Predicting lime-induced changes in soil-pH From exchangeable aluminum, soil-Ph, total exchangeable cations and organic-carbon values measured on unlimed soils

Soil Research ◽  
1995 ◽  
Vol 33 (1) ◽  
pp. 31 ◽  
Author(s):  
Z Hochman ◽  
GJ Crocker ◽  
EB Dettman
Keyword(s):  
Organic Carbon ◽  
Soil Ph ◽  
Field Experiments ◽  
Acid Soils ◽  
Exchangeable Cations ◽  
Ion Concentration ◽  
Soil Parameters ◽  
Ph Change ◽  
Data Set ◽  
Hydrogen Ion Concentration

The 'Lime-it' model is a decision support system for graziers wanting to lime acid soils. In this study we used field experimental data to test, improve and validate the model's ability to predict changes in soil pH due to variable rates of lime. Data from 13 field experiments, in which soil parameters were measured 1 year after liming acid soils, were used to derive an index of pH responsiveness to lime (LRI) at each site. Multivariate analysis was used to derive a predictive model: LRI was found to be significantly correlated (P < 0.0001) with hydrogen ion concentration ([H+]x 105 ), exchangeable aluminium (Al), exchangeable cations (TEC) and percent organic carbon (C) data of the unlimed soils. The multivariate equation was then tested against an independent data set by comparing the predicted pH change with the measured pH change for eight soils. This evaluation, though generally acceptable, showed a small but significant deviation from the desired 1:1 ratio between observed and predicted pH change. We re-calibrated the model for the combined data to derive the model: LRI = 0.764 + 0.042 [H+] - 0.016 TEC - 0.097 Al - 0.016 C. When this model was tested over the whole data set for predicted v. measured pH changes, the following result was found: measured pH change = 1.01 (predicted pH change) - 0.05 (R2 = 0.85, n = 308). The implications of the predictive equation are considered with regard to the mechanisms that are thought to be associated with pH buffering.

EFFECTS OF SOIL ACIDITY ON RHIZOBIA NUMBERS, NODULATION AND NITROGEN FIXATION BY ALFALFA AND RED CLOVER

1977 ◽  
Vol 57 (2) ◽  
pp. 197-203 ◽  
Author(s):  
W. A. RICE ◽  
D. C. PENNEY ◽  
M. NYBORG
Keyword(s):  
Nitrogen Fixation ◽  
Soil Ph ◽  
Soil Acidity ◽  
Field Experiments ◽  
Rhizobium Meliloti ◽  
Acid Soils ◽  
Red Clover ◽  
Ion Concentration ◽  
Hydrogen Ion Concentration ◽  
Greenhouse Experiments

The effects of soil acidity on nitrogen fixation by alfalfa (Medicago sativa L.) and red clover (Trifolium pratense L.) were investigated in field experiments at 28 locations, and in greenhouse experiments using soils from these locations. The pH of the soils (limed and unlimed) varied from 4.5 to 7.2. Rhizobia populations in the soil, nodulation, and relative forage yields (yield without N/yield with N) were measured in both the field and greenhouse experiments. Rhizobium meliloti numbers, nodulation scores, and relative yields of alfalfa decreased sharply as the pH of the soils decreased below 6.0. For soils with pH 6.0 or greater, there was very little effect of pH on any of the above factors for alfalfa. Soil pH in the range studied had no effect on nodulation scores and relative yields of red clover. However, R. trifolii numbers were reduced when the pH of the soil was less than 4.9. These results demonstrate that hydrogen ion concentration is an important factor limiting alfalfa growth on acid soils of Alberta and northeastern British Columbia, but it is less important for red clover. This supports the continued use of measurements of soil pH, as well as plant-available Al and Mn for predicting crop response to lime.

EFFECTS OF CALCIUM CARBONATE AND SULPHATE ON THE GROWTH OF LETTUCE AND RADISH IN SOME ORGANIC SOILS OF SOUTHWESTERN QUEBEC

1975 ◽  
Vol 55 (2) ◽  
pp. 205-212 ◽  
Author(s):  
WM. VAN LIEROP ◽  
A. F. MACKENZIE
Keyword(s):  
Calcium Carbonate ◽  
Soil Ph ◽  
Field Experiments ◽  
Acid Soils ◽  
Organic Soils ◽  
Ph Effects ◽  
Ph Change ◽  
Significant Treatment ◽  
Significant Yield ◽  
Yield Depression

The effects of lime and gypsum applications were determined on lettuce yields, soil pH and extractable aluminum for 10 organic soils. No increase in yield attributable to liming was found beyond pH 4, and a significant yield depression occurred with gypsum treatments. Further, the more acid soils outyielded the less acid but denser cultivated soils. Although the limestone applications increased soil pH significantly, significant treatment–soil interaction effects were found, and were ascribed to lower soil-limestone reactivities of the denser, less acid organic soils. Consequently, soil pH change upon liming was significantly correlated with bulk density and percent ash. Maximum yields were obtained at extractable aluminum levels lower than 0.1 meq/100 g soil. Further, potentially toxic levels of extractable aluminum disappeared at the same pH as maximum attainable lettuce yields; consequently, its possible toxicity was associated with pH effects in these soils. Field experiments with radishes grown on two organic soils gave initial increases in yields. This effect was surmised to be due to increased N-mineralization, because subsequently the controls outyielded the liming treatments.

Hydro-geochemical properties with respect to landuse in the southernmost river of Kerala

2018 ◽  
Vol 6 (1) ◽  
Author(s):  
Badusha M. ◽  
Santhosh S
Keyword(s):  
Organic Carbon ◽  
Drainage Basin ◽  
Anthropogenic Activities ◽  
Oxygen Demand ◽  
Ion Concentration ◽  
Total Hardness ◽  
Hydrogen Ion Concentration ◽  
Geochemical Properties ◽  
Quality Of Water

The hydro geochemical features of Neyyar River for a period of one year from May 2015 to April 2016 were analyzed. Six sampling sites were fixed considering physiography and present landuse pattern of the river basin. The residents in the drainage basin are primarily responsible for framing a better landuse and thereby maintain a good water and sediment regime. Geospatial pattern of the present landuse of the study area indicated that the sustainability of this river ecosystem is in danger due to unscientific landuse practices, which is reflected in the river quality as well. The parameters such as hydrogen ion concentration, electrical conductivity, chloride, Biological Oxygen Demand, total hardness and sulphate of river water and Organic Carbon of river bed sediments were analyzed in this study. The overall analysis shows that the highland areas are characterized by better quality of water together with low organic carbon, which is mainly due to better landuse and minimal reclamation. The midland and lowland areas are characterized by poor quality of water with high organic carbon, which is due to high anthropogenic activities and maximum pollutants associated with the region together with the alteration in landuse from a traditional eco-friendly pattern to a severely polluted current pattern.

AN ASSESSMENT OF THE SOIL ACIDITY PROBLEM IN ALBERTA AND NORTHEASTERN BRITISH COLUMBIA

1977 ◽  
Vol 57 (2) ◽  
pp. 157-164 ◽  
Author(s):  
D. C. PENNEY ◽  
M. NYBORG ◽  
P. B. HOYT ◽  
W. A. RICE ◽  
B. SIEMENS ◽  
...  
Keyword(s):  
British Columbia ◽  
Soil Ph ◽  
Soil Acidity ◽  
Field Experiments ◽  
Trifolium Pratense ◽  
Acid Soil ◽  
Acid Soils ◽  
Red Clover ◽  
Hordeum Vulgare L ◽  
Crop Species

The amount of cultivated acid soil in Alberta and northeastern British Columbia was estimated from pH values of farm samples analyzed by the Alberta Soil Testing Laboratory, and the effect of soil acidity on crops was assessed from field experiments on 28 typical acid soils. The field experiments consisted of two cultivars of barley (Hordeum vulgare L.) and one cultivar each of rapeseed (Brassica campestris L.), red clover (Trifolium pratense L.) and alfalfa (Medicago sativa L.) grown with and without lime for 2 yr. There are about 30,000 ha of soils with a pH of 5.0 or less where soil acidity seriously restricts yields of all four crop species. There are approximately 300,000 ha with a soil pH of 5.1–5.5 where liming will on the average increase yields of alfalfa by 100%, yields of barley by 10–15%, and yields of rapeseed and red clover by 5–10%. There are a further 1,600,000 ha where soil pH ranges from 5.6 to 6.0 and liming will increase yields of alfalfa by approximately 50% and yields of barley, rapeseed and red clover by at least 4–5%.

The interaction between soil pH and phosphorus for wheat yield and the impact of lime-induced changes to soil aluminium and potassium

Soil Research ◽  
2017 ◽  
Vol 55 (4) ◽  
pp. 341 ◽  
Author(s):  
Craig A. Scanlan ◽  
Ross F. Brennan ◽  
Mario F. D'Antuono ◽  
Gavin A. Sarre
Keyword(s):  
Grain Yield ◽  
Soil Ph ◽  
Field Experiments ◽  
Wheat Yield ◽  
Acid Soils ◽  
Combined Effect ◽  
Additive Effect ◽  
Yield Response ◽  
Response Curves ◽  
The Impact

Interactions between soil pH and phosphorus (P) for plant growth have been widely reported; however, most studies have been based on pasture species, and the agronomic importance of this interaction for acid-tolerant wheat in soils with near-sufficient levels of fertility is unclear. We conducted field experiments with wheat at two sites with acid soils where lime treatments that had been applied in the 6 years preceding the experiments caused significant changes to soil pH, extractable aluminium (Al), soil nutrients and exchangeable cations. Soil pH(CaCl2) at 0–10cm was 4.7 without lime and 6.2 with lime at Merredin, and 4.7 without lime and 6.5 with lime at Wongan Hills. A significant lime×P interaction (P<0.05) for grain yield was observed at both sites. At Merredin, this interaction was negative, i.e. the combined effect of soil pH and P was less than their additive effect; the difference between the dose–response curves without lime and with lime was greatest at 0kgPha–1 and the curves converged at 32kgPha–1. At Wongan Hills, the interaction was positive (combined effect greater than the additive effect), and lime application reduced grain yield. The lime×P interactions observed are agronomically important because different fertiliser P levels were required to maximise grain yield. A lime-induced reduction in Al phytotoxicity was the dominant mechanism for this interaction at Merredin. The negative grain yield response to lime at Wongan Hills was attributed to a combination of marginal soil potassium (K) supply and lime-induced reduction in soil K availability.

scholarly journals Plant-availability of soil and fertilizer zinc in cultivated soils of Finland

1993 ◽  
Vol 2 (3) ◽  
pp. 197-270
Author(s):  
Markku Yli-Halla
Keyword(s):  
Soil Ph ◽  
Field Experiments ◽  
Zinc Concentration ◽  
Acid Soils ◽  
Water Soluble ◽  
Peat Soils ◽  
Zn Uptake ◽  
Zn Concentration ◽  
Mineral Soils ◽  
Cultivated Soils

The Zn status of cultivated soils of Finland was investigated by chemical analyses and bioassays. The effect on ryegrass of different Zn fertilizers and Zn rates was studied in pot experiments and their effect on barley and timothy in field experiments. In an uncontaminated surface soil material of 72 mineral soils and 34 organogenic soils, total Zn (Zntot) was 10.3-202 mg kg-1(median 66 mg kg-1). In mineral soils, Zntot correlated positively with clay content (r = 0.81***) and in organogenic soils negatively with organic C (r = -0.53***). Zinc bound by organic matter and sesquioxides was sequentially extracted by 0.1 M K4P2O7 (Znpy) and 0.05 M oxalate at pH 2.9 (Znox), respectively. The sum Znpy + Znox, a measure of secondary Zn potentially available to plants, was 2 - 88% of Zntot and was the lowest in clay (median 5%) and highest in peat soils (median 49%). Water-soluble and exchangeable Zn consisted of0.3 - 37% (median 3%) of Zntot, the percentage being higher in acid soils, particularly in peat soils. Zinc was also extracted by 0.5 M ammonium acetate - 0,5 M acetic acid - 0.02 M Na2-EDTA at pH 4.65 (ZnAC), the method used in soil testing in Finland. The quantities of ZnAC (median 2.9 mg dm-3, range 0.6 - 29.9 mg dm-3) averaged 50% and 75% of Znpy + Znox in mineral and organogenic soils, respectively, and correlated closely with Znpy. In soil profiles, ZnAC was with few exceptions higher in the plough layer (0 - 20 cm) than in the subsoil (30 - 100 cm). In an intensive pot experiment on 107 surface soils, four crops of ryegrass took up 2 - 68% (median 26%)of Znpy + Znox. The plant-available Zn reserves were not exhausted even though in a few peat soils the Zn supply to grass decreased over time. Variation of Zn uptake was quite accurately explained by ZnAC but increasing pH had a negative impact on Zn uptake. Application of Zn (10 mg dm-3 of soil as ZnSO4 * 7 H2O) did not give rise to yield increases. In mineral soils, increase of plant Zn concentration correlated negatively with soil pH while ZnAC was of secondary importance. In those organogenic soils in which the reserves of native Zn were the most effectively utilized, plant Zn concentration also responded most strongly to applied Zn. In two 2-year field experiments, Zn application did not increase timothy or barley yields. Zinc concentration of timothy increased from 30 mg kg-1 to 33 and 36 mg kg-1 when 3 or 6 kg Zn ha-1 was applied, respectively. The efficiency of ZnSO4 * 7 H2O alone did not differ from that of a fertilizer where ZnSO4 * 7H20 was granulated with gypsum. Zinc concentration of barley grains increased by foliar sprays of Na2Zn-EDTA but only a marginal response to soil-applied Zn (4.8 or 5.4 kg ha-1 over three years) was detected in three 3-year experiments. High applications of Zn to soil (15 or 30 kg ha-1 as ZnSO4 * 7H2O) were required to increase Zn concentration of barley markedly. In order to prevent undue accumulation of fertilizer Zn in soil, it is proposed that Zn fertilizer recommendations for field crops should be based on both soil pH and ZnAC. In slightly acid and neutral soils, even if poor in Zn, response of plant Zn concentration to applied Zn remains small while there is a high response in strongly acid soils.

scholarly journals Technical note: Interpreting pH changes

2021 ◽  
Vol 18 (4) ◽  
pp. 1407-1415
Author(s):  
Andrea J. Fassbender ◽  
James C. Orr ◽  
Andrew G. Dickson
Keyword(s):  
Technical Note ◽  
Ion Concentration ◽  
Ph Change ◽  
Ph Measurements ◽  
Hydrogen Ion Concentration ◽  
Ph Changes ◽  
The Past ◽  
Initial Ph ◽  
Relative Change

Abstract. The number and quality of ocean pH measurements have increased substantially over the past few decades such that trends, variability, and spatial patterns of change are now being evaluated. However, comparing pH changes across domains with different initial pH values can be misleading because a pH change reflects a relative change in the hydrogen ion concentration ([H+], expressed in mol kg−1) rather than an absolute change in [H+]. We recommend that [H+] be used in addition to pH when describing such changes and provide three examples illustrating why.

scholarly journals The Use of Soil Parameters in Predicting Weed Infestation in Maize (Zea mays L.)

2015 ◽  
Vol 44 ◽  
pp. 15-24
Author(s):  
Gabriel Olulakin Adesina ◽  
Yetunde Bunmi Oyeyiola ◽  
Kasali Amofe Adelasoye ◽  
Akinpelu Festus Akin
Keyword(s):  
Organic Carbon ◽  
Soil Ph ◽  
Weed Management ◽  
Organic Fertilizer ◽  
Chemical Properties ◽  
Growth And Yield ◽  
Soil Parameters ◽  
Available Phosphorus ◽  
Fertilizer Treatment ◽  
Weed Species

A field work was carried out to investigate the extent to which selected soil chemical properties can influence weed species distribution. There were sixteen treatments of two factors (Fertilizer type and weeding regimes) laid out in RCBD. The treatments included four fertilizer types; no fertilizer (F1), inorganic fertilizer – NPK 15:15:15 applied at 100 kg NPK/ha (F2), organic fertilizer – phosphocompost applied at 2.5 t/ha and organomineral – 50% NPK 15:15:15 plus 50% phosphocompost. Four weeding regimes: weedy treatment (W1), weeding once (W2), weeding twice (W3) and weed free (W4). Weed free and weed once significantly improved maize growth and yield parameter under inorganic and organomineral fertilizer types. Increasing soil pH, organic carbon and available phosphorus significantly reduced total weed biomass with plot that received no fertilizer been responsible for highest weed population. In organic fertilizer treatment significantly reduced soil pH from the initial 6.5 to 6.0 though, it combination with weed once or weed twice gave highest grain yield. Better nutrition (in terms of improved soil nutrient especially macro nutrient and organic carbon) when combined with weeding once can ascertain proper weed management and sustainable maize production.

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