A QUEST FOR A NEW PARAMETER IN PETROLEUM EXPLORATION GEOCHEMISTRY

1987 ◽  
Vol 27 (1) ◽  
pp. 98 ◽  
Author(s):  
J.W. Smith ◽  
T.D. Gilbert
Keyword(s):  
Critical Factor ◽  
Liquid Hydrocarbon ◽  
General Concept ◽  
Source Rocks ◽  
Petroleum Exploration ◽  
Hydrocarbon Gases ◽  
Petrographic Composition ◽  
Exploration Geochemistry ◽  
Hydrous Pyrolysis ◽  
Rock Parameters

Primary Australian terrestrially-derived crudes are characterised by high wax and n-alkane contents. These characteristics, as determined by hydrogenation and hydrous pyrolysis, appear to be unrelated to either the chemical or petrographic compositions of Victorian brown coal lithotypes. Furthermore, since relationships between chemical and petrographic composition are obscure, a re-examination of current concepts which relate these established source rock parameters to liquid hydrocarbon generating potentials is warranted.The content of thermally stable, longer-chain, n-alkyl components in source rocks is introduced as the critical factor in determining whether these rocks have the potential to generate typical Australian waxy crudes or hydrocarbon gases. Modifications to this general concept are required by the thermal stability of directly substituted longer-chain n-alkyl aromatics and hydroaromatics. These appear to be sources of light hydrocarbons and gases, rather than oils.Inherent weaknesses in the experimental techniques of hydrogenation and hydrous pyrolysis have hindered the collection of data, but the concept that n-alkane potential is a critical factor in determining the petroleum-generating potential of immature source rocks is being pursued using techniques modified for the determination of their total heteroatom-bonded n-alkyl contents.

HYDROCARBON GASES IN SEAFLOOR SEDIMENTS, OTWAY AND GIPPSLAND BASINS: IMPLICATIONS FOR PETROLEUM EXPLORATION

1989 ◽  
Vol 29 (1) ◽  
pp. 96 ◽  
Author(s):  
G.W. O'Brien ◽  
D.T. Heggie
Keyword(s):  
Liquid Hydrocarbon ◽  
Source Rocks ◽  
Petroleum Exploration ◽  
Gas Content ◽  
Hydrocarbon Gases ◽  
Near Surface ◽  
Wet Gas ◽  
Well Data ◽  
Seafloor Sediments ◽  
Gippsland Basin

During April- May 1988, the BMR research vessel Rig Seismic carried out a 21- day geochemical and sedimento- logical research program in the Otway (17 days) and Gippsland (4 days) Basins. The concentrations and molecular compositions of light hydrocarbon gases (C1- C4) were measured in sediments at 203 locations on the continental shelf and upper continental slope: the presence of thermogenic hydrocarbons was inferred from the molecular compositions of the gas mixtures. Thermogenic hydrocarbons were identified in near- surface sediments at 32 locations in the Otway Basin; 6 of these locations were on the Crayfish Platform, 7 were on the Mussel Platform and 17 were in the Voluta Trough. Thermogenic hydrocarbons were identified at 10 locations in the Gippsland Basin. Data from the Otway Basin indicated that total C1- C4 gas concentrations were higher in the Voluta Trough than on the basin margins, probably because intense faulting in the trough facilitates gas migration from deeply buried source rocks and/or reservoirs to the seafloor. However, anomalies were detected where the Tertiary sequence was thick and relatively unfaulted. The wet gas contents of the anomalies were highest on the basin margins, lower in the Voluta Trough and co- varied with the depth of burial of the basal Early Cretaceous sedimentary sequence. These data, when integrated with geohistory, thermal maturation modelling and well data, suggest that the areas with the best potential for liquid hydrocarbon entrapment and preservation are the Crayfish Platform and the inshore part of the Mussel Platform. In contrast, the Late Cretaceous Sherbrook Group and much of the Voluta Trough appear to be gas prone.Thermogenic anomalies in the Gippsland Basin were concentrated within and along the margins of the Central Deep where mature Latrobe Group source rocks are present. The wet gas content of these anomalies was variable, which is consistent with the spatial heterogeneity of hydrocarbon accumulations in the Gippsland Basin.

Non-hydrocarbons of significance in petroleum exploration: volatile fatty acids and non-hydrocarbon gases

1987 ◽  
Vol 51 (362) ◽  
pp. 483-493 ◽  
Author(s):  
G. P. Cooles ◽  
A. S. Mackenzie ◽  
R. J. Parkes
Keyword(s):  
Volatile Fatty Acids ◽  
Source Rocks ◽  
Petroleum Exploration ◽  
Gas Generation ◽  
Hydrocarbon Gases ◽  
Natural Systems ◽  
Gaseous Products ◽  
Hydrous Pyrolysis ◽  
Hydrocarbon Gas ◽  
Thermodynamic Effects

AbstractNon-hydrocarbon gas species (CO2, N2, H2) are locally important in exploration for gas, and there is a growing body of evidence that acid water originating in shales materially affects the diagenesis of nearby sandstones. These gases have been studied by analysing the products of closed-vessel hydrous pyrolysis of known petroleum source rocks, and comparing the results with field observations. Alteration of petroleum source rocks at temperatures >250°C yields a significant amount of non-hydrocarbon components. Ethanoate and higher acid anions are liberated in substantial quantities; the yield appears to be related to the oxygen content of the sedimentary organic matter present.The non-hydrocarbon gases CO2, H2and N2are frequently the dominant gaseous products from hydrous pyrolysis: in the natural environment the same rock sequences at a higher maturity preferentially generate hydrocarbon gases—mainly methane. This discrepancy may be attributed to reaction and phase thermodynamic effects between laboratory and natural systems, behaviour that has important implications in the prediction of gas generation and composition in nature by source rock pyrolysis in the laboratory.

The Study on Hydrous Pyrolysis Experiments of Coal-Measure Source Rocks in Ordos Basin

2013 ◽  
Vol 734-737 ◽  
pp. 8-12
Author(s):  
Pei Xue ◽  
Yan Bin Wang ◽  
Jun Yuan
Keyword(s):  
Carbon Dioxide ◽  
Temperature Rise ◽  
Heating Temperature ◽  
Ordos Basin ◽  
Source Rocks ◽  
Coal Measure ◽  
Hydrocarbon Gases ◽  
Hydrous Pyrolysis ◽  
Hydrocarbon Gas ◽  
Hydrocarbon Productivity

Through the hydrous pyrolysis experiments of coal-measure source rocks in Taiyuan formation in Ordos Basin with different mediums from 250 °C to 550 °C, with a stepwise heating stage of 50 °C, the characteristics of gas and liquid products are discussed systematically in this paper. The results show that the change rule of hydrocarbon productivity of coal with temperature is similar to mudstone. Total hydrocarbon productivity and gas hydrocarbon productivity increase with temperature rise. Liquid hydrocarbon productivity increases with temperature rise first and then decreases. The peak yield of oil of coal appears at the heating temperature 350 °C, mudstone at 375 °C. The peak yield of mudstone lags behind. The non-hydrocarbon gas productivity increases with temperature rise. The non-hydrocarbon gases are carbon dioxide, nitrogen gas and oxygen mainly. The productivity of carbon dioxide is significantly higher than other non-hydrocarbon gas productivities. The main hydrocarbon gas is methane. The productivity of methane increases when temperature rises. And the productivity increases obviously after 400 °C.

Generation and origin of natural gas in Lower Palaeozoic shales from southern Sweden

1969 ◽  
pp. 37-40
Author(s):  
Niels Hemmingsen Schovsbo ◽  
Arne Thorshøj Nielsen
Keyword(s):  
Source Rocks ◽  
Southern Sweden ◽  
Hydrocarbon Gases ◽  
Biogenic Gas ◽  
South Central ◽  
Alum Shale ◽  
Marine Source ◽  
Lower Palaeozoic ◽  
Background Gas ◽  
Origin Of Natural Gas

The Lower Palaeozoic succession in Scandinavia includes several excellent marine source rocks notably the Alum Shale, the Dicellograptus shale and the Rastrites Shale that have been targets for shale gas exploration since 2008. We here report on samples of these source rocks from cored shallow scientific wells in southern Sweden. The samples contain both free and sorbed hydrocarbon gases with concentrations significantly above the background gas level. The gases consist of a mixture of thermogenic and bacterially derived gas. The latter likely derives from both carbonate reduction and methyl fermentation processes. The presence of both thermogenic and biogenic gas in the Lower Palaeozoic shales is in agreement with results from past and present exploration activities; thermogenic gas is a target in deeply buried, gas-mature shales in southernmost Sweden, Denmark and northern Poland, whereas biogenic gas is a target in shallow, immature-marginally mature shales in south central Sweden. We here document that biogenic gas signatures are present also in gas-mature shallow buried shales in Skåne in southernmost Sweden.

Kinetic study of the hydrocarbon generation from marine carbonate source rocks characterization of products of gas and liquid hydrocarbon

2006 ◽  
Vol 51 (23) ◽  
pp. 2885-2891 ◽  
Author(s):  
Xinhua Geng ◽  
Ansong Geng ◽  
Yongqiang Xiong ◽  
Jinzhong Liu ◽  
Haizu Zhang ◽  
...  
Keyword(s):  
Kinetic Study ◽  
Liquid Hydrocarbon ◽  
Source Rocks ◽  
Hydrocarbon Generation ◽  
Marine Carbonate ◽  
Carbonate Source

Evidence from the Changing Carbon Isotopic of Kerogen, Oil, and Gas during Hydrous Pyrolysis from Pinghu Formation, the Xihu Sag, East China Sea Basin

Energies ◽  
2021 ◽  
Vol 14 (24) ◽  
pp. 8317
Author(s):  
Qiang Cao ◽  
Jiaren Ye ◽  
Yongchao Lu ◽  
Yang Tian ◽  
Jinshui Liu ◽  
...  
Keyword(s):  
Carbon Isotopes ◽  
Oil And Gas ◽  
Thermal Evolution ◽  
Vitrinite Reflectance ◽  
Heating Time ◽  
Source Rocks ◽  
Evolution Process ◽  
Carbon Isotopic ◽  
Hydrous Pyrolysis ◽  
Increasing Temperature

Semi-open hydrous pyrolysis experiments on coal-measure source rocks in the Xihu Sag were conducted to investigate the carbon isotope evolution of kerogen, bitumen, generated expelled oil, and gases with increasing thermal maturity. Seven corresponding experiments were conducted at 335 °C, 360 °C, 400 °C, 455 °C, 480 °C, 525 °C, and 575 °C, while other experimental factors, such as the heating time and rate, lithostatic and hydrodynamic pressures, and columnar original samples were kept the same. The results show that the simulated temperatures were positive for the measured vitrinite reflectance (Ro), with a correlation coefficient (R2) of 0.9861. With increasing temperatures, lower maturity, maturity, higher maturity, and post-maturity stages occurred at simulated temperatures (Ts) of 335–360 °C, 360–400 °C, 400–480 °C, and 480–575 °C, respectively. The increasing gas hydrocarbons with increasing temperature reflected the higher gas potential. Moreover, the carbon isotopes of kerogen, bitumen, expelled oil, and gases were associated with increased temperatures; among gases, methane was the most sensitive to maturity. Ignoring the intermediate reaction process, the thermal evolution process can be summarized as kerogen0(original) + bitumen0(original)→kerogenr (residual kerogen) + expelled oil (generated) + bitumenn+r (generated + residual) + C2+(generated + residual) + CH4(generated). Among these, bitumen, expelled oil, and C2-5 acted as reactants and products, whereas kerogen and methane were the reactants and products, respectively. Furthermore, the order of the carbon isotopes during the thermal evolution process was identified as: δ13C1 < 13C2-5 < δ13Cexpelled oil < δ13Cbitumen < δ13Ckerogen. Thus, the reaction and production mechanisms of carbon isotopes can be obtained based on their changing degree and yields in kerogen, bitumen, expelled oil, and gases. Furthermore, combining the analysis of the geochemical characteristics of the Pinghu Formation coal–oil-type gas in actual strata with these pyrolysis experiments, it was identified that this area also had substantial development potential. Therefore, this study provides theoretical support and guidance for the formation mechanism and exploration of oil and gas based on changing carbon isotopes.

scholarly journals Sedimentology and geochemistry of Middle–Upper Permian in northwestern Turpan–Hami Basin, China: Implication for depositional environments and petroleum geology

2018 ◽  
Vol 36 (4) ◽  
pp. 910-941
Author(s):  
Jian Song ◽  
Zhidong Bao ◽  
Xingmin Zhao ◽  
Yinshan Gao ◽  
Xinmin Song ◽  
...  
Keyword(s):  
Depositional Environment ◽  
Saline Water ◽  
Depositional Environments ◽  
Source Rocks ◽  
Petroleum Exploration ◽  
Upper Permian ◽  
Late Permian ◽  
Humid Climate ◽  
Mountain Area ◽  
Volcanic Source

Studies have found that the Permian is another important stratum for petroleum exploration except the Jurassic coal measures within Turpan–Hami Basin recently. However, the knowledge of the depositional environments and its petroleum geological significances during the Middle–Late Permian is still limited. Based on the analysis about the sedimentological features of the outcrop and the geochemical characteristics of mudstones from the Middle Permian Taerlang Formation and Upper Permian Quanzijie Formation in the Taoshuyuanzi profile, northwest Turpan–Hami Basin, this paper makes a detailed discussion on the Middle–Late Permian paleoenvironment and its petroleum geological significances. The Middle–Upper Permian delta–lacustrine depositional system was characterized by complex vertical lithofacies assemblages, which were primarily influenced by tectonism and frequent lake-level variations in this area. The Taerlang Formation showed a significant lake transgression trend, whereas the regressive trend of the Quanzijie Formation was relatively weaker. The provenance of Taerlang and Quanzijie Formations was derived from the rift shoulder (Bogda Mountain area now) to the north and might be composed of a mixture of andesite and felsic volcanic source rocks. The Lower Taerlang Formation was deposited in a relatively hot–dry climate, whereas the Upper Taerlang and Quanzijie Formations were deposited in a relatively humid climate. During the Middle–Late Permian, this area belonged to an overall semi-saline water depositional environment. The paleosalinity values showed stepwise decreases from the Lower Taerlang Formation to the Upper Quanzijie Formation, which was influenced by the changes of paleoclimate in this region. During the Middle–Late Permian, the study area was in an overall anoxic depositional environment. The paleoenvironment with humid climate, lower paleosalinity, anoxic condition, and semi-deep to deep water during the deposition of the Upper Taerlang Formation was suitable for the accumulation of mudstones with higher TOC values.

scholarly journals New exploration strategy in igneous petroliferous basins – Enlightenment from simulation experiments

2018 ◽  
Vol 36 (4) ◽  
pp. 971-985
Author(s):  
Qingqiang Meng ◽  
Jiajun Jing ◽  
Jingzhou Li ◽  
Dongya Zhu ◽  
Ande Zou ◽  
...  
Keyword(s):  
Oil And Gas ◽  
Liquid Hydrocarbon ◽  
Hydrogen Gas ◽  
Source Rocks ◽  
Hydrocarbon Generation ◽  
Simulation Experiments ◽  
Gaseous Hydrocarbon ◽  
Oil And Gas Fields ◽  
Gaseous Hydrocarbons ◽  
Hydrocarbon Productivity

There are two kinds of relationships between magmatism and the generation of hydrocarbons from source rocks in petroliferous basins, namely: (1) simultaneous magmatism and hydrocarbon generation, and (2) magmatism that occurs after hydrocarbon generation. Although the influence of magmatism on hydrocarbon source rocks has been extensively studied, there has not been a systematic comparison between these two relationships and their influences on hydrocarbon generation. Here, we present an overview of the influence of magmatism on hydrocarbon generation based on the results of simulation experiments. These experiments indicate that the two relationships outlined above have different influences on the generation of hydrocarbons. Magmatism that occurred after hydrocarbon generation contributed deeply sourced hydrogen gas that improved liquid hydrocarbon productivity between the mature and overmature stages of maturation, increasing liquid hydrocarbon productivity to as much as 451.59% in the case of simulation temperatures of up to 450°C during modelling where no hydrogen gas was added. This relationship also increased the gaseous hydrocarbon generation ratio at temperatures up to 450°C, owing to the cracking of initially generated liquid hydrocarbons and the cracking of kerogen. Our simulation experiments suggest that gaseous hydrocarbons dominate total hydrocarbon generation ratios for overmature source rocks, resulting in a change in petroleum accumulation processes. This in turn suggests that different exploration strategies are warranted for the different relationships outlined above. For example, simultaneous magmatism and hydrocarbon generation in an area means that exploration should focus on targets likely to host large oilfields, whereas in areas with magmatism that post-dates hydrocarbon generation the exploration should focus on both oil and gas fields. In addition, exploration strategies in igneous petroliferous basins should focus on identifying high-quality reservoirs as well as determining the relationship between magmatism and initial hydrocarbon generation.

scholarly journals Oil generation from coal source rocks: the influence of depositional conditions and stratigraphic age

2005 ◽  
Vol 7 ◽  
pp. 9-12 ◽  
Author(s):  
Henrik I. Petersen
Keyword(s):  
North Sea ◽  
Liquid Hydrocarbon ◽  
Source Rocks ◽  
Hydrocarbon Generation ◽  
Oil Generation ◽  
Generation Capacity ◽  
The Subject ◽  
Coal Composition ◽  
Gippsland Basin ◽  
Australasian Region

Although it was for many years believed that coals could not act as source rocks for commercial oil accumulations, it is today generally accepted that coals can indeed generate and expel commercial quantities of oil. While hydrocarbon generation from coals is less well understood than for marine and lacustrine source rocks, liquid hydrocarbon generation from coals and coaly source rocks is now known from many parts of the world, especially in the Australasian region (MacGregor 1994; Todd et al. 1997). Most of the known large oil accumulations derived from coaly source rocks have been generated from Cenozoic coals, such as in the Gippsland Basin (Australia), the Taranaki Basin (New Zealand), and the Kutei Basin (Indonesia). Permian and Jurassic coal-sourced oils are known from, respectively, the Cooper Basin (Australia) and the Danish North Sea, but in general only minor quantities of oil appear to be related to coals of Permian and Jurassic age. In contrast, Carboniferous coals are only associated with gas, as demonstrated for example by the large gas deposits in the southern North Sea and The Netherlands. Overall, the oil generation capacity of coals seems to increase from the Carboniferous to the Cenozoic. This suggests a relationship to the evolution of more complex higher land plants through time, such that the highly diversified Cenozoic plant communities in particular have the potential to produce oil-prone coals. In addition to this overall vegetational factor, the depositional conditions of the precursor mires influenced the generation potential. The various aspects of oil generation from coals have been the focus of research at the Geological Survey of Denmark and Greenland (GEUS) for several years, and recently a worldwide database consisting of more than 500 coals has been the subject of a detailed study that aims to describe the oil window and the generation potential of coals as a function of coal composition and age.

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