The influence of the unipolar corona discharge on surface energy of modified cardboard

2019 ◽  
Author(s):  
S. I. Basyrova ◽  
M. F. Galikhanov ◽  
I. F. Shaymukhametova ◽  
S. A. Bogdanova
2011 ◽  
Vol 69 (4) ◽  
pp. 284-290 ◽  
Author(s):  
Hafiz Z. Alisoy ◽  
Ali Yesil ◽  
Murat Koseoglu ◽  
Ibrahim Unal

2021 ◽  
Vol 2064 (1) ◽  
pp. 012026
Author(s):  
B A Kozlov ◽  
D S Makhanko

Abstract This article presents the results of “electrical wind” investigations in CO2–laser mixtures at superatmospheric (1–12 atm) pressures. It is established that for a fixed value of the unipolar corona discharge current, the gas flow velocity does not depend on the pressure, but is determined by the chemical composition of the working mixture. The maximum values of the “electrical wind” velocity are achieved in carbon dioxide and molecular nitrogen and their values are 3.2 and 2.9 ms−1. In typical laser mixtures CO2:N2:He = 1:1:1 – 1:1:3 the velocity of the “electrical wind ” are in the range from 2.5 to 1.5 ms−.


2020 ◽  
pp. 30-37
Author(s):  
I. G. Shaikhiev ◽  
◽  
V. O. Dryakhlov ◽  
M. F. Galikhanov ◽  
D. D. Fazullin ◽  
...  

It is investigated the influence of the parameters of the unipolar corona discharge (the treatment time, voltage) on the performance and selectivity of separation of model emulsions “oil in water” based on the oil in the Devonian deposits Tomatocage field (Republic of Tatarstan) using polyacrylonitrile membranes with a molecular weight cut-off of 60 kDa particles. Determined COD values of the original emulsions and filtrates. The values of the processing time (30 seconds) and voltage of the corona (5 kV) membranes, which achieved the best performance and selectivity of the separation process of oil-water emulsion. Sitting drop methods, x-ray diffraction and atomic force microscopy showed changes of the surface structure and internal structure of treated membrane. In particular, there was decrease in the wetting angle from 45.1 to 43.3 and an increase in the degree of crystallinity from 0.15 to 0.18, which is due to the flow on the surface of PES membrane processes of etching and oxidation resulting from exposure to a unipolar corona discharge ozone, which is also confirmed by images of the surface of the filter elements and the histograms of the topography, based on which it showed a decrease in height and number of protrusions from 42 nm and 7500 to 10 nm and 2500.


1997 ◽  
Vol 27 (6) ◽  
pp. 505-508 ◽  
Author(s):  
Aleksandr K Shuaibov ◽  
Igor' V Shevera ◽  
Arkadii I Dashchenko

2009 ◽  
Vol 81 (3) ◽  
pp. 495-511 ◽  
Author(s):  
Morne Swart ◽  
Peter E. Mallon

Superhydrophobicity is dependent on both the surface energy and the texture of the surface. These factors are discussed in terms of a series of electrospun poly(methyl methacrylate)-graft-poly(dimethylsiloxane) (PMMA-g-PDMS) copolymers with different poly(dimethylsiloxane) (PDMS) content. These copolymers are synthesized via conventional free radical copolymerization of methyl methacrylate (MMA) and monomethacryloxypropyl-terminated PDMS macromonomers. It is shown how these copolymers can be electrospun to produce copolymer fibers with diameters in the 100-1000 nm range. The effect of the copolymer composition (and hence the surface energy) and the electrospinning tip-to-collector distance (TCD) on the fiber morphology is discussed. The surfaces produced by the electrospinning process show superhydrophobic properties where the preferential surface segregation of the PDMS component is combined with the roughness of the fiber surface. The surface energy of the fibers is varied by variation of the PDMS content in the copolymers as well as by post-spinning modification with corona discharge. The hydrophobicity of the surfaces shows a greater dependence on the PDMS content than on the average fiber diameter. After exposure of these fiber surfaces to corona discharge, the initial superhydrophobic surfaces become easily wettable despite the fact that much of the surface roughness is maintained after exposure. The samples show the phenomena of hydrophobocity recovery after corona exposure. The rate and extent of this recovery depends on the PDMS content and the corona exposure time. Despite the recovery, scanning electron microscopy (SEM), swelling measurements, and confocal Raman spectroscopy show that permanent surface changes have taken place. The surfaces do not recover to their original superhydrophobic state.


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