scholarly journals Solvent Extraction of Scandium and Yttrium Using Carboxylic Acid

2021 ◽  
Vol 333 ◽  
pp. 04010
Author(s):  
Jeong-Yi Moon ◽  
Syouhei Nishihama ◽  
Kazuharu Yoshizuka
Keyword(s):  
Solvent Extraction ◽  
Analysis Method ◽  
Adsorption Model ◽  
Organic Solution ◽  
Extraction Equilibrium ◽  
Langmuir Adsorption ◽  
Langmuir Adsorption Model ◽  
Slope Analysis ◽  
Impregnated Resin ◽  
Aqueous Chloride

Separation of scandium (Sc) from yttrium (Y) in aqueous chloride media by solvent extraction using Versatic acid 10 was investigated. Conventional slope analysis method revealed the extraction equilibrium formulation of the metals. Sc is more strongly extracted than Y by Versatic acid 10, and the separation factor of the metals is quite high at 1.93 × 104. Complete stripping of Sc from the loaded organic solution of Versatic acid 10 was achieved by 3M HCl solution. Then Versatic acid 10 was applied to solvent impregnated resin (SIR), separation of Sc was progressed via Langmuir adsorption model.

scholarly journals Determination of the absolute CH4 adsorption using simplified local density theory and comparison with the modified Langmuir adsorption model

RSC Advances ◽  
2018 ◽  
Vol 8 (72) ◽  
pp. 41509-41516
Author(s):  
Yeyu Zhang ◽  
Shaonan Zhang ◽  
Zhicheng Wang ◽  
Hucheng Deng ◽  
Minghui Qi ◽  
...  
Keyword(s):  
Shale Gas ◽  
Local Density ◽  
Gas Storage ◽  
Adsorption Model ◽  
Gas Reservoirs ◽  
Methane Recovery ◽  
Langmuir Adsorption ◽  
Langmuir Adsorption Model ◽  
Ch4 Adsorption

Accurately determining the adsorbed amount of CH4 on shale is significant for understanding the mechanisms of shale gas storage and shale methane recovery from shale gas reservoirs.

Investigation of Ultrasonic Effects in Cotton Dyeing Processing

2013 ◽  
Vol 787 ◽  
pp. 138-142 ◽  
Author(s):  
De Shuai Sun ◽  
Long Fang ◽  
Tao Liu
Keyword(s):  
Cotton Fiber ◽  
Ultrasound Irradiation ◽  
Cotton Fabrics ◽  
Dye Uptake ◽  
Adsorption Model ◽  
Langmuir Adsorption ◽  
Langmuir Adsorption Model ◽  
Dyeing Process ◽  
Direct Dye ◽  
Ultrasound Dyeing

Ultrasound can promote the dye-uptake in the dyeing process. The effects of ultrasound on the fiber, dye and dyeing system were investigated by dyeing cotton fabrics with a direct dye. The dye exhaustion exceeded 80% in 30 minutes with the assistant of ultrasound. Langmuir adsorption model could descript the ultrasound dyeing process of direct dye. The area of fiber accessibility of cotton fiber increased 1.68 times under the action of ultrasound. The absorbance of direct dye solution increased remarkably in the first 10 minutes of ultrasound irradiation. Ultrasound accelerated the diffusion of dye on cotton fiber, and then the diffusion coefficient increased 46 times

scholarly journals A three-site Langmuir adsorption model to elucidate the temperature, pressure, and support dependence of the hydrogen coverage on supported Pt particles

2007 ◽  
Vol 245 (2) ◽  
pp. 415-427 ◽  
Author(s):  
Y JI ◽  
V KOOT ◽  
A VANDEREERDEN ◽  
B WECKHUYSEN ◽  
D KONINGSBERGER ◽  
...  
Keyword(s):  
Adsorption Model ◽  
Langmuir Adsorption ◽  
Langmuir Adsorption Model

scholarly journals Molten solvent extraction behavior of palladium with 1-phenyl-3-methyl-4-benzoyl-5-pyrazolone at 60 °C

2007 ◽  
Vol 5 (3) ◽  
pp. 912-921 ◽  
Author(s):  
Bo Peng ◽  
Xiaojun Guo ◽  
Xuefen Mao ◽  
Jinzhang Gao
Keyword(s):  
Solvent Extraction ◽  
Precious Metal ◽  
Extraction Efficiency ◽  
Equilibrium Temperature ◽  
Paraffin Wax ◽  
Analysis Method ◽  
Extractant Concentration ◽  
Slope Analysis ◽  
Extraction Behavior ◽  
Ph Range

AbstractThe solvent extraction behavior of precious metal palladium with 1-phenyl-3-methyl-4-benzoyl-5-pyrazone (PMBP) into molten paraffin wax has been studied in the temperature range from 55 to 75 °C. The complex consisting of PMBP and palladium was extracted into molten wax phase in the pH range from 1.0 to 3.5 at 60 °C. The extraction efficiency was up to 97% at the experimental pH. The stoichiometry of the extracted species of palladium was determined on the basis of slope analysis method. The effects of time to achieve equilibrium, temperature, and extractant concentration on the extraction were discussed. The thermodynamic data indicate that the extraction is an endothermic reaction and the increase of temperature promotes the extraction of palladium into molten paraffin wax and the extraction of palladium with PMBP is entropy controlled at high temperatures.

scholarly journals Aizoon Extract As a Novel Eco-friendly Corrosion Inhibitor For Stainless Steel430 in HCl Solution

2021 ◽  
Author(s):  
Ahmed F. Molouk ◽  
Mohamed F. Atia ◽  
Abd El-Aziz S. Fouda
Keyword(s):  
Mixed Type ◽  
Electrochemical Impedance ◽  
Theoretical Data ◽  
Cathodic Reaction ◽  
Mass Reduction ◽  
Adsorption Model ◽  
Langmuir Adsorption ◽  
Langmuir Adsorption Model ◽  
Hcl Solution ◽  
Mixed Type Inhibitor

Abstract Aizoon extract used as anti-corrosion for stainless steel430 (SS430) in 2M hydrochloric acid solution. The mass reduction, electrochemical impedance, and potentiodynamic polarization were carried out to demonstrate the performance of Aizoon extract as corrosion resistance for SS430. Polarization revealed that the Aizoon extract is mixed type inhibitor with superiority to inhibiting the cathodic reaction. The inhibition percentage reaches 93% at 300 ppm extract. Adsorption of the extract on SS430 surface is regular with Langmuir adsorption model. Thermodynamic factors for adsorption and activation processes for SS430 dissolution were estimated and discussed. Furthermore, the SS430 surface is characterized using different techniques. The surface morphology of SS430 was tested utilizing several techniques. The experimental data were supported by the theoretical data.

Pumping Effect of Slider Air Bearing Surface for Non-Langmuir Adsorption

2010 ◽  
Author(s):  
Bo Zhang ◽  
Akira Nakajima
Keyword(s):  
Disk Surface ◽  
Air Bearing ◽  
Head Disk Interface ◽  
Bearing Surface ◽  
Adsorption Model ◽  
Adsorbed Film ◽  
Disk Interface ◽  
Langmuir Adsorption ◽  
Langmuir Adsorption Model ◽  
Slider Air Bearing

Numerical analysis of the adsorbed film thickness at the air bearing surface is conducted using the non-Langmuir adsorption model. It is found that the adsorbed film at the air bearing surface becomes significant when the viscosity of adsorbed film is higher than about 1 Pa s. The adsorbed contaminant will accumulate at the rear end of the slider, and it is possible that the accumulated liquid-like contaminant may form a liquid tail which will directly contact with the disk surface, resulting in a crush of the head/disk interface.

Measurement of DNA Hybridization by Nano-Deformation of Microcantilever in CMOS Biosensor

2008 ◽  
Author(s):  
S. M. Yang ◽  
T. I. Yin ◽  
C. Chang
Keyword(s):  
Dna Hybridization ◽  
Layer Structure ◽  
Cmos Process ◽  
Insulation Layer ◽  
Adsorption Model ◽  
Nucleotide Polymorphism ◽  
Langmuir Adsorption ◽  
Langmuir Adsorption Model ◽  
Biosensor Chip

A 1 cm × 1 cm biosensor chip for analyzing DNA hybridization is developed by CMOS process. The sensor chip has 6 measurement regions, each region with 3 pairs of parallel microcantilever of 125 × 60 × 0.75μm. The microcantilever is a 4-layer structure composed of an immobilized surface layer, a top insulation layer, an embedded piezoresistive layer, and a bottom insulation layer to measure the nano-deformation induced by the surface-assemble monolayer of alkanethiols on Au. By the Langmuir adsorption model, the estimated adsorption rate of the ssDNA is 0.005sec−1. The design has intrinsic sensitivity needed in biochemical applications such as detecting nucleotide polymorphism and single base mutation to sequence DNA. The capability of in-situ, multipoint measurement promise many frontiers to be explored.

scholarly journals Extraction and separation of U(VI) and Th(IV) from hydrobromic acid media using Cyanex-923 extractant

2010 ◽  
Vol 75 (11) ◽  
pp. 1549-1557 ◽  
Author(s):  
Snehal Ghag ◽  
Suresh Pawar
Keyword(s):  
Solvent Extraction ◽  
Metal Ions ◽  
Organic Phase ◽  
Phosphine Oxide ◽  
Hydrobromic Acid ◽  
Analysis Method ◽  
Acid Media ◽  
Extraction And Separation ◽  
Slope Analysis ◽  
Cyanex 923

A systematic study of the solvent extraction of uranium(VI) and thorium(IV) from hydrobromic acid media was performed using the neutral phosphine oxide extractant Cyanex-923 in toluene. These metal ions were found to be quantitatively extracted with Cyanex-923 in toluene in the acidity range 5x10-5-1x10-4 M and 5x10-5-5x10-3 M, respectively, and they are stripped from the organic phase with 7.0 M HClO4 and 2.0- 4.0 M HCl, respectively. The effect of the equilibrium period, diluents, diverse ions and stripping agent on the extraction of U(VI) and Th(IV) was studied. The stoichiometry of the extracted species of these metal ions was determined based on the slope analysis method. The extraction reactions proceed by solvation and their probable extracted species found in the organic phase were UO2Br2?2Cyanex-923 and ThBr4?2Cyanex-923. Based on these results, a sequential procedure for their separation from each other was developed.

scholarly journals ADSORPTION MODEL OF Mn2+, Cd2+ and Hg2+ IN THE WATER - SEDIMENT SYSTEMS ALONG CODE RIVER, YOGYAKARTA

2010 ◽  
Vol 8 (3) ◽  
pp. 314-319 ◽  
Author(s):  
Muzakky Muzakky
Keyword(s):  
Metal Ions ◽  
Adsorption Energy ◽  
Initial Condition ◽  
Adsorption Model ◽  
River Dynamics ◽  
Binding Strength ◽  
Langmuir Adsorption ◽  
Langmuir Adsorption Model ◽  
Isotherm Adsorption ◽  
Adsorption Energies

Prediction of adsorption model of Mn2+, Cd2+ and Hg2+ in water-sediment systems along Code River, Yogyakarta has been experimentally investigated. The aim of this investigation is to predict the transfer models based on isotherm adsorption of Mn2+, Cd2+ and Hg2+ metal ions from water into sediment. In addition, this investigation is expected to be able to inform the initial condition of Code River, dynamics, and the fate of Mn2+, Cd2+ and Hg2+ ions from upstream to downstream. Based on the investigation the transfer of Mn2+, and Cd2+ ions into sediment follows Langmuir adsorption model, with the coefficient determination (R2) of 0,9916 and 0,9799, while the value of the adsorption energy are 20,95 kJ/mol and 16,85 kJ/mol. The transfer of Hg2+ ion tend to follow Freundlich adsorption model. From the adsorption energies, it is proven  that Mn2+ ion was chemically sorpted into the sediment, while Cd2+ ion will tend to be physically sorpted into the sediment. The binding strength of which ise in the order of Mn2+ > Cd2+ and the adsorption energy of Hg2+ ion could not be determined.   Keywords: adsorption model, chemically sorpted, physically sorpted

Adsorption of Lead (II) in Liquid-Solid Interfaces on Natural and Modified Hydroxyapatite

2016 ◽  
Vol 721 ◽  
pp. 117-122 ◽  
Author(s):  
Samia Benhammadi ◽  
Andrei Shishkin ◽  
Abdelkader Iddou ◽  
Hakim Aguedal ◽  
Louis Charles de Menorval
Keyword(s):  
Heavy Metals ◽  
Lactic Acid ◽  
Extraction Method ◽  
Room Temperature ◽  
Adsorption Model ◽  
Initial Concentration ◽  
Langmuir Adsorption ◽  
Langmuir Adsorption Model ◽  
Adsorption Capacities ◽  
Different Temperatures

The removal of lead from aqueous solutions was studied using the liquid-solid extraction method. The solids used are the crude phosphocalcic hydroxapatite [Ca10(PO4)6(OH)2] (HAPc), and phosphocalcic hydroxapatite treated with 5 % lactic acid solution (HAPal). The extraction results showed the influence of the initial concentration of Pb (II) and temperature of the suspensions. The maximum adsorption capacities of each material (HAPc and HAPal) were obtained with the application of Langmuir adsorption model. The most important quantity was founded as 41,84mg/g for HAPal. Isotherms established at different temperatures showed that this parameter affects greatly the adsorption of Pb (II) on both adsorbents. The best results were obtained at room temperature (25°C) compared with those recorded at 50°C.Finally, the results of this study allow us to note that the hydroxiapatite material can be as good extractant solid, for heavy metals, especially when it is modified with lactic acid.

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