Feasibility of Using Coal Ash Residues as CO-Composting Materials for Sewage Sludge

1997 ◽  
Vol 18 (5) ◽  
pp. 563-568 ◽  
Author(s):  
J.W. C. Wong ◽  
M. Fang ◽  
G. X. Li ◽  
M. H. Wong
Keyword(s):  
2013 ◽  
Vol 20 (2) ◽  
pp. 303-320
Author(s):  
Ewa Krzywy-Gawrońska

Abstract A single-factor field experiment was carried out at the Cultivar Evaluation Station in Szczecin-Dabie in 2008-2010. The soil on which this experiment was set up is formed from light loamy sand (lls). In respect of granulometric composition, it is classified to the category of light soils, of soil quality class IV b and good rye complex. In the experiment, compost produced with municipal sewage sludge by the GWDA method was used. This compost contained clearly more nitrogen and phosphorus in relation to potassium. The content of heavy metals (Cd, Cu, Mn, Ni, Pb and Zn) in composts did not exceed standards of the Regulation of the Minister of Agriculture and Rural Development (Official Journal of Laws No. 165, item 765 of 2008) referring to organic fertilisers. In the study design, the following fertilisation treatments were applied: I - carbonate lime (CaCO3) at a dose of 1.5 Mg CaO · ha-1, II - high-calcium brown coal ash at a dose of 1.5 Mg CaO · ha-1, III - municipal sewage sludge compost at a dose of 250 kg N·ha-1, IV - municipal sewage sludge compost at a dose of 250 kg N · ha-1 + high-calcium brown coal ash at a dose of 1.5 Mg CaO · ha-1 (1st year of study), V - high-calcium brown coal ash at a dose of 1.5 Mg CaO · ha-1 (1st year of study), and 0.75 Mg CaO · ha-1 in following study years each, VI - municipal sewage sludge compost at a dose of 250 kg N · ha-1 + high-calcium brown coal ash at a dose of 1.5 Mg CaO · ha-1 (1st year of study), and 0.75 Mg CaO · ha-1 in following study years each. In addition, mineral fertilisation was applied annually in the form of multi-component fertiliser Polifoska 20, complex fertiliser Polimag S and ammonium nitrate. A test plant was perennial grass - Amur silver grass (Miscanthus sachariflorus). The obtained results show that Amur silver grass biomass contained on average the most nitrogen, ie 6.87 g·kg-1 d.m., in 2008, while the most phosphorus (0.39 g P·kg-1 d.m.), potassium (7.82 g K·kg-1 d.m.), magnesium (0.98 g Mg·kg-1 d.m.) and sulphur (1.19 g S·kg-1 d.m.) in 2010, whereas the most calcium ie 4.13 g Ca kg-1 d.m., in 2009. Significantly more nitrogen, calcium and sulphur was contained by Amur silver grass biomass from the objects where municipal sewage sludge compost had been applied without and with addition of high-calcium brown coal ash when compared to calcium carbonate or high-calcium brown coal ash being applied at a dose of 1.5 Mg CaO · ha-1. Differences in average phosphorus, potassium and magnesium contents in test plant biomass from particular fertilisation objects were not significant. The biomass of Amur silver grass contained significantly more cadmium, nickel, lead and zinc as affected by organic fertilisation without and with addition of high-calcium brown coal ash when compared with the objects where solely calcium carbonate or high-calcium brown coal ash had been introduced into soil. Differences in the average content of cadmium, nickel and zinc in test plant biomass from the objects fertilised with municipal sewage sludge compost without and with addition of high-calcium brown coal ash were not significant. The uptake of heavy metals by Amur silver grass biomass, ie its mean value of three harvest during three years of its cultivation, can be arranged in the following descending order of values: Zn > Mn > Pb > Cu > Ni > Cd. The degree of cadmium, copper, manganese, nickel, lead and zinc bioaccumulation in test plant biomass differed, depending on the fertilisation applied. The average degree of cadmium, nickel, lead and zinc accumulation after three study years was intense for all fertilisation objects, whereas average for copper and manganese.


2005 ◽  
Vol 19 (6) ◽  
pp. 2562-2570 ◽  
Author(s):  
M. Belén Folgueras ◽  
R. María Díaz ◽  
Jorge Xiberta ◽  
M. Purificación García ◽  
J. Juan Pis
Keyword(s):  

2013 ◽  
Vol 15 (3) ◽  
pp. 48-54
Author(s):  
Ewa Krzywy-Gawrońska

Abstract A field experiment was conducted univariate in 2008-2010 in the Variety Assessment Station in Szczecin - Dąbie. The soil on which the experience was based is made of light loamy sand (pgl). In terms of granulometric composition it includes it into the category of light soils, agricultural suitability complex IV b, good (5). The experiment included, inter alia, waste compost produced with municipal sewage sludge produced by *GWDA and ash from brown coal (waste grate). No normal ranges for heavy metals being specified in the ministerial regulations were used for environmental purposes, which are maximum 20, 500, 750, 300, 1000 and 16 mg per 1 kg dry matter for cadmium, chromium, lead, nickel, copper and mercury, respectively16 were exceeded in the sewage sludge being used to produce the compost. The field experiment design consisted of 6 fertilisation objects. A test plant was Virginia fanpetals (Sida hermaphodrita Rusby). The content of available phosphorus, potassium and magnesium in the soil, being fertilised with municipal SSC with and without an addition of high-calcium BCA, changed after three years. There was an increase in the content of available phosphorus, potassium and magnesium forms, on average by 8.5%, 16.0% and 9.0%, respectively. When analysing the chemical properties of soil before and after this study, it may be stated that respective systems of municipal sewage sludge compost and high-calcium brown coal ash application differently affected most soil richness indices. The best fertilisation effects were obtained in the system with municipal sewage sludge compost being applied at a dose corresponding to 250 kg N ∙ ha-1 as well as with high-calcium brown coal ash at a dose corresponding to 1.5 Mg CaO ∙ ha-1 being introduced into soil in the first year of study and at a dose corresponding to 0.75 Mg CaO ∙ ha-1 in successive years. Fertilisation with municipal sewage sludge compost without and with addition of high-calcium brown coal ash favourably affected the preservation of soil environment stability and improvement of soil chemical composition


2003 ◽  
Vol 44 (4) ◽  
pp. 419-432 ◽  
Author(s):  
D. Chaudhuri ◽  
S. Tripathy ◽  
H. Veeresh ◽  
M. A. Powell ◽  
B. R. Hart

1998 ◽  
Vol 64 (1) ◽  
pp. 55-61 ◽  
Author(s):  
M. Fang ◽  
J.W.C. Wong ◽  
G.X. Li ◽  
M.H. Wong

2019 ◽  
Vol 2019 ◽  
pp. 1-12
Author(s):  
Esam Al-Qadhi ◽  
Gaiye Li ◽  
Yaxing Ni

In this paper, the two-stage sintering process as a promising strategy has been adopted to prepare high-performance porous ceramics with high porosity. Sewage sludge and waste coal ash were used as raw materials and added were starch and CaCO3 as a mixed foaming agent. The chemical composition of the raw materials and mixed foaming agents were analyzed by standard techniques. All mixtures were prepared from fixed solid materials mixed at a ratio of 48 : 32 : 10 : 10 (wt.%) for coal ash, sludge, starch, and CaCO3, respectively, followed by granular molding, aging, sintering and property survey tests. The influence of heating rate, holding time, and heating temperature of the two stages on the characteristics of the as-obtained porous ceramics was deeply investigated. The properties investigated are apparent porosity, bulk density, compressive strength, and linear shrinkage. On the one hand, the results show that the major content of the raw materials is silica (SiO2). On the other hand, the results show that the first-stage sintering process had minimal influence on the properties, whereas the second-stage sintering process had a significant influence on the properties of the porous ceramics. With the optimized sintering parameters (temperature, heating rate, and holding time) of the first stage and second stage, we obtained a high-performance porous ceramic product with an apparent porosity up to 51.3%, bulk density up to 1.22 g/cm3, linear shrinkage up to 14.3%, and compressive strength up to 25.1 MPa. Also, the results of the phase composition and microstructure revolution showed sufficient glassy phases and feldspar (Ca, Na) (Si, Al)4O8, which are known to enhance bending strength of ceramics. A comparison of these properties and characteristics with those of standard porous ceramics revealed that the product developed in this study would compete favorably for real applications.


Minerals ◽  
2021 ◽  
Vol 11 (7) ◽  
pp. 778
Author(s):  
Agnieszka Bęś ◽  
Łukasz Sikorski ◽  
Krzysztof Szreder

Coal fly ash (CFA), which is generated in huge quantities in coal-fired power plants, is a problem worldwide. Mixtures with ash and sewage sludge alter morphological and biochemical characteristics of plants. In this experiment, the response of pine, spruce, beech and alder growing for four years to mineral mixtures based on coal fly ash and high salinity sewage sludge (SS) was studied. The four-year experiment determined the chlorophyll a fluorescence of the tested plants, their height and yield, the salinity level of the tested mixtures and their phytotoxicity. Mixtures of coal ash with sewage sludge proved to be more beneficial to plants than their separate application. After four years, among the studied species, the highest increase in height and biomass was recorded for European alder and Scots pine. These species were also characterized by high photosynthetic indices. Mixtures containing 29% SS created optimal conditions for the development of the studied tree species. Grey alder and ponderosa pine can be recommended for reclamation of degraded areas where CFA and SS mixtures are used.


2019 ◽  
Vol 136 ◽  
pp. 07026
Author(s):  
Qianfeng He ◽  
Jie Zhao ◽  
Ming Xu ◽  
Jing Tao ◽  
Peipei Zhang ◽  
...  

In this study, dewatered domestic sewage sludge of moisture content of 65.6% was used as a pore-forming agent to sinter Ceramics with kaolin clay, coal ash and sodium silicate at 1050-1100 oC for 20 min. The weight percentage of sludge of total dried solids was 60% with pore rate >45% and compressive >20 MPa. The Ceramics could be used as catalysts in heterogeneous Fenton-like system to treat phenol wastewater through modification by FeSO4 solution. After reaction with ceramics catalyst for 2.5 h, phenol removal of the wastewater could reach 99.87% from 100 mg/L to 0.13 mg/L and the COD removal is 85.75%. The performance of this catalyst was stable and had no significant in 30d repeat experiments.


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