Bismuth chromate (Cr2Bi3O11): A new bismuth-based semiconductor with excellent photocatalytic activity

2022 ◽  
Author(s):  
Xinyu Gao ◽  
Kelei Huang ◽  
Zisheng Zhang ◽  
Xiangchao Meng

A novel bismuth chromate material (Cr2Bi3O11) was synthesized by a direct mixing method with higher photocatalytic activity in both organic pollutants’ detoxification and oxygen evolution. Cr2Bi3O11 with a band gap...

RSC Advances ◽  
2016 ◽  
Vol 6 (107) ◽  
pp. 105980-105987 ◽  
Author(s):  
Muthusamy Tamilselvan ◽  
Aninda J. Bhattacharyya

A highly crystalline 3D urchin-shaped SbSI with an ns2 cationic electronic configuration displays very high and efficient photocatalytic degradation of organic pollutants.


2014 ◽  
Vol 2014 ◽  
pp. 1-14 ◽  
Author(s):  
Ting Feng ◽  
Gen Sheng Feng ◽  
Lei Yan ◽  
Jia Hong Pan

The present paper reviews the progress in the synthesis of one-dimensional (1D) TiO2nanostructures and their environmental applications in the removal of organic pollutants. According to the shape, 1D TiO2nanostructures can be divided into nanorods, nanotubes, nanowires/nanofibers, and nanobelts. Each of them can be synthesized via different technologies, such as sol-gel template method, chemical vapor deposition, and hydrothermal method. These methods are discussed in this paper, and the recent development of the synthesis technologies is also presented. Furthermore, the organic pollutants, degradation using the synthesized 1D TiO2nanostructures is studied as an important application of photocatalytic oxidation (PCO). The 1D nanostructured TiO2exhibited excellent photocatalytic activity in a PCO process, and the mechanism of photocatalytic degradation of organic pollutants is also discussed. Moreover, the modification of 1D TiO2nanostructures using metal ions, metal oxide, or inorganic element can further enhance the photocatalytic activity of the photocatalyst. This phenomenon can be explained by the suppression of e−-h+pairs recombination rate, increased specific surface area, and reduction of band gap. In addition, 1D nanostructured TiO2can be further constructed as a film or membrane, which may extend its practical applications.


Author(s):  
Yan Huang ◽  
Lichao Ning ◽  
Zibo Feng ◽  
Guifeng Ma ◽  
Shuliang Yang ◽  
...  

Oxygen-doped (O-doped) graphitic carbon nitride (g-C3N4) usually presents excellent photocatalytic activity than pristine g-C3N4 with the common ON2-doping. However, very few researches concerned about the ON1-doped g-C3N4. Herein, g-C3N4 nanosheets...


2021 ◽  
Vol 11 (1) ◽  
Author(s):  
Somayeh Safat ◽  
Foad Buazar ◽  
Salim Albukhaty ◽  
Soheila Matroodi

AbstractThis contribution presents the biosynthesis, physiochemical properties, toxicity and photocatalytic activity of biogenic CeO2 NPs using, for the first time, marine oyster extract as an effective and rich source of bioreducing and capping/stabilizing agents in a one-pot recipe. CeO2 NPs formation was initially confirmed through the color change from light green to pale yellow and subsequently, their corresponding absorption peak was spectroscopically determined at 310 nm with an optical band-gap of 4.67 eV using the DR-UV technique. Further, XRD and Raman analyses indicated that nanoceria possessed face-centered cubic arrangements without any impurities, having an average crystallite size of 10 nm. TEM and SEM results revealed that biogenic CeO2 NPs was approximately spherical in shape with a median particle size of 15 ± 1 nm. The presence of various bioorganic substances on the surface of nanoparticles was deduced by FTIR and TGA results. It is found that marine-based nanoceria shows no cytotoxic effect on the normal cell, thus indicating their enhanced biocompatibility and biosafety to living organisms. Environmentally, due to energy band gap, visible light-activated CeO2 nanocatalyst revealed superior photocatalytic performance on degradation of methylene blue pollutant with removal rate of 99%. Owing to the simplicity, cost-effectiveness, and environmentally friendly nature, this novel marine biosynthetic route paves the way for prospective applications of nanoparticles in various areas.


2021 ◽  
Vol 0 (0) ◽  
Author(s):  
Wail Al Zoubi ◽  
Abbas Ali Salih Al-Hamdani ◽  
Baek Sunghun ◽  
Young Gun Ko

Abstract Heterogeneous photocatalysts was a promising material for removing organic pollutants. Titanium dioxide (TiO2) was a suitable photocatalyst for its cost efficiency and high stability to reduce various pollutants. Enhancing TiO2 photocatalyst performance by doping with changed metals or non-metal ions and organic compounds have been reviewed. These methods could enhance photoelectrochemical activity via: (i) by a donor of electrons via electron-donor agents that would produce particular defects in TiO2 structure and capture transporters of charge; (ii) by reducing recombination rate of the charge transporters and increasing degradation of pollutants. This study investigates the modification approaches of TiO2 that comprise methods for overcoming the essential TiO2 restrictions and enhancing the photocatalytic degradation of organic pollutants. Consequently, it emphasized on the current progress of modified-TiO2 used for different pollutants in ambient conditions. Amendment techniques, such as inorganic and organic parts as doping, are studied. The reported experimental results obtained with the photocatalytic oxidation process for degrading organic pollutants were also collected and assessed.


RSC Advances ◽  
2021 ◽  
Vol 11 (17) ◽  
pp. 10300-10308
Author(s):  
Hui Feng ◽  
Siqi Feng ◽  
Niu Tang ◽  
Songbai Zhang ◽  
Xiangyang Zhang ◽  
...  

New idea for the low cost synthesis of high performance photocatalysts for the photodegradation of organic pollutants in aqueous solution.


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