Simultaneous measurement of exchangeable Al and other cations in acidic soils

Soil Research ◽  
2018 ◽  
Vol 56 (5) ◽  
pp. 503 ◽  
Author(s):  
Mark Conyers ◽  
Graeme Poile
Keyword(s):  
Contact Time ◽  
New South ◽  
Standard Procedure ◽  
Acid Soils ◽  
Exchange Capacity ◽  
Average Charge ◽  
Acidic Soils ◽  
South Wales ◽  
Exchangeable Al ◽  
Physical Mixing

It is both time consuming and costly to undertake two extractions of acidic soils when there is a need to measure exchangeable Al along with the other cations. There is some evidence that, although 1 M KCl is the standard procedure for exchangeable Al, the extraction of soil with 0.1 M BaCl2 + 0.1 M NH4Cl gives similar values. It would then be possible to measure all cations from one extraction. There is also concern that the assumption of trivalence of Al does not hold true in all situations, as commonly held to be true in the literature of the 1950s to the 1970s. Two experiments were conducted: the first a simple comparison of three extraction procedures in common use in New South Wales and the second a repeated comparison of two extractions but with more detailed measurements to enable interpretation of the results. During the second experiment we also measured the charge on the extracted Al by titration. The three methods for extraction of Al gave similar results despite very different procedures with respect to physical mixing, soil–solution contact time and strength of electrolyte, indicating that the pool of exchangeable Al was operationally well defined. The average charge on KCl-extracted Al was within error of 3 moles per mole of Al, supporting the current trivalent model of Alex. The 0.1 M BaCl2 + 0.1 M NH4Cl procedure estimated Alex successfully on acid soils of low effective cation exchange capacity (ECEC) (<10 cmolc/kg) and so can be used for extraction of all cations. However, as ECEC increased the 0.1 M BaCl2 + 0.1 M NH4Cl extraction tended to underestimate Alex compared with KCl on soils with above ~1.5 to 2 cmolc/kg of Alex.

The assessment of available manganese and aluminium status in acid soils under subterranean clover pastures of various ages

1983 ◽  
Vol 23 (121) ◽  
pp. 192 ◽  
Author(s):  
SM Bromfield ◽  
RW Cumming ◽  
DJ David ◽  
CH Williams
Keyword(s):  
Ammonium Acetate ◽  
New South ◽  
Acid Soils ◽  
Subterranean Clover ◽  
Exchange Capacity ◽  
Manganese Toxicity ◽  
Manganese Concentration ◽  
South Wales ◽  
Yield Responses ◽  
Practical Measure

Three methods of estimating available manganese and aluminium status in acid soils were compared on three groups of soils from the Pejar district near Goulburn, New South Wales in which differences in pH had been brought about by different periods under subterranean clover pasture. Managanese extracted by 0.01 M calcium chloride gave the best correlation with the manganese concentration in rape and subterranean clover grown in pot culture, and provided the best index of available manganese. Soil solution manganese was inferior to CaCl2-extractable manganese and was more difficult to determine. Extraction with neutral ammonium acetate was unsatisfactory because this reagent overestimated available forms of manganese in soils containing high levels of reactive manganese. Aluminium extracted by 0.01 M CaCl2 was well correlated with exchangeable aluminium and with percentage aluminium saturation of the effective cation exchange capacity. None of the three measures of aluminium status alone was an effective index for predicting lime response by rape on these soils because both manganese and aluminium status were involved in this response. These three parameters were equally effective in multiple regressions for yield responses of rape to lime. Because of its relative ease of determination, CaCl2 extraction is preferred as a practical measure of aluminium status. Aluminium interacted with and increased the toxic effects of manganese in rape. Thus CaCl2-extractable manganese alone only provided a satisfactory index of a 'critical' value for manganese toxicity in rape for soils low in available aluminium. Subterranean clover was only slightly affected by aluminium and manganese levels in these soils, and manganese toxicity symptoms were only observed on soils containing 50 ppm or more CaCl2-extractable manganese. Nodulation failure in pots occurred in all soils with pH below 5.2 (water) or below 4.3 in CaCl2, whereas nodulation was normal when these soils were treated with CaCO3 to raise the pH to 5.8-6.0 (water). With one exception nodulation appeared adequate at field sites from which soils showing nodulation failure in the glasshouse had been collected.

Lime responses by barley as related to available soil aluminium and manganese

1991 ◽  
Vol 42 (3) ◽  
pp. 379 ◽  
Author(s):  
MK Conyers ◽  
MK Conyers ◽  
GJ Poile ◽  
GJ Poile ◽  
BR Cullis ◽  
...  
Keyword(s):  
Dry Matter ◽  
New South ◽  
Extraction Procedure ◽  
Acid Soils ◽  
Dry Matter Yield ◽  
Pyrocatechol Violet ◽  
South Wales ◽  
Exchangeable Al ◽  
Pot Trials ◽  
Extractable Al

Twenty-three surface soils (0-10 cm) sampled from major New South Wales lime trials were incubated at six lime rates, from 0 to 10 t/ha, and used in pot trials with barley (Hordeurn vulgare cv. Schooner) which was grown for five weeks. Each replicate pot was soil tested for exchangeable cations (Ca, Mg, K, Na, Mn, Al), pH in 0.01 M CaCl2, and Al in the 0.01 M CaCl2 extract by pyrocatechol violet (total Al) and by reaction for 15 s in 8-hydroxyquinoline (monomeric Al). The latter was also converted to the activity of Al3 in the 0.01 M CaCl2 extract. The soil tests were compared for their prediction of the dry matter yield of whole tops of barley. The four tests for aluminium (exchangeable Al as Al/ECEC; total 0.01 M CaCl2 extractable Al; monomeric 0.01 M CaCl2 extractable Al; and Al3+ activity in 0.01 M CaCl2) were each better indicators of the infertility of the acid soils than soil pH. The prediction of the dry matter yield of barley by the four aluminium tests was improved by the inclusion of exchangeable soil manganese in the statistical analysis. The use of 0.01 M CaCl2 is recommended as a routine extraction procedure for diagnosing Al toxicity. Soil Mn should also be measured and included in correlations with barley growth. Pyrocatechol violet is the recommended analytical procedure for Al owing to its comparative simplicity.

Efficacy of various soil phosphate tests for predicting phosphate responsiveness and requirements of clover pastures on acidic tableland soils

Soil Research ◽  
1988 ◽  
Vol 26 (3) ◽  
pp. 479 ◽  
Author(s):  
ICR Holford ◽  
GJ Crocker
Keyword(s):  
White Clover ◽  
Significant Positive Correlation ◽  
New South ◽  
Acid Soils ◽  
Critical Values ◽  
Yield Response ◽  
Acidic Soils ◽  
Soil Phosphate ◽  
South Wales ◽  
Fertilizer Requirement

The efficacies of six different soil phosphate tests (Bray1, Bray2, alkaline fluoride, lactate, Olsen and Colwell) for predicting yield responsiveness and phosphate requirements of white clover pastures were investigated in 41 experiments over five years on acidic soils of the Northern Tablelands of New South Wales. The results contrasted with those obtained on slightly acid-to-alkaline wheat-growing soils and supported the dual hypothesis that a different type of phosphate extractant is required on acidic pasture soils from that required on more alkaline wheat-growing soils, and that phosphate sorptivity is of little importance on more acid soils. The Bray1 test was the most effective, and the lactate test least effective, in predicting responsiveness and fertilizer requirement. All soil tests, except Bray2 and lactate, were more effective on these acidic soils than on more alkaline wheat-growing soils. This was partly caused by a significant positive correlation between values of the more effective tests and yield response curvatures. However, there was no correlation between phosphate sorption and response curvature. The critical values for Bray1, fluoride and bicarbonate tests were similar to those on wheat-growing soils, but those for Bray2 and lactate were somewhat higher. Critical values for the Colwell test tended to increase with increasing phosphate sorptivity.

An examination of some acid soils at Batlow, New-South-Wales

Soil Research ◽  
1993 ◽  
Vol 31 (4) ◽  
pp. 437 ◽  
Author(s):  
IP Little
Keyword(s):  
Acid Soils ◽  
Principal Component ◽  
Apple Fruit ◽  
Exchange Capacity ◽  
Soil Survey ◽  
South Wales ◽  
Exchangeable Ca ◽  
Exchangeable Al ◽  
Clay Suspensions

This paper has two components. Firstly it evaluates a set of data for the apple-growing soils of the Batlow district. Secondly it makes some comments on the use of silver thiourea for the determination of exchangeable Al and Mn and the estimation of exchangeable Al by titration of 1 M KCl suspensions. A group of 21 profiles from soils used for apple-growing in the Batlow District were examined in the laboratory. It was found that many of the soils were very acidic, especially in the subsoil. Dilute CaCl2 extracted as much as 50 �g g-1 of Al and considerable exchangeable Al was extracted by silver thiourea. Exchangeable Ca levels were usually adequate for plant growth, hence low levels in apple fruit may reflect the adverse effect of Al on Ca uptake by the plant. Potassium levels were low and may be marginal in some cases and Mg tended to be low in the surface. Principal component analysis showed 77% of the variation in the data was accounted for by three independent components, one involving pH, exchangeable Ca and Al, one involving K and Mg and one involving exchangeable Mn. It was demonstrated that silver thiourea does not replace Al as effectively as the basic exchangeable cations. Also, thiourea reduces Mn so that low values will be obtained for exchangeable Al in soils with much easily reducible Mn because of the increase in pH that accompanies reduction. Silver thiourea appears to overestimate exchangeable Al in some soils with very low cation exchange capacity. Titration of clay suspensions in 1 M KCl is a satisfactory and reliable way of measuring exchangeable Al that also enables an assessment of pH-dependent charge. The method used by the USDA Soil Survey Staff, viz. equilibration of soil samples with 1 M KCl for 16 h, filtration, and determination of Al also gives reproducible results and is taken as the standard. Successive leaching with portions of 1 M KCl tends to give low values for exchangeable Al.

Acidification of soils on a transect from plains to slopes, south western New-South-Wales

Soil Research ◽  
1990 ◽  
Vol 28 (4) ◽  
pp. 539 ◽  
Author(s):  
CJ Chartres ◽  
RW Cumming ◽  
JA Beattie ◽  
GM Bowman ◽  
JT Wood
Keyword(s):  
Cation Exchange ◽  
Soil Acidification ◽  
Cation Exchange Capacity ◽  
Management Practices ◽  
New South ◽  
Exchange Capacity ◽  
Soil Types ◽  
The West ◽  
South Wales ◽  
Red Earth

Samples were collected from unimproved road reserves and adjacent paddocks on a 90 km transect crossing red-brown earth soils in the west and red earth soils in the east. Measurements of pH in water and CaCl2 indicated that the red earths have been acidified by approximately 0.5 pH units over the last 30-40 years. Small increases in CaCl2-extractable A1 were also recorded for the acidified red earths. The red-brown earths do not appear to have been markedly affected by soil acidification to date. Clay mineralogical data and measurements of cation exchange capacity of the <2 �m fraction indicate that red-brown earths are better buffered against acidification than red earths. However, small differences in management practices and rainfall along the transect may also be partially responsible for differences in acidification between soil types.

The residual effect of phosphorus on soil fertility and pasture development on acid soils

1951 ◽  
Vol 2 (4) ◽  
pp. 377 ◽  
Author(s):  
AJ Anderson ◽  
KD McLachlan
Keyword(s):  
Soil Fertility ◽  
New South ◽  
Total Yield ◽  
Acid Soils ◽  
Residual Effect ◽  
Early Years ◽  
High Fertility ◽  
South Wales ◽  
Phosphate Fixation ◽  
Nitrogen Demand

A study was made of the residual effect of superphosphate applied to pasture on acid soils on the Southern Tablelands of New South Wales. The effect of the superphosphate on the development of clover and subsequent changes in soil fertility and development of grass was examined. Only a limited proportion of the phosphorus applied was taken up by the pasture over the period of the experiments, but the evidence obtained suggests that this cannot be ascribed merely to phosphate fixation in the soil. The residual phosphorus was little, if any, less effective than current dressings over a number of years. The total yield of pasture was dependent almost entirely on the amount of superphosphate applied, and frequency of application had little or no effect on the total yield. A single dose at the commencement of the trials was as effective in increasing the total yield and the uptake of phosphorus as were annual dressings. High fertility and grass dominance were achieved by heavy annual dressings of superphosphate or by application of the bulk of the phosphorus in the early years. Lighter annual dressings resulted in clover dominance. Some advantages of heavier, less frequent application of superphosphate are discussed. Competition for phosphorus was an important factor in suppression of the clover by the grass. Evidence was presented in support of a hypothesis that grass or clover dominance is dependent both upon the vigour and fertility requirements of the species and upon the relation between the nitrogen demand of the pasture unit and the soil nitrogen status.

Effect of parent material, natural available soil boron, and applied boron and lime on the growth and chemical composition of lucerne on some acidic soils of the Central Tablelands of New South Wales

1982 ◽  
Vol 22 (117) ◽  
pp. 317 ◽  
Author(s):  
KS Haddad ◽  
CJ Kaldor
Keyword(s):  
Boron Content ◽  
Boron Concentration ◽  
New South ◽  
New South Wales ◽  
Water Soluble ◽  
Hot Water ◽  
Boron Deficiency ◽  
Alluvial Soils ◽  
Acidic Soils ◽  
South Wales

Fifteen acidic soils (0-1 5 cm), three from each of the five main parent materials in the Central Tablelands of New South Wales, were collected for a glasshouse experiment. The hot water soluble boron content of these soils and some other related soil properties were measured. Boron at nil and 1.5 �g/g air-dried soil and lime at nil and 670 �g/g air-dried soil in a factorial combination were applied to the soils. The effects of the treatments on the performance of lucerne (Medicago sativa cv. Hunter River) grown on these soils were studied. Boron application tended to increase the production of lucerne dry matter on sandstone, shale and slate, and granitic soils, but not on basaltic or alluvial soils. Also, it increased the boron concentration in the leaves of lucerne grown in all soils and consequently, reduced the calcium to boron ratio. The boron levels that produced 90% of the maximum yield and below which boron deficiency symptoms were manifested by the plants, were 0.34 �g/g in air-dried soil and 25 �g/g in oven-dried leaves. There was a linear correlation (r = 0.98) between the hot water soluble boron content of the untreated soils and the boron concentration in the leaves. The hot water soluble boron content of the soils derived from sandstone, shale and slate, and granite was much lower than the basaltic or alluvial soils and were nearly equal to or below the determined critical level. Although liming had the tendency to induce the symptoms of boron deficiency, the effect of lime was greater than boron in increasing the yield. The role of lime in eliminating the problems of these acidic soils and hence promoting the yield of lucerne is discussed.

The effect of biosolids on cereals in central New South Wales, Australia. 1. Crop growth and yield

2005 ◽  
Vol 45 (4) ◽  
pp. 435 ◽  
Author(s):  
J. L. Cooper
Keyword(s):  
Sewage Sludge ◽  
Soil Ph ◽  
New South ◽  
New South Wales ◽  
Acid Soils ◽  
Crop Growth ◽  
Growth And Yield ◽  
South Wales ◽  
Sludge Cake ◽  
Dewatered Sewage Sludge

Two forms of biosolids, with and without lime, were applied to acid soils at 2 sites in central New South Wales. Wheat and triticale were then grown on these sites to determine the effect of biosolids on crop growth and yield. The forms of biosolids used were dewatered sewage sludge cake, and N-Viro Soil which is a lime amended sewage sludge. Dewatered sewage sludge cake was applied at rates of 0, 6, 12 and 24 dry Mg/ha, and N-Viro soil at 0, 1.5, 3.0 and 4.5 dry Mg/ha. Biosolids produced grain yield increases of over 50% at both sites, with the largest yield increases at the highest rate of dewatered sewage sludge. Continued cropping at 1 of the sites showed that significant yield increases were still obtained 3 years after the initial application. The addition of lime and N-Viro Soil raised soil pH, and produced small but long lasting yield increases. However, the main benefit of biosolids seems to have come from the nutrients they supplied rather than changes in soil pH.

The growth of improved pastures on acid soils. 1. The effect of superphosphate and lime on soil pH and on the establishment and growth of phalaris and lucerne

1985 ◽  
Vol 25 (1) ◽  
pp. 149 ◽  
Author(s):  
LJ Horsnell
Keyword(s):  
Soil Ph ◽  
New South ◽  
Acid Soils ◽  
Potassium Sulfate ◽  
First Year ◽  
Growth Responses ◽  
South Wales ◽  
Large Growth ◽  
Lime Application ◽  
Effect Of Surface

The response of improved pastures to the application of superphosphate is low on the acid sedimentary soils, of the Southern Tablelands of New South Wales, which contain high levels of exchangeable aluminium. An investigation was made into the effect of surface-applied fertilizers on soil pH and on the establishment and growth of lucerne and phalaris on these soils. At 6 weeks after the application of gypsum, superphosphate, or superphosphate plus potassium sulfate, soil pH (H2O) had decreased markedly. This effect extended to a depth of 20 cm, but decreased with time. Initially, lime application increased the pH of the surface soil only. When superphosphate was applied with lime the pH of the soil under the lime layer decreased to the same level as that found in the soil treated with superphosphate alone. Lime, however, had penetrated into the subsoil 102 weeks after application and substantially more so after 13 years. Soil pH (0.01 M CaCl2) was not depressed by the application of fertilizers. Growth and persistence of both species in the first summer were poor, but growth responses to phosphorus, lime and nitrogen increased after the first year. Lucerne showed large growth responses to lime, greater than those found on plots receiving nitrogen fertilizer. Lime reduced aluminium levels both in lucerne plants and in soil. It is suggested that the slow penetration of lime into the soil, the relatively quick effect of superphosphate in increasing subsoil acidity, and high soil aluminium levels are together responsible for the poor persistence and slow growth of both lucerne and phalaris in the early stages. The subsequent large dry matter responses of lucerne to lime are possibly related to increased nitrogen fixation and a lowering of plant and soil aluminium levels. It is suggested that the lime responses of phalaris are also related to lower aluminium levels.

Effect of biosolids compost on two NSW coastal soils used to grow vegetables

Soil Research ◽  
2002 ◽  
Vol 40 (5) ◽  
pp. 761 ◽  
Author(s):  
R. A. Sarooshi ◽  
G. C. Cresswell ◽  
L. Tesoriero ◽  
P. J. Milham ◽  
I. Barchia ◽  
...  
Keyword(s):  
New South ◽  
Nutrient Status ◽  
Exchange Capacity ◽  
Nutrient Loss ◽  
Vegetable Production ◽  
South Wales ◽  
Coastal Soils ◽  
C And N ◽  
Initial Difference ◽  
Biosolids Compost

The study compares the effects of biosolids compost (BC) and inorganic fertiliser (IF) on the nutrient status of a clay loam at Rydalmere in Western Sydney, and an earthy sand at Somersby, 85 km north of Sydney. The soils represent the textural range used for vegetable production in the Sydney Basin of New South Wales. The soils had been under permanent sod (Rydalmere) or native vegetation (Somersby) for at 40 years prior to the experiment. There were 3 treatments during February 1994: IF, fallow (F), and BC. The same plots were treated again during September 1994 to give the combinations: IF followed by IF (IF + IF); F by BC (F + BC); BC by BC (BC + BC). The 4 replicates of each treatment were randomised in blocks. Treatments were incorporated into raised beds to a depth of 15 cm and vegetables were planted in March and again in October 1994. The total amounts of C and N initially present in the soil in the beds (0-15 cm) at Rydalmere were at least 3 times greater than at Somersby and the ratio was greater for S, P, Ca, Mg, K, and Na. By April 1995, the quantities of the 8 monitored nutrients had decreased at both sites for the IF + IF treatment; increased at Somersby, but not at Rydalmere for F + BC; and increased at both sites for the BC + BC treatment. The changes caused by the BC + BC treatment were greater in relative terms at Somersby, because of the initial difference in fertility between the 2 soils. For example, the C and N content increased by an approximate factor of 2 at Somersby, and by greater factors for the other elements. BC + BC was also the only treatment to increase other indices of fertility, such as effective cation exchange capacity (ECEC) and Bray-P, in the surface 15 cm. The treatments did not affect pH in the soil profile (0-50 cm) and increases in EC were ephemeral. The nutrient composition of the 20-30 cm zone was affected at both sites. By the end of the experiment the concentration of C, N, P, Ca, and Bray-P increased and Mg decreased. For C and N between-treatment differences were small, indicating that the observed effects were mostly caused by leaching of the products of mineralisation of soil organic matter. Treatment effects were larger for P, Ca, Mg, and Bray-P, and the final concentrations for the F + BC and BC + BC treatments exceeded those for the IF + IF treatment. At Somersby, both BC treatments increased ECEC, consistent with the importance of leaching as a process of nutrient loss at this site. Consequently, intensive vegetable cropping may pose serious environmental risks particularly on sandy sites.

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