scholarly journals Freshwater salinization syndrome on a continental scale

2018 ◽  
Vol 115 (4) ◽  
pp. E574-E583 ◽  
Author(s):  
Sujay S. Kaushal ◽  
Gene E. Likens ◽  
Michael L. Pace ◽  
Ryan M. Utz ◽  
Shahan Haq ◽  
...  

Salt pollution and human-accelerated weathering are shifting the chemical composition of major ions in fresh water and increasing salinization and alkalinization across North America. We propose a concept, the freshwater salinization syndrome, which links salinization and alkalinization processes. This syndrome manifests as concurrent trends in specific conductance, pH, alkalinity, and base cations. Although individual trends can vary in strength, changes in salinization and alkalinization have affected 37% and 90%, respectively, of the drainage area of the contiguous United States over the past century. Across 232 United States Geological Survey (USGS) monitoring sites, 66% of stream and river sites showed a statistical increase in pH, which often began decades before acid rain regulations. The syndrome is most prominent in the densely populated eastern and midwestern United States, where salinity and alkalinity have increased most rapidly. The syndrome is caused by salt pollution (e.g., road deicers, irrigation runoff, sewage, potash), accelerated weathering and soil cation exchange, mining and resource extraction, and the presence of easily weathered minerals used in agriculture (lime) and urbanization (concrete). Increasing salts with strong bases and carbonates elevate acid neutralizing capacity and pH, and increasing sodium from salt pollution eventually displaces base cations on soil exchange sites, which further increases pH and alkalinization. Symptoms of the syndrome can include: infrastructure corrosion, contaminant mobilization, and variations in coastal ocean acidification caused by increasingly alkaline river inputs. Unless regulated and managed, the freshwater salinization syndrome can have significant impacts on ecosystem services such as safe drinking water, contaminant retention, and biodiversity.

2006 ◽  
Vol 63 (3) ◽  
pp. 471-474 ◽  
Author(s):  
Daniel Houle ◽  
Rock Ouimet ◽  
Suzanne Couture ◽  
Christian Gagnon

The acidification of forest soils and surface waters and their relatively poor recovery record following reductions in atmospheric sulphur emissions is a major ongoing environmental problem, particularly in northeastern North America. The slow recovery of surface water is widely hypothesized to result from depletion of reservoirs of base cations in soil. This is concordant with the theory that the acid-neutralizing capacity (ANC) of lakes is likely proportional to the size of the exchangeable base cation reservoirs present in surrounding watershed soils. However, data describing these linkages are still nonexistent in the literature. Here we show that lake ANC is highly predictable (r2 = 0.75) based on the size of the exchangeable Ca2+ reservoir in soil in 21 catchments representative of soil and lake conditions encountered in northeastern North America. This finding indirectly supports the hypothesis that the poor recovery of surface water from acidification is governed by the size of base cation reservoirs present in catchment soils. The size of the base cation reservoir in soil is thus a strong indicator of the acid–base status of both soils and surface waters.


1995 ◽  
Vol 26 (4-5) ◽  
pp. 369-388 ◽  
Author(s):  
Espen Lydersen ◽  
Arne Henriksen

Input of neutral salt, primarily NaCl, from sea spray is an important factor for short-term acidification of surface water, primarily in already acidified areas, because Na may substitute for H+ and cationic aluminium by cation-exchange reactions in the soil. By evaluating the variation of non-marine sodium (Na*) separately it is possible to estimate the major effect of seasalt episodes on the neutralizing capacity (ANC) of stream water. At four long-term monitored Norwegian catchments, the Na* in stream water on average explained 28 ± 4% of the monthly variations of ANC in stream water at Birkenes, and 27 ± 3%, 20 ± 2% and 56 ± 5% of the correspondent variations at Storgama, Langtjern and Kaarvatn, during the respective monitoring periods. The remaining variations in acid neutralizing capacity are explained by the difference between non-marine base cations (ΣCa*,Mg*,K*) and non-marine sulphate (SO4*) and NO3. This paper also indicates that seasalt episodes are probably of greater importance for the periodic variations in ANC of stream water than commonly recognized. During the last years, extreme seasalt episodes have occurred in southern Norway, and more frequently at winter-time, which means that seasalt inputs have played a more important role for the short-term variations of ANC in stream water the last years. This tendency is also strengthened by the fact that there has been a significant decline in the input of acidic sulphur compounds and non-marine base cations in stream water during the last 10-15 years. Because the decline in soil-derived base cations in stream water is somewhat lower than the correspondent decline of sulphate, a slowly improving ANC of stream water should be expected on long-term basis. Seasalt episodes of the same magnitude as those present during the last years, will therefore most likely cause less extreme water-chemical conditions in the years to come. Because the seasalt effect seems to be a short-term effect, there is no reason to claim that these effects may cause long-term acidification, a conclusion earlier drawn from several correspondent studies.


Analysis of sediment diatom and chrysophyte assemblages is the best technique currently available for inferring past lake water pH trends. Use of this approach for assessing the ecological effects of acidic deposition is increasing rapidly. As of August 1989, sediment core inferred pH data existed for at least 150 lakes in North America and cores from about 100 more lakes are being analysed. Equations for inferring past pH are based on at least 15-20 calibration data-sets involving about 700 lakes. Palaeolimnological studies indicate that recent acidification has been caused by acidic deposition in the Adirondack Mountains (New York), northern New England, Ontario, Quebec and the Canadian Atlantic provinces. Inferred pH decreases are commonly as much as 0.5-1.0 pH units. With the exception of one lake, no acidification trends were observed in regions currently receiving low deposition of strong acids (e.g. Rocky Mountains and Sierra Nevada in the western United States). Slight or no trends towards decreasing pH were observed in study lakes receiving moderately acidic deposition (upper Mid-west and northern Florida). The amount of inferred acidification (increase in H + concentration) correlates with the amount of S and N loading and the ability of watersheds and lakes to neutralize acid inputs, and is generally consistent with current lake-acidification theory. In most cases, the primary cause of recent acidification (post-1850) is acidic deposition, as opposed to land-use changes or natural processes, though these may be contributing factors. Acid loading has decreased in some regions since 1970 (e.g., northeastern United States). Some lakes have become less acidic in response, but others continue to lose acid neutralizing capacity. Many currently acidic lakes were naturally acidic (pH < 5.5) before the onset of anthropogenic acidification. These lakes are typically small (less than 10 ha) are located at moderately high elevations, have thin or peaty soils, or are located in outwash deposits. Many of these have acidified further recently.


2001 ◽  
Vol 58 (11) ◽  
pp. 2271-2283 ◽  
Author(s):  
Brian E Margolis ◽  
Mark S Castro ◽  
Richard L Raesly

We measured the impacts of beaver impoundments on the water chemistry of two headwater streams on the Appalachian Plateau, an unnamed tributary to Herrington Creek (HR), and Mountain Run (MT). We measured acid-neutralizing capacity (ANC), pH, conductivity, discharge, temperature, and the concentrations of major ions, dissolved organic carbon (DOC), and trace metals in stream water upstream and 1 m, 10 m, and 100 m downstream of the beaver impoundments and at two locations, 147 m apart, in a tributary to HR that did not contain a beaver impoundment. There were significant differences in water chemistry upstream and downstream of the beaver impoundments at both MT and HR, but these differences were generally confined to the summer. During the summer, both beaver impoundments generated ANC and increased pH by acting as sinks for NO3– and sources of NH4+, iron, and manganese. In addition, the beaver impoundment at MT was a sink for SO42– and the impoundment at HR was a source of DOC. The generation of ANC by beaver impoundments may be important to streams of this region where inputs of strong acids from atmospheric deposition are relatively high.


2000 ◽  
Vol 30 (8) ◽  
pp. 1206-1213 ◽  
Author(s):  
C W Martin ◽  
C T Driscoll ◽  
T J Fahey

Long-term patterns of streamwater chemistry provide valuable evidence of the effects of environmental change on ecosystem biogeochemistry. Observations from old-growth forests may be particularly valuable, because patterns should not be influenced by forest succession. Water samples were collected biweekly from four streams in, and near, the old-growth forest watershed of the Bowl Research Natural Area in the White Mountains of New Hampshire from May 1973 through October 1974, and from June 1994 through June 1997. Average NO3– concentrations, which ranged from 40.8 to 46.1 µequiv.·L-1 in 1973-1974, declined significantly to averages of 14.9-20.1 µequiv.·L-1 during 1994-1997. Concentrations of the base cations, Ca2+ and Mg2+, also declined in stream water between the two sampling periods. The northeastern United States, including the study area, has been subjected to elevated atmospheric deposition of sulfur and nitrogen for more than 40 years. This observation has led to the concern that mature forest ecosystems may exhibit N saturation and depletion of Ca2+ from exchangeable soil pools. While the Bowl exhibits a pattern of elevated concentrations of NO3– throughout the year, suggestive of conditions of N saturation, concentrations have declined markedly over the last 20 years. Concentrations of Ca2+ have also declined suggesting possible depletion from the exchangeable soil pool, but the acid neutralizing capacity of stream water has remained constant or increased, indicating resistance to additional acidification.


2019 ◽  
Vol 1 ◽  
pp. 1-2
Author(s):  
Javier A. Arce-Nazario

<p><strong>Abstract.</strong> The question of how to communicate with lay audiences about dynamic spatial processes is important in many disciplines. A diversity of paradigms for representing space and time have been developed in cartography, GIS science, and geovisualization, but these paradigms are unlikely to converge to a standard representation of spatiotemporal data (Goodchild 2013). Thus, finding the best visualization techniques to support the general public’s understanding of spatiotemporal analysis requires some exploration. In the following, I discuss how this exploration produced the novel approaches to representing time and landscape dynamics in <i>geo/visual/isla</i>, which was a science-art exhibit about social and ecological changes in the landscape of Puerto Rico over the past century.</p><p><i>geo/visual/isla</i> (Museo Casa Blanca, San Juan, 2017) was developed from static, large-format prints of aerial imagery of the Caribbean island nation of Puerto Rico, which were created by a collective of undergraduate students and a geographer at the University of Puerto Rico at Cayey. The data associated with times in the 1930s were derived from aerial photographs provided by the Puerto Rican Department of Transportation, and more recent data were derived from the United States Geological Survey and United States Army Corps of Engineers. The exhibit ultimately presented an 80-year history of changes in the natural and constructed landscape, during a period in which shifting global and local economies, migration, climate events and colonial policies were drivers of dramatic landscape transitions. The purpose of the exhibit was to capture the beauty and the dynamics of the landscape’s history, while helping visitors to envision and discuss past landscape change and future land use in Puerto Rico.</p><p>The problem of geovisualizing time and change is an old one that has been extensively reviewed – for example, by Yuan (2016) – but when the audience is a general public, there are additional challenges. Most notably, the limited period of interaction that a lay person will have with the geospatial data in question means that the scheme for representing space and time together must be either simple or familiar to be successful. Many creators of geographic exhibits for lay audiences do utilize well-established geovisualization paradigms such as the space-time cube (Bogucka and Jahnke 2017), the time-animated series of maps (Harner, Knapp, and Davis-Witherow 2017), and the annotated timeline (Caine 2017). However, these techniques must be adapted for the intended audience: the authors in each case highlight the specific techniques they use to help viewers by reducing the information burden and interpretation ambiguity of the representations they choose.</p><p> Like these other public geographic exhibits, <i>geo/visual/isla</i> extensively used an early cartographic representation of time, which was chosen for its simplicity and familiarity. Several of the works in the exhibit were “time-slice snapshots,” as described by Langran and Chrisman (1998). We took advantage of the rich vocabulary of the human experience of time to help viewers more easily navigate the temporal dimension of the data being displayed. For example, we encouraged viewers to associate neighboring time-slices by using the visual metaphor of the triptych, and used color schemes emphasizing the time coordinate (Figure 1). Spatial orientation between images was reinforced by choosing images with prominent, essentially consistent landscape features such as a coastline. The triptych format also reduced the temporal resolution to a manageable level, reducing the information burden noted above.</p><p> Perhaps the most important distinction between science-art exhibits and GIS representations or standalone geovisualizations is possibility to use the exhibit site as an additional dimension of experience. Harner, Knapp, and Davis-Witherow (2017) used this space for physical objects, and describe how their exhibit’s interactive maps replace interpretation of these objects by curators. In <i>geo/visual/isla</i>, we chose the inverse relationship: the space itself provided orientation that helped viewers interpret the maps. This was achieved by two techniques: first, the viewers’ path through the exhibit allowed them to learn the “vocabulary” of the space-time representation as they progressed. Timeslice snapshots gave way to more complex presentations where data with different space and time coordinates appeared in the same frame (Figure 2). By the end of the exhibit, viewers were easily able to read the spatial landscape enough to understand the story of change in these blended presentations. Second, the environment in different parts of the exhibit hall reinforced an understanding of timescales. Images in the exhibit depicting topological landscape features in the 1950s and 1960s were portrayed in red-blue anaglyph images and viewed with paper anaglyph glasses. In this corner of the exhibit, which was populated by other visitors in “retro” glasses and complemented by artworks referencing visual tropes of other dimensions and flashbacks, our intention was to make the actual ambiance provoke discussions of this particular period of Puerto Rico’s past (Figure 3).</p><p>The techniques explored in <i>geo/visual/isla</i> made the dimensions of space and time equally easy to navigate for users, and our observation of visitors and their responses on surveys demonstrated that we successfully produced a conducive environment for substantive discussions of landscape change. The demonstrated effectiveness of the format is consistent with our visitor survey results from prior exhibitions (Arce-Nazario 2016). Our choices were specifically designed for a physical, artistic exhibit and a non-expert audience, but the training and cueing used to make <i>geo/visual/isla</i> work so well could also be adapted to other geovisualization presentations and tools.</p>


2021 ◽  
Vol 13 (18) ◽  
pp. 3631
Author(s):  
Austin Madson ◽  
Yongwei Sheng

Of the approximately 6700 lakes and reservoirs larger than 1 km2 in the Contiguous United States (CONUS), only ~430 (~6%) are actively gaged by the United States Geological Survey (USGS) or their partners and are available for download through the National Water Information System database. Remote sensing analysis provides a means to fill in these data gaps in order to glean a better understanding of the spatiotemporal water level changes across the CONUS. This study takes advantage of two-plus years of NASA’s ICESat-2 (IS-2) ATLAS photon data (ATL03 products) in order to derive water level changes for ~6200 overlapping lakes and reservoirs (>1 km2) in the CONUS. Interactive visualizations of large spatial datasets are becoming more commonplace as data volumes for new Earth observing sensors have markedly increased in recent years. We present such a visualization created from an automated cluster computing workflow that utilizes tens of billions of ATLAS photons which derives water level changes for all of the overlapping lakes and reservoirs in the CONUS. Furthermore, users of this interactive website can download segmented and clustered IS-2 ATL03 photons for each individual waterbody so that they may run their own analysis. We examine ~19,000 IS-2 derived water level changes that are spatially and temporally coincident with water level changes from USGS gages and find high agreement with our results as compared to the in situ gage data. The mean squared error (MSE) and the mean absolute error (MAE) between these two products are 1 cm and 6 cm, respectively.


2014 ◽  
Vol 11 (1) ◽  
pp. 173-184 ◽  
Author(s):  
H. Borg ◽  
M. Sundbom

Abstract. The water chemistry of streams and precipitation in the province of Jämtland, northern Sweden has been monitored since the 1980s to study long-term trends, occurrence of acid episodes, and effects of liming. The acidity in precipitation increased in the 1970s, followed by a loss of acid neutralizing capacity (ANC) and low pH in the streams. Sulfur deposition began to decrease in the 1980s, until approximately 2000, after which the decrease levelled out. Stream water sulfate concentration followed the precipitation trend but decreased more slowly and since the late 1990s a subtle increase was observed. Sulfate concentrations in the snow typically have been higher than or equal to the stream sulfate levels. However, during the period of rapid deposition decrease and also since 2005 stream sulfate has sometimes exceeded snow sulfate, indicating desorption of stored soil sulfate, possibly because of climate-related changes in run-off routes through the soil profiles, following shorter periods of frost. From 1982 to 2000, total organic carbon (TOC) increased by approximately 0.1 mg L−1 yr−1. The mean trends in sulfate and TOC from approximately 1990 until today were generally opposite. Acidic episodes with pH 4.0 at flow peaks occurred frequently in the unlimed streams, despite relatively well-buffered waters at baseflow. To evaluate the main causes for the loss of ANC during episodes, the changes in major ion concentrations during high flow episodes were evaluated. The most important factors contributing to ANC loss were dilution of base cations (Na+, K+, Ca2+, Mg2+), enrichment of organic anions and enrichment of sulfate. Wetland liming started in 1985 after which the earlier observed extreme peak values of iron, manganese and aluminium, did not reoccur. The studied area is remote from emission sources in Europe, but the critical load of acidity is still exceeded. The long-term recovery observed in the unlimed streams is thus slow, and severe acidic episodes still occur.


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