scholarly journals Influence of Copper Precursor on the Catalytic Transformation of Oleylamine during Cu Nanoparticles Synthesis

Author(s):  
Antoine Pesesse ◽  
Sophie Carenco

For an optimal use of copper nanoparticles in catalysis, in-depth understanding of the reaction mechanisms and fine characterization of final products are equally relevant. Indeed, both have a direct impact...

MRS Advances ◽  
2019 ◽  
Vol 4 (5-6) ◽  
pp. 305-309 ◽  
Author(s):  
Yuen-ting Rachel Chau ◽  
Lianlian Deng ◽  
Mai Thanh Nguyen ◽  
Tetsu Yonezawa

ABSTRACTMetallic Copper nanoparticles (Cu NPs) were obtained via sputtering of Cu target onto liquid polymer, i.e., poly(ethylene glycol), PEG, under vacuum condition. The Cu NPs growth significantly right after the sputtering deposition from 3.1 nm to 4.1 nm in 4 hours as monitored by TEM. There was negligible growth of NPs for longer time and completely PEG acts as the coating material of Cu NPs so no agglomeration was observed for 1 week. The challenge of characterization of Cu NPs was also discussed.


Catalysts ◽  
2021 ◽  
Vol 11 (3) ◽  
pp. 365
Author(s):  
Jose Luis Cerrillo ◽  
Antonio Eduardo Palomares

The presence of bromate in water sources generates environmental concern due to its toxicity for humans. Diverse technologies, like membranes, ion exchange, chemical reduction, etc., can be employed to treat bromate-polluted water but they produce waste that must be treated. An alternative to these technologies can be the catalytic reduction of bromate to bromide using hydrogen as a reducing agent. In this review, we analyze the research published about this catalytic technology. Specifically, we summarize and discuss about the state of knowledge related to (1) the different metals used as catalysts for the reaction; (2) the influence of the support on the catalytic activity; (3) the characterization of the catalysts; (4) the reaction mechanisms; and (5) the influence of the water composition in the catalytic activity and in the catalyst stability. Based on published papers, we analyze the strength and weaknesses of this technique and the possibilities of using this reaction for the treatment of bromate-polluted water as a sustainable process.


2019 ◽  
Vol 471 ◽  
pp. 862-868 ◽  
Author(s):  
Rusbel Coneo Rodríguez ◽  
Luis Yate ◽  
Emerson Coy ◽  
Ángel M. Martínez-Villacorta ◽  
Andrea V. Bordoni ◽  
...  

Polymers ◽  
2021 ◽  
Vol 13 (24) ◽  
pp. 4364
Author(s):  
Rutaba Amjad ◽  
Bismillah Mubeen ◽  
Syed Shahbaz Ali ◽  
Syed Sarim Imam ◽  
Sultan Alshehri ◽  
...  

The use of biomaterials in the synthesis of nanoparticles is one of the most up-to-date focuses in modern nanotechnologies and nanosciences. More and more research on green methods of producing metal oxide nanoparticles (NP) is taking place, with the goal to overcome the possible dangers of toxic chemicals for a safe and innocuous environment. In this study, we synthesized copper nanoparticles (CuNPs) using Fortunella margarita leaves’ extract, which reflects its novelty in the field of nanosciences. The visual observation of a color change from dark green to bluish green clearly shows the instant and spontaneous formation of CuNPs when the phytochemicals of F. margarita come in contact with Cu+2 ions. The synthesis of CuNPs was carried out at different conditions, including pH, temperature, concentration ratio and time, and were characterized with UV-Vis absorption spectra, scanning electron microscope (SEM) and X-ray diffraction (XRD). The UV-Vis analysis reveals the surface plasmon resonance property (SPR) of CuNPs, showing a characteristic absorption peak at 679 nm, while SEM reveals the spherical but agglomerated shape of CuNPs of the size within the range of 51.26–56.66 nm.


2018 ◽  
Vol 10 (22) ◽  
pp. 2614-2622 ◽  
Author(s):  
Qiang Xie ◽  
Dongmin Shi ◽  
Jing Wan ◽  
Xiaojun Zhang ◽  
Guangfeng Wang

Despite the distinct features of polythymine (T)-templated copper nanoparticles (polyT-Cu NPs) as fluorescent probes for various biosensors, most of the reported methods involve labeling with an appropriate fluorescence quencher, or the addition of enzyme to digest the DNA-template.


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