Scaling properties of induction times in heterogeneous nucleation

1991 ◽  
Vol 95 (12) ◽  
pp. 9148-9150 ◽  
Author(s):  
Vitaly A. Shneidman ◽  
Michael C. Weinberg
Keyword(s):  
Heterogeneous Nucleation ◽  
Scaling Properties ◽  
Induction Times

scholarly journals Heterogeneous Nucleation of Calcium Oxalate on Native Oxide Surfaces

1994 ◽  
Vol 346 ◽  
Author(s):  
Lin Song ◽  
Michael J. Pattillo ◽  
Gordon L. Graff ◽  
Allison A. Campbell ◽  
Bruce C. Bunker
Keyword(s):  
Calcium Oxalate ◽  
Heterogeneous Nucleation ◽  
Biomimetic Synthesis ◽  
Native Oxide ◽  
Oxide Surfaces ◽  
Constant Composition ◽  
Ceramic Thin Films ◽  
Atomic Force ◽  
Induction Times ◽  
Better Than

ABSTRACTThe aqueous deposition of calcium oxalate onto colloidal oxides has been studied as a model system for understanding heterogeneous nucleation processes of importance in biomimetic synthesis of ceramic thin films. Calcium oxalate nucleation has been monitored by measuring induction times for nucleation using Constant Composition techniques and by measuring nucleation densities on extended oxide surfaces using an atomic force microscope. Results show that the dependence of calcium oxalate nucleation on solution supersaturation fits the functional form predicted by classical nucleation theories. Anionic surfaces appear to promote nucleation better than cationic surfaces, lowering the effective energy barrier to heterogeneous nucleation.

Integrated Fractional white Noise as an Alternative to Multifractional Brownian Motion

2007 ◽  
Vol 44 (02) ◽  
pp. 393-408 ◽  
Author(s):  
Allan Sly
Keyword(s):  
Stochastic Process ◽  
Brownian Motion ◽  
White Noise ◽  
Gaussian Process ◽  
Discrete Data ◽  
Hölder Exponent ◽  
Scaling Properties ◽  
Multifractional Brownian Motion ◽  
Local Properties

Multifractional Brownian motion is a Gaussian process which has changing scaling properties generated by varying the local Hölder exponent. We show that multifractional Brownian motion is very sensitive to changes in the selected Hölder exponent and has extreme changes in magnitude. We suggest an alternative stochastic process, called integrated fractional white noise, which retains the important local properties but avoids the undesirable oscillations in magnitude. We also show how the Hölder exponent can be estimated locally from discrete data in this model.

Amorphous silica coating on α-alumina particles

1995 ◽  
Vol 53 ◽  
pp. 210-211
Author(s):  
J. W. Mellowes ◽  
C. M. Chun ◽  
I. A. Aksay
Keyword(s):  
Amorphous Silica ◽  
Heterogeneous Nucleation ◽  
Homogeneous Nucleation ◽  
Silica Coating ◽  
Full Density ◽  
Optimal Conditions ◽  
Fine Grained ◽  
Alumina Particles ◽  
Complete Mullitization ◽  
Powder Compacts

Mullite (3Al2O32SiO2) can be fabricated by transient viscous sintering using composite particles which consist of inner cores of a-alumina and outer coatings of amorphous silica. Powder compacts prepared with these particles are sintered to almost full density at relatively low temperatures (~1300°C) and converted to dense, fine-grained mullite at higher temperatures (>1500°C) by reaction between the alumina core and the silica coating. In order to achieve complete mullitization, optimal conditions for coating alumina particles with amorphous silica must be achieved. Formation of amorphous silica can occur in solution (homogeneous nucleation) or on the surface of alumina (heterogeneous nucleation) depending on the degree of supersaturation of the solvent in which the particles are immersed. Successful coating of silica on alumina occurs when heterogeneous nucleation is promoted and homogeneous nucleation is suppressed. Therefore, one key to successful coating is an understanding of the factors such as pH and concentration that control silica nucleation in aqueous solutions. In the current work, we use TEM to determine the optimal conditions of this processing.

scholarly journals Strain-induced variant selection in heterogeneous nucleation of α -Ti at screw dislocations in β -Ti

2018 ◽  
Vol 2 (8) ◽  
Author(s):  
Max Poschmann ◽  
Joseph Lin ◽  
Henry Geerlings ◽  
Ian S. Winter ◽  
D. C. Chrzan
Keyword(s):  
Heterogeneous Nucleation ◽  
Variant Selection ◽  
Screw Dislocations

scholarly journals First Principle Study of TiB2 (0001)/γ-Fe (111) Interfacial Strength and Heterogeneous Nucleation

Materials ◽  
2021 ◽  
Vol 14 (6) ◽  
pp. 1573
Author(s):  
Qin Wang ◽  
Peikang Bai ◽  
Zhanyong Zhao
Keyword(s):  
Stainless Steel ◽  
Heterogeneous Nucleation ◽  
316L Stainless Steel ◽  
Interfacial Strength ◽  
Interface Energy ◽  
Interface Fracture ◽  
Partial Density ◽  
Covalent Bonds ◽  
Tib2 Particles ◽  
Adhesion Work

TiB2/316L stainless steel composites were prepared by selective laser melting (SLM), and the adhesion work, interface energy and electronic structure of TiB2/γ-Fe interface in TiB2/316L stainless steel composites were investigated to explore the heterogeneous nucleation potential of γ-Fe grains on TiB2 particles using first principles. Six interface models composed of three different stacking positions and two different terminations were established. The B-terminated-top 2 site interface (“B-top 2”) was the most stable because of the largest adhesion work, smallest interfacial distances, and smallest interfacial energy. The difference charge density and partial density of states indicated that a large number of strong Fe-B covalent bonds were formed near the “B-top 2” interface, which increased the stability of interface. Fracture analysis revealed that the bonding strength of the “B-top 2” interface was higher than that of the Fe matrix, and it was difficult to fracture at the interface. The interface energy at the Ti-poor position in the “B-top 2” interface model was smaller than that of the γ-Fe/Fe melt, indicating that TiB2 had strong heterogeneous nucleation potency for γ-Fe.

scholarly journals From Center-Vortex Ensembles to the Confining Flux Tube

Universe ◽  
2021 ◽  
Vol 7 (8) ◽  
pp. 253
Author(s):  
David R. Junior ◽  
Luis E. Oxman ◽  
Gustavo M. Simões
Keyword(s):  
Degrees Of Freedom ◽  
String Tension ◽  
Effective Field ◽  
Scaling Properties ◽  
Flux Tubes ◽  
Topological Solitons ◽  
Yang Mills ◽  
Center Vortex ◽  
Asymptotic Scaling ◽  
The Continuum

In this review, we discuss the present status of the description of confining flux tubes in SU(N) pure Yang–Mills theory in terms of ensembles of percolating center vortices. This is based on three main pillars: modeling in the continuum the ensemble components detected in the lattice, the derivation of effective field representations, and contrasting the associated properties with Monte Carlo lattice results. The integration of the present knowledge about these points is essential to get closer to a unified physical picture for confinement. Here, we shall emphasize the last advances, which point to the importance of including the non-oriented center-vortex component and non-Abelian degrees of freedom when modeling the center-vortex ensemble measure. These inputs are responsible for the emergence of topological solitons and the possibility of accommodating the asymptotic scaling properties of the confining string tension.

scholarly journals Non-Isothermal Crystallization Kinetics of Poly(Ethylene Glycol)–Poly(l-Lactide) Diblock Copolymer and Poly(Ethylene Glycol) Homopolymer via Fast-Scan Chip-Calorimeter

Polymers ◽  
2021 ◽  
Vol 13 (7) ◽  
pp. 1156
Author(s):  
Dejia Chen ◽  
Lisha Lei ◽  
Meishuai Zou ◽  
Xiaodong Li
Keyword(s):  
Ethylene Glycol ◽  
Heterogeneous Nucleation ◽  
Isothermal Crystallization ◽  
Crystallization Process ◽  
Poly Ethylene Glycol ◽  
Ozawa Method ◽  
Isothermal Crystallization Kinetics ◽  
Fast Cooling ◽  
Poly Ethylene ◽  
Kinetics Of

The non-isothermal crystallization kinetics of double-crystallizable poly(ethylene glycol)–poly(l-lactide) diblock copolymer (PEG-PLLA) and poly(ethylene glycol) homopolymer (PEG) were studied using the fast cooling rate provided by a Fast-Scan Chip-Calorimeter (FSC). The experimental data were analyzed by the Ozawa method and the Kissinger equation. Additionally, the total crystallization rate was represented by crystallization half time t1/2. The Ozawa method is a perfect success because secondary crystallization is inhibited by using fast cooling rate. The first crystallized PLLA block provides nucleation sites for the crystallization of PEG block and thus promotes the crystallization of the PEG block, which can be regarded as heterogeneous nucleation to a certain extent, while the method of the PEG block and PLLA block crystallized together corresponds to a one-dimensional growth, which reflects that there is a certain separation between the crystallization regions of the PLLA block and PEG block. Although crystallization of the PLLA block provides heterogeneous nucleation conditions for PEG block to a certain extent, it does not shorten the time of the whole crystallization process because of the complexity of the whole crystallization process including nucleation and growth.

scholarly journals Robust and efficient hydrogenation of carbonyl compounds catalysed by mixed donor Mn(I) pincer complexes

2021 ◽  
Vol 12 (1) ◽  
Author(s):  
Wenjun Yang ◽  
Ivan Yu. Chernyshov ◽  
Robin K. A. van Schendel ◽  
Manuela Weber ◽  
Christian Müller ◽  
...  
Keyword(s):  
Noble Metal ◽  
Crucial Role ◽  
Carbonyl Compounds ◽  
Catalytic Performance ◽  
Hydrogen Atmosphere ◽  
Pincer Complexes ◽  
Catalyst Activation ◽  
Hydrogenation Catalysts ◽  
Induction Times

AbstractAny catalyst should be efficient and stable to be implemented in practice. This requirement is particularly valid for manganese hydrogenation catalysts. While representing a more sustainable alternative to conventional noble metal-based systems, manganese hydrogenation catalysts are prone to degrade under catalytic conditions once operation temperatures are high. Herein, we report a highly efficient Mn(I)-CNP pre-catalyst which gives rise to the excellent productivity (TOF° up to 41 000 h−1) and stability (TON up to 200 000) in hydrogenation catalysis. This system enables near-quantitative hydrogenation of ketones, imines, aldehydes and formate esters at the catalyst loadings as low as 5–200 p.p.m. Our analysis points to the crucial role of the catalyst activation step for the catalytic performance and stability of the system. While conventional activation employing alkoxide bases can ultimately provide catalytically competent species under hydrogen atmosphere, activation of Mn(I) pre-catalyst with hydride donor promoters, e.g. KHBEt3, dramatically improves catalytic performance of the system and eliminates induction times associated with slow catalyst activation.

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