scholarly journals Statistical approaching of sol-gel process in preparation of silica aerogel derived from geothermal silica by several acids

2019 ◽  
Author(s):  
S. Silviana ◽  
Ilham Nur Hakim Rambe ◽  
Hendra Sudrajat ◽  
Mochammad Abdillah Zidan
Keyword(s):  
Silica Aerogel ◽  
Sol Gel ◽  
Sol Gel Process

Preparation of Silica Aerogels Monoliths from Hydrophobic Silica Gels and Pluronic10R5 via Sol–Gel Process

2020 ◽  
Vol 12 (2) ◽  
pp. 206-211
Author(s):  
Supattra Eangpayung ◽  
Supan Yodyingyong ◽  
Darapond Triampo
Keyword(s):  
Mass Loss ◽  
Propylene Oxide ◽  
Silica Aerogel ◽  
Sol Gel ◽  
Silica Aerogels ◽  
Silica Gels ◽  
High Porosity ◽  
Hydrophobic Silica ◽  
Sol Gel Process ◽  
Poly Propylene

Silica aerogel, the most common type of aerogels, comprised of 95% air in its structure which made the aerogel has a high surface area, high porosity, low density, and low thermal conductivity. Because of its structure and high porosity, one of its major weakness compared to other materials is being very brittle. This study aims at strengthening the connection points between silica nanoparticles using Pluronic10R5 (poly(propylene oxide)8–poly(ethylene oxide)22–poly(propylene oxide)8) where the Pluronic10R5 was used to reduce phase separation during the silica condensation reaction in the sol–gel process. Silica aerogel monoliths were prepared via a sol–gel process from hydrophobic silica gels and Pluronic10R5 with an ambient pressure drying (APD) process. Results from the compression test showed that the Pluronic10R5/silica aerogels have improved mechanical property by ten times that of unmodified silica aerogels. A thermogravimetric analysis (TGA) showed a mass loss at 300–400 °C that is attributed to the surface methyl group, while a mass loss at 200 °C refers to the loss of Pluronic10R5 which confirms the incorporation of Pluronic10R5 into the monolith. Moreover, infrared (IR) images revealed that the top surface temperature of Pluronic10R5/silica aerogels monolith is about 80 °C differs from the bottom heat source temperature of 160 °C.

Preparation and Characterization of Ultralow Density Silica Aerogels by Acetonitrile Supercritical Drying

2012 ◽  
Vol 519 ◽  
pp. 83-86 ◽  
Author(s):  
Guang Wu Liu ◽  
Xing Yuan Ni ◽  
Bin Zhou ◽  
Qiu Jie Yu
Keyword(s):  
Specific Surface ◽  
Surface Area ◽  
Specific Surface Area ◽  
Silica Aerogel ◽  
Sol Gel ◽  
Supercritical Drying ◽  
Silica Aerogels ◽  
High Specific Surface Area ◽  
Molar Ratio ◽  
Sol Gel Process

This paper deals with the synthesis of ultralow density silica aerogels using tetramethyl orthosilicate (TMOS) as the precursor via sol-gel process followed by supercritical drying using acetonitrile solvent extraction. Ultralow density silica aerogels with 6 mg/cc of density was made for the molar ratio by this method. The microstructure and morphology of the ultralow density silica aerogels was characterized by the specific surface area, SBET, SEM, and the pore size distribution techniques. The results show that the ultralow density silica aerogel has the high specific surface area of 812m2/g. Thermal conductivities at desired temperatures were analyzed by the transient plane heat source method. Thermal conductivity coefficients of silica aerogel monoliths changed from 0.024 to 0.043W/ (m K) as temperature increased to 400°C, revealed an excellent heat insulation effect during thermal process.

The Monolithic Silica Aerogel Derived from MTMS/TEOS

2013 ◽  
Vol 364 ◽  
pp. 631-634
Author(s):  
Yu Xi Yu ◽  
Yong Chen
Keyword(s):  
Specific Surface ◽  
Surface Area ◽  
Specific Surface Area ◽  
Silica Aerogel ◽  
Sol Gel ◽  
Supercritical Drying ◽  
Silica Aerogels ◽  
Synthesis And Characterization ◽  
Sol Gel Process

The experimental results on the synthesis and characterization of tetraethoxysilane (TEOS)/ methyltrimethoxysilane (MTMS)-based silica aerogels using two step sol-gel process via supercritical drying, are described. The obtained TEOS/MTMS-based aerogel showed properties of 0.1g/cm3 density, 95.5% porosity and 1070 m2/g specific surface area.

scholarly journals Aerogels in Aerospace: An Overview

2013 ◽  
Vol 2013 ◽  
pp. 1-18 ◽  
Author(s):  
Nadiir Bheekhun ◽  
Abd. Rahim Abu Talib ◽  
Mohd Roshdi Hassan
Keyword(s):  
Silica Aerogel ◽  
Outer Space ◽  
Sol Gel ◽  
Supercritical Drying ◽  
Research Trend ◽  
Sound Waves ◽  
Space Applications ◽  
Sol Gel Process ◽  
Drying Technology ◽  
Highly Porous

Aerogels are highly porous structures prepared via a sol-gel process and supercritical drying technology. Among the classes of aerogels, silica aerogel exhibits the most remarkable physical properties, possessing lower density, thermal conductivity, refractive index, and dielectric constant than any solids. Its acoustical property is such that it can absorb the sound waves reducing speed to 100 m/s compared to 332 m/s for air. However, when it comes to commercialization, the result is not as expected. It seems that mass production, particularly in the aerospace industry, has dawdled behind. This paper highlights the evolution of aerogels in general and discusses the functions and significances of silica aerogel in previous astronautical applications. Future outer-space applications have been proposed as per the current research trend. Finally, the implementation of conventional silica aerogel in aeronautics is argued with an alternative known as Maerogel.

Delocalization of electronic states in graphene oxide stabilised mesoporous silica nanoparticles revealed using photoluminescence

RSC Advances ◽  
2014 ◽  
Vol 4 (34) ◽  
pp. 17879-17883 ◽  
Author(s):  
Naveen Chandrasekaran ◽  
Santhana Sivabalan ◽  
Aswin Prathap ◽  
S. Mohan ◽  
R. Jagannathan
Keyword(s):  
Graphene Oxide ◽  
Mesoporous Silica ◽  
Silica Nanoparticles ◽  
Silica Aerogel ◽  
Mesoporous Silica Nanoparticles ◽  
Sol Gel ◽  
Electronic States ◽  
Coordination Complexes ◽  
Sol Gel Process ◽  
Graphene Oxide Sheets

Mesoporous silica aerogel obtained through a sol–gel process when surface treated with 2-D graphene oxide sheets reveals many fascinating features particularly, leading to multiple coordination complexes based on amide linkages.

FTIR Study on the Preliminary Development of Synthesis Methods for Hydroxyapatite Modified Silica Aerogel

2015 ◽  
Vol 799-800 ◽  
pp. 493-499 ◽  
Author(s):  
Nor Suriani Sani ◽  
Nik Ahmad Nizam Nik Malek ◽  
Mohammed Rafiq Abdul Kadir ◽  
Halimaton Hamdan
Keyword(s):  
Fourier Transform ◽  
Ftir Spectroscopy ◽  
Silica Aerogel ◽  
Sol Gel ◽  
Fourier Transform Infrared ◽  
Synthesis Methods ◽  
Modified Silica ◽  
Ftir Study ◽  
Sol Gel Process

Hydroxyapatite (HA) modified silica aerogel (SA) was synthesized based on 2 different techniques namely encapsulation andin-situvia aqueous colloidal sol-gel process. The structure of the synthesized HA modified SA have been studied using Fourier transform infrared (FTIR) spectroscopy. FTIR spectra of HA modified SA, derived fromin-situtechnique appear to be different from those of encapsulation technique and free HA, with the main difference lying in the phosphate bending absorbance. Results showed that the encapsulation technique preserved the native confirmation of HA in SA frameworks compared toin-situtechnique. It confirms that the use of an aqueous sol-gel encapsulation route provides a promising approach for the stabilization of HA in SA networks.

The crystallization of thin-film ceramics

1992 ◽  
Vol 50 (1) ◽  
pp. 338-339
Author(s):  
J.M. Schwartz ◽  
L.F. Francis ◽  
L.D. Schmidt ◽  
P.S. Schabes-Retchkiman
Keyword(s):  
Thin Films ◽  
Grain Size ◽  
Sol Gel ◽  
Processing Route ◽  
Small Areas ◽  
Ceramic Thin Films ◽  
Complex Shapes ◽  
Sol Gel Process ◽  
Ceramic Precursors ◽  
Crystalline Ceramic

Ceramic thin films and coatings are of interest for electrical, optical, magnetic and thermal barrier applications. Critical for improved properties in thin films is the development of specific microstructures during processing. To this end, the sol-gel method is advantageous as a versatile processing route. The sol-gel process involves depositing a solution containing metalorganic or colloidal ceramic precursors onto a substrate and heating the deposited layer to form a crystalline or non-crystalline ceramic coating. This route has several advantages, including the ability to create tailored microstructures and properties, to coat large or small areas, simple or complex shapes, and to more easily prepare multicomponent ceramics. Sol-gel derived coatings are amorphous in the as-deposited state and develop their crystalline structure and microstructure during heat-treatment. We are particularly interested in studying the amorphous to crystalline transformation, because many key features of the microstructure such as grain size and grain size distribution may be linked to this transformation.

Epitaxial Growth of Sr0.3Ba0.7Nb2O6 Thin Films Prepared by Sol-Gel Process

1999 ◽  
Vol 606 ◽  
Author(s):  
Keishi Nishio ◽  
Jirawat Thongrueng ◽  
Yuichi Watanabe ◽  
Toshio Tsuchiya
Keyword(s):  
Thin Film ◽  
Thin Films ◽  
Epitaxial Growth ◽  
Raw Materials ◽  
Substrate Surface ◽  
Sol Gel ◽  
Tungsten Bronze ◽  
Monomethyl Ether ◽  
Tetragonal Tungsten Bronze ◽  
Sol Gel Process

AbstructWe succeeded in the preparation of strontium-barium niobate (Sr0.3Ba0.7Nb2O6 : SBN30)that have a tetragonal tungsten bronze type structure thin films on SrTiO3 (100), STO, or La doped SrTiO3 (100), LSTO, single crystal substrates by a spin coating process. LSTO substrate can be used for electrode. A homogeneous coating solution was prepared with Sr and Ba acetates and Nb(OEt)5 as raw materials, and acetic acid and diethylene glycol monomethyl ether as solvents. The coating thin films were sintered at temperature from 700 to 1000°C for 10 min in air. It was confirmed that the thin films on STO substrate sintered above 700°C were in the epitaxial growth because the 16 diffraction spots were observed on the pole figure using (121) reflection. The <130> and <310> direction of the thin film on STO were oriented with the c-axis in parallel to the substrate surface. However, the diffraction spots of thin film on LSTO substrate sintered at 700°C were corresponds to the expected pattern for (110).

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