scholarly journals Use of the water-swellable polymers (WSP) for wellbore stabilization in intensely fractured rock intervals

2021 ◽  
Vol 266 ◽  
pp. 01013
Author(s):  
M.I. Sadykov ◽  
P.A. Blinov ◽  
M.V. Nutskova
Keyword(s):  
Fractured Rocks ◽  
Fractured Rock ◽  
Drilling Fluid ◽  
Standard Laboratory ◽  
Laboratory Equipment ◽  
Stability Coefficient ◽  
Complex Effect ◽  
Fluid Properties ◽  
The Stability ◽  
The One

Current research on the stability of well walls when drilling in fractured rocks and also when drilling inclined sections of the well profile are based on the assessment of the effect of drilling fluid filtrate. The novelty of this work lies in studying the complex effect of a water-swellable polymer on the stability of well wall, on the one hand, and on the controlled loss of circulation on the other. For preparing rock samples, a method was used based on standard laboratory equipment fordrilling fluid properties. The well wall stability tests are performedon a direct shear apparatus.The WSP composition based on alcohol, ether, and surfactant (Polyecanol Flora) showed its efficiency by increasing the stability coefficient with the engagement of less and more internal friction angle.PHPA-based viscoelastic composition showed the best result by increasing the stability coefficient in the hazardous areas by 50-60%.

scholarly journals Experimental investigation of the effect of TiO2 nanofluid and KCl salt on polymeric water-based drilling fluid properties

2019 ◽  
Vol 74 ◽  
pp. 9 ◽  
Author(s):  
AmirHossein Parizad ◽  
Ali Khorram Ghahfarokhi ◽  
Khalil Shahbazi ◽  
Amin Daryasafar ◽  
Tofigh Sayahi ◽  
...  
Keyword(s):  
Oil Recovery ◽  
Base Fluid ◽  
Drilling Fluid ◽  
Rheological Parameters ◽  
Rheological Models ◽  
Shear Rates ◽  
Water Based ◽  
Fluid Properties ◽  
Different Temperatures ◽  
The Stability

In petroleum industries, nanofluids have the potential to improve the characteristics of the fluids used in drilling wells or Enhanced Oil Recovery (EOR) processes. In this study, a water based mud containing polymer was considered as the base fluid. Different concentrations of TiO2 nanoparticle (0, 0.5 and 0.75 wt%) and different concentrations of KCl salt (0, 0.5, 1.5, and 3 wt%) were added to the base fluid and exposed to different temperatures (30, 50, 70 and 90 °C) with 19 different shear rates for investigating the effects of nanoparticle concentration, salt concentration, temperature and shear rate on viscosity of the base mud. Presence of TiO2 particles enhanced not only the rheological behavior but also electrical and thermal conductivity of fluid up to 25% and 43%, respectively. Furthermore, the stability of the fluid containing salt and nanoparticle was investigated in these temperatures owing to the fact that the temperature could cause degradation of the fluid. For the purpose of investigating this phenomenon, the after cooling experiment was conducted. In addition, the data gathered in this investigation were examined by using three famous rheological models (Power law, Herschel-Bulkley and Herschel-Bulkley-Papanastasiou models) and the rheological parameters of each model were determined.

Residual Stress Research of Cold-Formed Thin-Wall Steel Members Using the Finite Element Method

2012 ◽  
Vol 166-169 ◽  
pp. 3343-3347
Author(s):  
Hua Chen Liu
Keyword(s):  
Residual Stress ◽  
Ultimate Load ◽  
Thin Wall ◽  
The Finite Element Method ◽  
Distribution Models ◽  
Stability Coefficient ◽  
Steel Members ◽  
Angle Steel ◽  
The Stability ◽  
The One

This paper analyzes the results of experience and rules of distribution of the cold – formed residual stress. Distribution models of residual stress in cold-formed thin-wall steel that are close to the real condition and initial stress files of ANSYS which can describe the magnitude and distribution of the residual stress are established. This method can be applicable to simulate different distribution of the residual stress. Through importing the files into the stability analysis of ANSYS, ultimate load in the effect of residual stress can be gained. The stability coefficient of cold-formed thin-wall crimping angle steel under influence of the initial bending of 1/750 is studied, comparing the result curve with the one in GB50018-2002, it is proved that the curve is reasonable and the stability coefficient of the code should be suitable to improve.

Use of a Lyophilized Reference Plasma to Compare Coagulation Test Procedures

1975 ◽  
Vol 34 (02) ◽  
pp. 426-444 ◽  
Author(s):  
J Kahan ◽  
I Nohén
Keyword(s):  
Oral Anticoagulant Therapy ◽  
Repeated Measurements ◽  
Test Procedures ◽  
Coagulation Activity ◽  
Close Relationship ◽  
Measured Activity ◽  
Test Materials ◽  
The Difference ◽  
The Stability ◽  
The One

SummaryIn 4 collaborative trials, involving a varying number of hospital laboratories in the Stockholm area, the coagulation activity of different test materials was estimated with the one-stage prothrombin tests routinely used in the laboratories, viz. Normotest, Simplastin-A and Thrombotest. The test materials included different batches of a lyophilized reference plasma, deep-frozen specimens of diluted and undiluted normal plasmas, and fresh and deep-frozen specimens from patients on long-term oral anticoagulant therapy.Although a close relationship was found between different methods, Simplastin-A gave consistently lower values than Normotest, the difference being proportional to the estimated activity. The discrepancy was of about the same magnitude on all the test materials, and was probably due to a divergence between the manufacturers’ procedures used to set “normal percentage activity”, as well as to a varying ratio of measured activity to plasma concentration. The extent of discrepancy may vary with the batch-to-batch variation of thromboplastin reagents.The close agreement between results obtained on different test materials suggests that the investigated reference plasma could be used to calibrate the examined thromboplastin reagents, and to compare the degree of hypocoagulability estimated by the examined PIVKA-insensitive thromboplastin reagents.The assigned coagulation activity of different batches of the reference plasma agreed closely with experimentally obtained values. The stability of supplied batches was satisfactory as judged from the reproducibility of repeated measurements. The variability of test procedures was approximately the same on different test materials.

Structure, Stability and Water Adsorption on Ultra-Thin TiO2 Supported on TiN

2019 ◽  
Author(s):  
Jose Julio Gutierrez Moreno ◽  
Marco Fronzi ◽  
Pierre Lovera ◽  
alan O'Riordan ◽  
Mike J Ford ◽  
...  
Keyword(s):  
Density Functional ◽  
Water Adsorption ◽  
Chemical Potential ◽  
Energy Gap ◽  
Molecular Water ◽  
Structure Stability ◽  
Ambient Conditions ◽  
Rutile Structure ◽  
The Stability ◽  
The One

<p></p><p>Interfacial metal-oxide systems with ultrathin oxide layers are of high interest for their use in catalysis. In this study, we present a density functional theory (DFT) investigation of the structure of ultrathin rutile layers (one and two TiO<sub>2</sub> layers) supported on TiN and the stability of water on these interfacial structures. The rutile layers are stabilized on the TiN surface through the formation of interfacial Ti–O bonds. Charge transfer from the TiN substrate leads to the formation of reduced Ti<sup>3+</sup> cations in TiO<sub>2.</sub> The structure of the one-layer oxide slab is strongly distorted at the interface, while the thicker TiO<sub>2</sub> layer preserves the rutile structure. The energy cost for the formation of a single O vacancy in the one-layer oxide slab is only 0.5 eV with respect to the ideal interface. For the two-layer oxide slab, the introduction of several vacancies in an already non-stoichiometric system becomes progressively more favourable, which indicates the stability of the highly non-stoichiometric interfaces. Isolated water molecules dissociate when adsorbed at the TiO<sub>2</sub> layers. At higher coverages the preference is for molecular water adsorption. Our ab initio thermodynamics calculations show the fully water covered stoichiometric models as the most stable structure at typical ambient conditions. Interfacial models with multiple vacancies are most stable at low (reducing) oxygen chemical potential values. A water monolayer adsorbs dissociatively on the highly distorted 2-layer TiO<sub>1.75</sub>-TiN interface, where the Ti<sup>3+</sup> states lying above the top of the valence band contribute to a significant reduction of the energy gap compared to the stoichiometric TiO<sub>2</sub>-TiN model. Our results provide a guide for the design of novel interfacial systems containing ultrathin TiO<sub>2</sub> with potential application as photocatalytic water splitting devices.</p><p></p>

scholarly journals Stability of a one-dimensional morphoelastic model for post-burn contraction

2021 ◽  
Vol 83 (3) ◽  
Author(s):  
Ginger Egberts ◽  
Fred Vermolen ◽  
Paul van Zuijlen
Keyword(s):  
Wound Healing ◽  
Residual Stresses ◽  
Truncation Error ◽  
Signaling Molecules ◽  
Discrete Problem ◽  
One Dimensional ◽  
Stability Constraint ◽  
Biological Interpretation ◽  
The Stability ◽  
The One

AbstractTo deal with permanent deformations and residual stresses, we consider a morphoelastic model for the scar formation as the result of wound healing after a skin trauma. Next to the mechanical components such as strain and displacements, the model accounts for biological constituents such as the concentration of signaling molecules, the cellular densities of fibroblasts and myofibroblasts, and the density of collagen. Here we present stability constraints for the one-dimensional counterpart of this morphoelastic model, for both the continuous and (semi-) discrete problem. We show that the truncation error between these eigenvalues associated with the continuous and semi-discrete problem is of order $${{\mathcal {O}}}(h^2)$$ O ( h 2 ) . Next we perform numerical validation to these constraints and provide a biological interpretation of the (in)stability. For the mechanical part of the model, the results show the components reach equilibria in a (non) monotonic way, depending on the value of the viscosity. The results show that the parameters of the chemical part of the model need to meet the stability constraint, depending on the decay rate of the signaling molecules, to avoid unrealistic results.

scholarly journals Wet Drilled Cuttings Bed Rheology

Energies ◽  
2021 ◽  
Vol 14 (6) ◽  
pp. 1644
Author(s):  
Camilo Pedrosa ◽  
Arild Saasen ◽  
Bjørnar Lund ◽  
Jan David Ytrehus
Keyword(s):  
Drilling Fluid ◽  
Drilling Fluids ◽  
Parallel Plates ◽  
Single Particles ◽  
Cuttings Transport ◽  
Transport Studies ◽  
Water Based ◽  
Fluid Properties ◽  
External Forces ◽  
Cuttings Bed

The cuttings transport efficiency of various drilling fluids has been studied in several approaches. This is an important aspect, since hole cleaning is often a bottleneck in well construction. The studies so far have targeted the drilling fluid cuttings’ transport capability through experiments, simulations or field data. Observed differences in the efficiency due to changes in the drilling fluid properties and compositions have been reported but not always fully understood. In this study, the cuttings bed, wetted with a single drilling fluid, was evaluated. The experiments were performed with parallel plates in an Anton Paar Physica 301 rheometer. The results showed systematic differences in the internal friction behaviors between tests of beds with oil-based and beds with water-based fluids. The observations indicated that cutting beds wetted with a polymeric water-based fluid released clusters of particles when external forces overcame the bonding forces and the beds started to break up. Similarly, it was observed that an oil-based fluid wetted bed allowed particles to break free as single particles. These findings may explain the observed differences in previous cutting transport studies.

scholarly journals One-Dimensional Organic–Inorganic Material (C6H9N2)2BiCl5: From Synthesis to Structural, Spectroscopic, and Electronic Characterizations

2021 ◽  
Vol 22 (4) ◽  
pp. 2030
Author(s):  
Hela Ferjani ◽  
Hammouda Chebbi ◽  
Mohammed Fettouhi
Keyword(s):  
Hydrogen Bonding ◽  
Density Functional ◽  
Crystal Packing ◽  
Diffuse Reflectance Spectrum ◽  
Enrichment Ratio ◽  
One Dimensional ◽  
Organic Part ◽  
Fukui Indices ◽  
The Stability ◽  
The One

The new organic–inorganic compound (C6H9N2)2BiCl5 (I) has been grown by the solvent evaporation method. The one-dimensional (1D) structure of the allylimidazolium chlorobismuthate (I) has been determined by single crystal X-ray diffraction. It crystallizes in the centrosymmetric space group C2/c and consists of 1-allylimidazolium cations and (1D) chains of the anion BiCl52−, built up of corner-sharing [BiCl63−] octahedra which are interconnected by means of hydrogen bonding contacts N/C–H⋯Cl. The intermolecular interactions were quantified using Hirshfeld surface analysis and the enrichment ratio established that the most important role in the stability of the crystal structure was provided by hydrogen bonding and H···H interactions. The highest value of E was calculated for the contact N⋯C (6.87) followed by C⋯C (2.85) and Bi⋯Cl (2.43). These contacts were favored and made the main contribution to the crystal packing. The vibrational modes were identified and assigned by infrared and Raman spectroscopy. The optical band gap (Eg = 3.26 eV) was calculated from the diffuse reflectance spectrum and showed that we can consider the material as a semiconductor. The density functional theory (DFT) has been used to determine the calculated gap, which was about 3.73 eV, and to explain the electronic structure of the title compound, its optical properties, and the stability of the organic part by the calculation of HOMO and LUMO energy and the Fukui indices.

scholarly journals Real-Time Measurement of Drilling Fluid Rheological Properties: A Review

Sensors ◽  
2021 ◽  
Vol 21 (11) ◽  
pp. 3592
Author(s):  
Naipeng Liu ◽  
Di Zhang ◽  
Hui Gao ◽  
Yule Hu ◽  
Longchen Duan
Keyword(s):  
Decision Making ◽  
Rheological Properties ◽  
Real Time ◽  
Drilling Fluid ◽  
Time Measurement ◽  
Decision Making Process ◽  
Rate Of Penetration ◽  
The Real ◽  
Real Time Measurement ◽  
Fluid Properties

The accurate and frequent measurement of the drilling fluid’s rheological properties is essential for proper hydraulic management. It is also important for intelligent drilling, providing drilling fluid data to establish the optimization model of the rate of penetration. Appropriate drilling fluid properties can improve drilling efficiency and prevent accidents. However, the drilling fluid properties are mainly measured in the laboratory. This hinders the real-time optimization of drilling fluid performance and the decision-making process. If the drilling fluid’s properties cannot be detected and the decision-making process does not respond in time, the rate of penetration will slow, potentially causing accidents and serious economic losses. Therefore, it is important to measure the drilling fluid’s properties for drilling engineering in real time. This paper summarizes the real-time measurement methods for rheological properties. The main methods include the following four types: an online rotational Couette viscometer, pipe viscometer, mathematical and physical model or artificial intelligence model based on a Marsh funnel, and acoustic technology. This paper elaborates on the principle, advantages, limitations, and usage of each method. It prospects the real-time measurement of drilling fluid rheological properties and promotes the development of the real-time measurement of drilling rheological properties.

A TWELFTH-ORDER FOUR-STEP FORMULA FOR THE NUMERICAL INTEGRATION OF THE ONE-DIMENSIONAL SCHRÖDINGER EQUATION

2003 ◽  
Vol 14 (08) ◽  
pp. 1087-1105 ◽  
Author(s):  
ZHONGCHENG WANG ◽  
YONGMING DAI
Keyword(s):  
Schrödinger Equation ◽  
Numerical Integration ◽  
Schrodinger Equation ◽  
Numerical Test ◽  
New Method ◽  
Step Method ◽  
One Dimensional ◽  
The Stability ◽  
The One ◽  
Order Four

A new twelfth-order four-step formula containing fourth derivatives for the numerical integration of the one-dimensional Schrödinger equation has been developed. It was found that by adding multi-derivative terms, the stability of a linear multi-step method can be improved and the interval of periodicity of this new method is larger than that of the Numerov's method. The numerical test shows that the new method is superior to the previous lower orders in both accuracy and efficiency and it is specially applied to the problem when an increasing accuracy is requested.

First Principles Investigation of the Stability and the Chemical Behavior of Hydrogen in ThCoH4

2011 ◽  
Vol 66 (3) ◽  
pp. 269-274
Author(s):  
Samir F. Matar
Keyword(s):  
Negative Charge ◽  
Geometry Optimization ◽  
Full Geometry Optimization ◽  
Intermetallic Matrix ◽  
Charge Analysis ◽  
The Stability ◽  
The One ◽  
Site Selective ◽  
Bader Charge Analysis ◽  
Positively Charged

We address the changes in the electronic structure brought by the insertion of hydrogen into ThCo leading to the experimentally observed ThCoH4. Full geometry optimization positions the hydrogen in three sites stabilized in the expanded intermetallic matrix. From a Bader charge analysis, hydrogen is found to be in a narrow iono-covalent (~−0.6) to covalent (~−0.3) bonding which should enable site-selective desorption. The overall chemical picture shows a positively charged Thδ+ with the negative charge redistributed over a complex anion {CoH4}δ− with δ~1.8. Nevertheless this charge transfer remains far from the one in the more ionic hydridocobaltate anion CoH54− in Mg2CoH5, due to the largely electropositive character of Mg.

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