽  
Small Energy ◽  
High Performance Polymer ◽  
Nonfullerene Acceptor

A new non-fullerene acceptor named NTO-4F is developed. The optimal PSC based on PM6:NTO-4F achieves a PCE of 11.5% with simultaneously high open-circuit voltage of 0.99 V and short-circuit current density of 19.1 mA cm−2.

The effect of methyl ammonium chloride doping for perovskite solar cells on structure, crystallization and power conversion efficiency

2020 ◽  
pp. 2150096
Author(s):  
Jing Gao ◽  
Chujian Liao ◽  
Yanqun Guo ◽  
Difan Zhou ◽  
Zhigang Zeng ◽  
...  
Keyword(s):  
Solar Cells ◽  
Power Conversion Efficiency ◽  
Conversion Efficiency ◽  
Surface Defects ◽  
Short Circuit ◽  
Power Conversion ◽  
Perovskite Solar Cells ◽  
Short Circuit Current ◽  
High Quality ◽  
Perovskite Layer

The perovskite membrane with large particle size, uniform coverage and high quality is the prerequisite for the preparation of efficient and stable perovskite solar cells. Various additives have been used to increase the grain size and improve the film morphology and crystal quality. In this paper, methylammonium chloride (MACl) was proposed to obtain high crystalline quality of [Formula: see text] perovskite absorption layer. The results show that the adding ammonium methyl chloride into the precursor of tricationic perovskite not only passivates surface defects to form high-quality and large-grain perovskite films, but also facilitates the formation of pure [Formula: see text]-phase [Formula: see text]. Meanwhile, the designed perovskite precursor solutions were used to fabricate mesoporous perovskite solar cells (PSCs). Owing to the perovskite layer consisting of optimized MACl doping, the short-circuit current density [Formula: see text] of PSCs reaches 23.81 mA/cm2, which is 2.73 mA/cm2 higher than the primary [Formula: see text] based on PSCs. The obtained power conversion efficiency (PCE) increases from 13.67% to 17.59%.

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