Evidence from the Changing Carbon Isotopic of Kerogen, Oil, and Gas during Hydrous Pyrolysis from Pinghu Formation, the Xihu Sag, East China Sea Basin

Energies ◽  
2021 ◽  
Vol 14 (24) ◽  
pp. 8317
Author(s):  
Qiang Cao ◽  
Jiaren Ye ◽  
Yongchao Lu ◽  
Yang Tian ◽  
Jinshui Liu ◽  
...  
Keyword(s):  
Carbon Isotopes ◽  
Oil And Gas ◽  
Thermal Evolution ◽  
Vitrinite Reflectance ◽  
Heating Time ◽  
Source Rocks ◽  
Evolution Process ◽  
Carbon Isotopic ◽  
Hydrous Pyrolysis ◽  
Increasing Temperature

Semi-open hydrous pyrolysis experiments on coal-measure source rocks in the Xihu Sag were conducted to investigate the carbon isotope evolution of kerogen, bitumen, generated expelled oil, and gases with increasing thermal maturity. Seven corresponding experiments were conducted at 335 °C, 360 °C, 400 °C, 455 °C, 480 °C, 525 °C, and 575 °C, while other experimental factors, such as the heating time and rate, lithostatic and hydrodynamic pressures, and columnar original samples were kept the same. The results show that the simulated temperatures were positive for the measured vitrinite reflectance (Ro), with a correlation coefficient (R2) of 0.9861. With increasing temperatures, lower maturity, maturity, higher maturity, and post-maturity stages occurred at simulated temperatures (Ts) of 335–360 °C, 360–400 °C, 400–480 °C, and 480–575 °C, respectively. The increasing gas hydrocarbons with increasing temperature reflected the higher gas potential. Moreover, the carbon isotopes of kerogen, bitumen, expelled oil, and gases were associated with increased temperatures; among gases, methane was the most sensitive to maturity. Ignoring the intermediate reaction process, the thermal evolution process can be summarized as kerogen0(original) + bitumen0(original)→kerogenr (residual kerogen) + expelled oil (generated) + bitumenn+r (generated + residual) + C2+(generated + residual) + CH4(generated). Among these, bitumen, expelled oil, and C2-5 acted as reactants and products, whereas kerogen and methane were the reactants and products, respectively. Furthermore, the order of the carbon isotopes during the thermal evolution process was identified as: δ13C1 < 13C2-5 < δ13Cexpelled oil < δ13Cbitumen < δ13Ckerogen. Thus, the reaction and production mechanisms of carbon isotopes can be obtained based on their changing degree and yields in kerogen, bitumen, expelled oil, and gases. Furthermore, combining the analysis of the geochemical characteristics of the Pinghu Formation coal–oil-type gas in actual strata with these pyrolysis experiments, it was identified that this area also had substantial development potential. Therefore, this study provides theoretical support and guidance for the formation mechanism and exploration of oil and gas based on changing carbon isotopes.

scholarly journals Effects of igneous intrusions on source rock in the early diagenetic stage: A case study on Beipiao Formation in Jinyang Basin, Northeast China

2020 ◽  
Vol 12 (1) ◽  
pp. 990-1002
Author(s):  
Shouliang Sun ◽  
Tao Zhang ◽  
Yongfei Li ◽  
Shuwang Chen ◽  
Qiushi Sun
Keyword(s):  
Source Rock ◽  
Oil And Gas ◽  
Thermal Evolution ◽  
Vitrinite Reflectance ◽  
Scientific Basis ◽  
Source Rocks ◽  
Temperature History ◽  
Hydrocarbon Generation ◽  
Intrusive Body ◽  
Geochemical Parameters

AbstractMesozoic intrusive bodies play an important role in the temperature history and hydrocarbon maturation of the Jinyang Basin in northeastern China. The Beipiao Formation, which is the main source rock in Jinyang Basin, was intruded by numerous igneous bodies and dykes in many areas. The effects of igneous intrusive bodies on thermal evolution and hydrocarbon generation and migration in the Beipiao Formation were investigated. A series of samples from the outcrop near the intrusive body were analyzed for vitrinite reflectance (R0%) and other organic geochemical parameters to evaluate the lateral extension of the thermal aureole. The R0 values of the samples increase from a background value of ∼0.9% at a distance above 200 m from the intrusive body to more than 2.0% at the vicinity of the contact zone. The width of the altered zone is equal to the thickness of the intrusive body outcropped in the field. Organic geochemical proxies also indicate the intrusive body plays a positive and beneficial role in the formation of regional oil and gas resources. Due to the influence of the anomalous heat from the intrusive body, the hydrocarbon conversion rate of the source rocks of the Beipiao Formation was significantly improved. The accumulation properties and the storage capacity of the shales also greatly improved due to the intrusive body as indicated by the free hydrocarbon migration in the shales. This new understanding not only provides a reliable scientific basis for the accurate assessment of oil and gas genesis and resources in the Jinyang Basin but also provides guidance and reference for oil and gas exploration in the similar type of basin.

COAL AS A SOURCE OF OIL AND GAS: A CASE STUDY FROM THE BASS BASIN, AUSTRALIA

2003 ◽  
Vol 43 (1) ◽  
pp. 117 ◽  
Author(s):  
C.J. Boreham ◽  
J.E. Blevin ◽  
A.P. Radlinski ◽  
K.R. Trigg
Keyword(s):  
Organic Matter ◽  
Oil And Gas ◽  
Middle Eocene ◽  
Vitrinite Reflectance ◽  
Mineral Resources ◽  
Sedimentary Basins ◽  
Source Rocks ◽  
Gas Generation ◽  
Australian Context ◽  
Effective Source

Only a few published geochemical studies have demonstrated that coals have sourced significant volumes of oil, while none have clearly implicated coals in the Australian context. As part of a broader collaborative project with Mineral Resources Tasmania on the petroleum prospectivity of the Bass Basin, this geochemical study has yielded strong evidence that Paleocene–Eocene coals have sourced the oil and gas in the Yolla, Pelican and Cormorant accumulations in the Bass Basin.Potential oil-prone source rocks in the Bass Basin have Hydrogen Indices (HIs) greater than 300 mg HC/g TOC. The coals within the Early–Middle Eocene succession commonly have HIs up to 500 mg HC/g TOC, and are associated with disseminated organic matter in claystones that are more gas-prone with HIs generally less than 300 mg HC/g TOC. Maturity of the coals is sufficient for oil and gas generation, with vitrinite reflectance (VR) up to 1.8 % at the base of Pelican–5. Igneous intrusions, mainly within Paleocene, Oligocene and Miocene sediments, produced locally elevated maturity levels with VR up to 5%.The key events in the process of petroleum generation and migration from the effective coaly source rocks in the Bass Basin are:the onset of oil generation at a VR of 0.65% (e.g. 2,450 m in Pelican–5);the onset of oil expulsion (primary migration) at a VR of 0.75% (e.g. 2,700–3,200 m in the Bass Basin; 2,850 m in Pelican–5);the main oil window between VR of 0.75 and 0.95% (e.g. 2,850–3,300 m in Pelican–5); and;the main gas window at VR >1.2% (e.g. >3,650 m in Pelican–5).Oils in the Bass Basin form a single oil population, although biodegradation of the Cormorant oil has resulted in its statistical placement in a separate oil family from that of the Pelican and Yolla crudes. Oil-to-source correlations show that the Paleocene–Early Eocene coals are effective source rocks in the Bass Basin, in contrast to previous work, which favoured disseminated organic matter in claystone as the sole potential source kerogen. This result represents the first demonstrated case of significant oil from coal in the Australian context. Natural gases at White Ibis–1 and Yolla–2 are associated with the liquid hydrocarbons in their respective fields, although the former gas is generated from a more mature source rock.The application of the methodologies used in this study to other Australian sedimentary basins where commercial oil is thought to be sourced from coaly kerogens (e.g. Bowen, Cooper and Gippsland basins) may further implicate coal as an effective source rock for oil.

scholarly journals 3D-Basin Modelling of the Lishui Sag: Research of Hydrocarbon Potential, Petroleum Generation and Migration

Energies ◽  
2019 ◽  
Vol 12 (4) ◽  
pp. 650 ◽  
Author(s):  
Jinliang Zhang ◽  
Jiaqi Guo ◽  
Jinshui Liu ◽  
Wenlong Shen ◽  
Na Li ◽  
...  
Keyword(s):  
Source Rock ◽  
Thermal Evolution ◽  
Vitrinite Reflectance ◽  
Three Dimensional ◽  
Source Rocks ◽  
Rock Properties ◽  
Hydrocarbon Generation ◽  
Hydrocarbon Accumulation ◽  
Southeastern Part ◽  
Petroleum Generation

The Lishui Sag is located in the southeastern part of the Taibei Depression, in the East China Sea basin, where the sag is the major hydrocarbon accumulation zone. A three dimensional modelling approach was used to estimate the mass of petroleum generation and accumulated during the evolution of the basin. Calibration of the model, based on measured maturity (vitrinite reflectance) and borehole temperatures, took into consideration two main periods of erosion events: a late Cretaceous to early Paleocene event, and an Oligocene erosion event. The maturation histories of the main source rock formations were reconstructed and show that the peak maturities have been reached in the west central part of the basin. Our study included source rock analysis, measurement of fluid inclusion homogenization temperatures, and basin history modelling to define the source rock properties, the thermal evolution and hydrocarbon generation history, and possible hydrocarbon accumulation processes in the Lishui Sag. The study found that the main hydrocarbon source for the Lishui Sag are argillaceous source rocks in the Yueguifeng Formation. The hydrocarbon generation period lasted from 58 Ma to 32 Ma. The first period of hydrocarbon accumulation lasted from 51.8 Ma to 32 Ma, and the second period lasted from 23 Ma to the present. The accumulation zones mainly located in the structural high and lithologic-fault screened reservoir filling with the hydrocarbon migrated from the deep sag in the south west direction.

scholarly journals Hydrocarbon generation from Carboniferous-Permian coaly source rocks in the Huanghua depression under different geological processes

2020 ◽  
Vol 17 (6) ◽  
pp. 1540-1555
Author(s):  
Jin-Jun Xu ◽  
Qiang Jin
Keyword(s):  
Oil And Gas ◽  
Vitrinite Reflectance ◽  
Source Rocks ◽  
Bohai Bay ◽  
Hydrocarbon Generation ◽  
Oil And Gas Exploration ◽  
Geological Processes ◽  
Light Oil ◽  
Huanghua Depression ◽  
Higher Temperature

AbstractNatural gas and condensate derived from Carboniferous-Permian (C-P) coaly source rocks discovered in the Dagang Oilfield in the Bohai Bay Basin (east China) have important implications for the potential exploration of C-P coaly source rocks. This study analyzed the secondary, tertiary, and dynamic characteristics of hydrocarbon generation in order to predict the hydrocarbon potentials of different exploration areas in the Dagang Oilfield. The results indicated that C-P oil and gas were generated from coaly source rocks by secondary or tertiary hydrocarbon generation and characterized by notably different hydrocarbon products and generation dynamics. Secondary hydrocarbon generation was completed when the maturity reached vitrinite reflectance (Ro) of 0.7%–0.9% before uplift prior to the Eocene. Tertiary hydrocarbon generation from the source rocks was limited in deep buried sags in the Oligocene, where the products consisted of light oil and gas. The activation energies for secondary and tertiary hydrocarbon generation were 260–280 kJ/mol and 300–330 kJ/mol, respectively, indicating that each instance of hydrocarbon generation required higher temperature or deeper burial than the previous instance. Locations with secondary or tertiary hydrocarbon generation from C-P coaly source rocks were interpreted as potential oil and gas exploration regions.

scholarly journals Hydrocarbon biomarkers and isotopic composition of carbon from bitumoids and oils of Mesozoic sediments in the western part of the Yenisei-Khatanga oil and gas region

Georesursy ◽  
2019 ◽  
Vol 21 (1) ◽  
pp. 47-63
Author(s):  
Alexander P. Afanasenkov ◽  
Tatyana P. Zheglova ◽  
Alexander L. Petrov
Keyword(s):  
Isotopic Composition ◽  
Oil And Gas ◽  
Carbon Isotopic Composition ◽  
Source Rocks ◽  
Type I ◽  
Composition Distribution ◽  
Carbon Isotopic ◽  
Hydrocarbon Biomarkers ◽  
Humus Type ◽  
Hydrocarbon Deposits

Based on analyzes of carbon isotopic composition, distribution and composition of hydrocarbon biomarkers of oils and bitumoids from source rocks of the Mesozoic sediments in the western part of the Yenisei-Khatanga oil and gas region and the northeast of the West-Siberian plate, two groups of oils and bitumoids are identified, genetically associated with organic matter, mainly sapropel type (I group) and mainly humus type (II group). The genetic correlation of oils and bitumoids has been made. Possible foci of generation, which participated in the formation of hydrocarbon deposits, have been determined.

Hydrocarbon Generation Indication from Source Rock to Reservoir Rock: Case Studies of Anambra and Abakaliki Basins South-Eastern Nigeria

2016 ◽  
Author(s):  
Samuel Salufu ◽  
Rita Onolemhemhen ◽  
Sunday Isehunwa
Keyword(s):  
Case Studies ◽  
Source Rock ◽  
Oil And Gas ◽  
Vitrinite Reflectance ◽  
Source Rocks ◽  
Reservoir Rock ◽  
Hydrocarbon Generation ◽  
Geochemical Analysis ◽  
Anambra Basin ◽  
Oil Generation

ABSTRACT This paper sought to use information from outcrop sections to characterize the source and reservoir rocks in a basin in order to give indication(s) for hydrocarbon generation potential in a basin in minimizing uncertainty and risk that are allied with exploration and field development of oil and gas, using subsurface data from well logs, well sections, seismic and core. The methods of study includes detailed geological, stratigraphical, geochemical, structural,, petro-graphical, and sedimentological studies of rock units from outcrop sections within two basins; Anambra Basin and Abakaliki Basin were used as case studies. Thirty eight samples of shale were collected from these Basins; geochemical analysis (rockeval) was performed on the samples to determine the total organic content (TOC) and to assess the oil generating window. The results were analyzed using Rock wares, Origin, and Surfer software in order to properly characterize the potential source rock(s) and reservoir rock(s) in the basins, and factor(s) that can favour hydrocarbon traps. The results of the geological, stratigraphical, sedimentological, geochemical, and structural, were used to developed a new model for hydrocarbon generation in the Basins. The result of the geochemical analysis of shale samples from the Anambra Basin shows that the TOC values are ≥ 1wt%, Tmax ≥ 431°C, Vitrinite reflectance values are ≥ 0.6%, and S1+S2 values are &gt; 2.5mg/g for Mamu Formation while shale samples from other formations within Anambra Basin fall out of these ranges. The shale unit in the Mamu Formation is the major source rock for oil generation in the Anambra Basin while others have potential for gas generation with very little oil generation. The shale samples from Abakaliki Basin shows that S1+S2 values range from&lt; 1 – 20mg/g, TOC values range from 0.31-4.55wt%, vitrinite reflectance ranges from 0.41-1.24% and Tmax ranges from423°C – 466°C. This result also shows that there is no source rock for oil generation in Abakaliki Basin; it is either gas or graphite. This observation indicates that all the source rocks within Abakaliki Basin have exceeded petroleum generating stage due to high geothermal heat resulting from deep depth or the shale units have not attained catagenesis stage as a result of S1+S2 values lesser than 2.5mg/g despite TOC values of ≥ 0.5wt% and vitrinite reflectance values of ≥ 0.6%. The novelty of this study is that the study has been able to show that here there is much more oil than the previous authors claimed, and the distribution of this oil and gas in the basins is controlled by two major factors; the pattern of distribution of the materials of the source rock prior to subsidence and during the subsidence period in the basin, and the pattern and the rate of tectonic activities, and heat flow in the basin. If these factors are known, it would help to reduce the uncertainties associated with exploration for oil and gas in the two basins.

scholarly journals Differential Thermal Evolution between Oil and Source Rocks in the Carboniferous Shale Reservoir of the Qaidam Basin, NW China

Energies ◽  
2021 ◽  
Vol 14 (21) ◽  
pp. 7088
Author(s):  
Qianru Wang ◽  
Haiping Huang ◽  
Chuan He ◽  
Zongxing Li
Keyword(s):  
Crude Oil ◽  
Thermal Evolution ◽  
Qaidam Basin ◽  
Vitrinite Reflectance ◽  
Hydrocarbon Exploration ◽  
Source Rocks ◽  
Gas Chromatography Mass Spectrometry ◽  
Thermal Maturity ◽  
Maturity Level ◽  
Shale Reservoir

Shale oil and source rock samples of the Carboniferous Keluke Formation from well Chaiye 2 in the Delingha Depression were analyzed by gas chromatography–mass spectrometry. Source rocks were highly mature at the gas generation stage with vitrinite reflectance (Ro) of 1.45–1.88%. However, the oil produced from the shale reservoir was characterized by abundant biomarkers but low abundance of diamondoid hydrocarbons with estimated Ro of ca. 0.78%, indicating hydrocarbons were still at a relatively low thermal maturity level. As the crude oil was generated and accumulated autochthonously, preliminary results indicate that crude oil and source rocks witnessed differential thermal evolution and significant disparity of the current thermal maturity in the shale reservoir due to rapid tectonic subsidence and clay mineral catalysts that accelerated the thermal maturation process. Although tectonic uplifts occurred afterwards, the vitrinite recorded the highest maturity that source rocks have ever reached, whereas the oil has not reached the same maturity level due to less impact from thermal alteration or mineral catalysis than source rocks in the shale reservoir. Such a discovery enlarges the hydrocarbon perseveration of maturity ranges in reservoirs, particularly for the unconventional tight formation, and benefits potential hydrocarbon exploration from highly mature sediments.

scholarly journals Petroleum generation and migration in the Mesopotamian Basin and Zagros Fold Belt of Iraq: results from a basin-modeling study

GeoArabia ◽  
2004 ◽  
Vol 9 (4) ◽  
pp. 41-72 ◽  
Author(s):  
Janet K. Pitman ◽  
Douglas Steinshouer ◽  
Michael D. Lewan
Keyword(s):  
Late Cretaceous ◽  
Oil And Gas ◽  
Source Rocks ◽  
Peak Oil ◽  
Fold Belt ◽  
Hydrous Pyrolysis ◽  
Oil Generation ◽  
Petroleum Generation ◽  
And Migration ◽  
Migration Pathways

ABSTRACT A regional 3-D total petroleum-system model was developed to evaluate petroleum generation and migration histories in the Mesopotamian Basin and Zagros fold belt in Iraq. The modeling was undertaken in conjunction with Middle East petroleum assessment studies conducted by the USGS. Regional structure maps, isopach and facies maps, and thermal maturity data were used as input to the model. The oil-generation potential of Jurassic source-rocks, the principal known source of the petroleum in Jurassic, Cretaceous, and Tertiary reservoirs in these regions, was modeled using hydrous pyrolysis (Type II-S) kerogen kinetics. Results showed that oil generation in source rocks commenced in the Late Cretaceous in intrashelf basins, peak expulsion took place in the late Miocene and Pliocene when these depocenters had expanded along the Zagros foredeep trend, and generation ended in the Holocene when deposition in the foredeep ceased. The model indicates that, at present, the majority of Jurassic source rocks in Iraq have reached or exceeded peak oil generation and most rocks have completed oil generation and expulsion. Flow-path simulations demonstrate that virtually all oil and gas fields in the Mesopotamian Basin and Zagros fold belt overlie mature Jurassic source rocks (vertical migration dominated) and are situated on, or close to, modeled migration pathways. Fields closest to modeled pathways associated with source rocks in local intrashelf basins were charged earliest from Late Cretaceous through the middle Miocene, and other fields filled later when compression-related traps were being formed. Model results confirm petroleum migration along major, northwest-trending folds and faults, and oil migration loss at the surface.

scholarly journals Geological and geochemical conditions for the formation of the oil composition in the deposits of the Permian and Jurassic oil and gas complexes in the Fukang depression (Junggar basin)

Georesursy ◽  
2021 ◽  
Vol 23 (2) ◽  
pp. 110-119
Author(s):  
Houqiang Yang ◽  
Elena V. Soboleva
Keyword(s):  
Isotopic Composition ◽  
Middle Jurassic ◽  
Oil And Gas ◽  
Carbon Isotopic Composition ◽  
Source Rocks ◽  
Middle Permian ◽  
Geochemical Conditions ◽  
Carbon Isotopic ◽  
Gas Source ◽  
Β Carotene

Within the eastern part of the Fukang depression, the main productive series are confined to the Permian and Jurassic oil and gas complexes (OGC), in which the Middle Permian and Lower-Middle Jurassic oil and gas source rocks (OGSRs) are distinguished. The article discusses in detail the oil and gas source characteristics of the Middle Permian and Lower-Middle Jurassic rocks, the molecular composition of oils and bitumoids from the OGSRs, and also interprets the characteristics of the biomarkers in them from the standpoint of the sedimentary-migration theory of oil generation. An attempt is made to explain the reasons for the difference in the properties and composition of oils from different OGCs. It is shown that the composition of hydrocarbon fluids of deposits is determined not only by the geological and geochemical conditions of sedimentation of oil and gas source deposits, but also associated with migration processes and subsequent secondary changes in the accumulation. In terms of composition, three groups of oils were identified: Permian and Jurassic heavy oils with a light carbon isotopic composition and the presence of β-carotene and gammacerane, they underwent different degrees of biodegradation, which depended on the geological conditions of the deposits; Permian medium oils in density (0.84 and 0.87 g/cm3), the composition of biomarkers of which is very close to that of the first group, and Jurassic light oils with a high content of solid paraffins and a heavier carbon isotopic composition, almost do not contain β-carotene and gammacerane concentrations are low.

scholarly journals Geochemical Evaluation of the Cretaceous Mudrocks and Sandstones (Wackes) in the Southern Bredasdorp Basin, Offshore South Africa: Implications for Hydrocarbon Potential

Minerals ◽  
2020 ◽  
Vol 10 (7) ◽  
pp. 595
Author(s):  
Temitope Love Baiyegunhi ◽  
Kuiwu Liu ◽  
Oswald Gwavava ◽  
Nicola Wagner ◽  
Christopher Baiyegunhi
Keyword(s):  
South Africa ◽  
Oil And Gas ◽  
Vitrinite Reflectance ◽  
Source Rocks ◽  
Geochemical Data ◽  
Minor Amount ◽  
Hydrocarbon Potential ◽  
Hydrocarbon Generation ◽  
Thermal Maturity ◽  
The Mean

The southern Bredasdorp Basin, off the south coast of South Africa, is only partly understood in terms of its hydrocarbon potential when compared to the central and northern parts of the basin. Hydrocarbon potential assessments in this part of the basin have been limited, perhaps because the few drilled exploration wells were unproductive for hydrocarbons, yielding trivial oil and gas. The partial integration of data in the southern Bredasdorp Basin provides another reason for the unsuccessful oil and gas exploration. In this study, selected Cretaceous mudrocks and sandstones (wacke) from exploration wells E-AH1, E-AJ1, E-BA1, E-BB1 and E-D3 drilled in the southern part of the Bredasdorp Basin were examined to assess their total organic carbon (TOC), thermal maturity, organic matter type and hydrocarbon generation potential. The organic geochemical results show that these rocks have TOC contents ranging from 0.14 to 7.03 wt.%. The hydrogen index (HI), oxygen index (OI), and hydrocarbon index (S2/S3) values vary between 24–263 mg HC/g TOC, 4–78 mg CO2/g TOC, and 0.01–18 mgHC/mgCO2 TOC, respectively, indicating predominantly Type III and IV kerogen with a minor amount of mixed Type II/III kerogen. The mean vitrinite reflectance values vary from 0.60–1.20%, indicating that the samples are in the oil-generation window. The Tmax and PI values are consistent with the mean vitrinite reflectance values, indicating that the Bredasdorp source rocks have entered the oil window and are considered as effective source rocks in the Bredasdorp Basin. The hydrocarbon genetic potential (SP), normalized oil content (NOC) and production index (PI) values all indicate poor to fair hydrocarbon generative potential. Based on the geochemical data, it can be inferred that most of the mudrocks and sandstones (wackes) in the southern part of the Bredasdorp Basin have attained sufficient burial depth and thermal maturity for oil and gas generation potential.

Sign in / Sign up

Export Citation Format

Share Document