Deep desulfurization of FCC gasoline by extraction with dicarboxylic acid-based deep eutectic solvents

2017 ◽  
Vol 35 (19) ◽  
pp. 1903-1909 ◽  
Author(s):  
Jing-jing Li ◽  
Miao Zhou ◽  
Xiao-dong Tang ◽  
Huan Xiao ◽  
Xiao-Pu Zhang
Keyword(s):  
Dicarboxylic Acid ◽  
Deep Eutectic Solvents ◽  
Fcc Gasoline ◽  
Deep Desulfurization

scholarly journals Deep desulfurization performance of thiophene with deep eutectic solvents loaded carbon nanotube composites

2021 ◽  
Vol 8 (4) ◽  
Author(s):  
Yue Liu ◽  
Jiaojiao Xue ◽  
Xin Zhou ◽  
Yingna Cui ◽  
Jingmei Yin
Keyword(s):  
Composite Material ◽  
Chemical Properties ◽  
Oxidation Mechanism ◽  
Deep Eutectic Solvents ◽  
Fuel Oil ◽  
Desulfurization Rate ◽  
Composites Materials ◽  
Deep Desulfurization ◽  
Physico Chemical ◽  
Nanotube Composites

One source of air pollution is the combustion of sulfur compounds in fuel oil. Reducing sulfur content in fuel oil has become a hot issue demanding timely solutions. Using ionic liquids and deep eutectic solvents (DESs) to remove sulfides in fuel oil has achieved good results presently. However, since DESs are liquid and their transportation and separation are inconvenient, a new way is proposed that the DESs are loaded on the carbon nanotubes (CNTs) with large specific surface area and good chemical stability. A series of composites materials (DESs/CNTs) were prepared. Finally, they are applied to the removal of sulfides in fuel oil. This loading method, which imparts introduced unique physico-chemical properties of the DESs to the carrier materials, preserves both advantages while overcoming some of the problems with DESs. The interaction between DESs and CNTs is mutual promotion. Therefore, this study has important theoretical significance and industrial application value. Under optimal conditions, when the reagent ChCl/p-TsOH (1 : 2) was loaded on multi-walled CNTs (OD = 30–60 nm) to prepare the composite material (ChCl/p-TsOH)/CNTs, the single desulfurization rate of the composite material was 95.8%. Finally, the catalytic/oxidation mechanism was studied systematically and this work would provide a green route for the desulfurization of fuels.

Deep desulfurization of fuels based on an oxidation/extraction process with acidic deep eutectic solvents

2015 ◽  
Vol 17 (9) ◽  
pp. 4552-4559 ◽  
Author(s):  
Jingmei Yin ◽  
Jinping Wang ◽  
Zhuo Li ◽  
Dan Li ◽  
Guang Yang ◽  
...  
Keyword(s):  
Deep Eutectic Solvents ◽  
Extraction Process ◽  
Deep Desulfurization

A series of acidic deep eutectic solvents were designed and synthesized, which could be used for the successful oxidation/extraction desulfurization of fuels.

scholarly journals Achieving deep desulfurization with inverse-micellar polyoxometalates and oxygen

RSC Advances ◽  
2021 ◽  
Vol 11 (16) ◽  
pp. 9043-9047
Author(s):  
Jinghui Wu ◽  
Yue Li ◽  
Menting Jiang ◽  
Yang Huo ◽  
Xianze Wang ◽  
...  
Keyword(s):  
Fcc Gasoline ◽  
Deep Desulfurization ◽  
Excellent Activity

(CTA)PMo4V8 exhibited excellent activity in treating S-containing compounds (dibenzothiophene (DBT), 4,6-dimethyldibenzothiophene (DMDBT), benzothiophene (BT) and thiophene) in real oils, i.e. diesel and FCC gasoline.

Deep desulfurization of fuels with cobalt chloride-choline chloride/polyethylene glycol metal deep eutectic solvents

Fuel ◽  
2018 ◽  
Vol 225 ◽  
pp. 104-110 ◽  
Author(s):  
Hang Xu ◽  
Dandan Zhang ◽  
Fengmin Wu ◽  
Xuefeng Wei ◽  
Jun Zhang
Keyword(s):  
Polyethylene Glycol ◽  
Cobalt Chloride ◽  
Choline Chloride ◽  
Deep Eutectic Solvents ◽  
Deep Desulfurization

Deep desulfurization of fuels: Are deep eutectic solvents the alternative for ionic liquids?

Fuel ◽  
2021 ◽  
Vol 293 ◽  
pp. 120297
Author(s):  
Filipa Lima ◽  
Luis C. Branco ◽  
Armando J.D. Silvestre ◽  
Isabel M. Marrucho
Keyword(s):  
Ionic Liquids ◽  
Deep Eutectic Solvents ◽  
Deep Desulfurization

One-pot furfural production using choline chloride-dicarboxylic acid based deep eutectic solvents under mild conditions

2019 ◽  
Vol 278 ◽  
pp. 486-489 ◽  
Author(s):  
Cornelius Basil Tien Loong Lee ◽  
Ta Yeong Wu ◽  
Chow Hung Ting ◽  
Ju Kheng Tan ◽  
Lee Fong Siow ◽  
...  
Keyword(s):  
Dicarboxylic Acid ◽  
Choline Chloride ◽  
Deep Eutectic Solvents ◽  
One Pot ◽  
Mild Conditions ◽  
Furfural Production

scholarly journals Positive Impact of Natural Deep Eutectic Solvents on the Biocatalytic Performance of 5-Hydroxymethyl-Furfural Oxidase

Catalysts ◽  
2020 ◽  
Vol 10 (4) ◽  
pp. 447 ◽  
Author(s):  
Gonzalo de Gonzalo ◽  
Caterina Martin ◽  
Marco W. Fraaije
Keyword(s):  
Dicarboxylic Acid ◽  
Carbonyl Compounds ◽  
Positive Impact ◽  
Deep Eutectic Solvents ◽  
Redox Enzymes ◽  
Beneficial Effects ◽  
Hydroxymethyl Furfural ◽  
Natural Deep Eutectic Solvents ◽  
The Stability ◽  
Positive Effect

Deep eutectic solvents (DESs) have been applied as cosolvents in various biocatalytic processes during recent years. However, their use in combination with redox enzymes has been limited. In this study, we have explored the beneficial effects of several DES as cosolvents on the performance of 5-hydroxymethylfurfural oxidase (HMFO), a valuable oxidative enzyme for the preparation of furan-2,5-dicarboxylic acid (FDCA), and other compounds, such as carbonyl compounds and carboxylic acids. The use of natural DESs, based on glucose and fructose, was found to have a positive effect. Higher conversions are obtained for the synthesis of several oxidized compounds, including FDCA. Depending on the type of DES, the stability of HMFO could be significantly improved. As the use of DES increases the solubility of many substrates while they only mildly affect dioxygen solubility, this study demonstrates that biocatalysis based on HMFO and other redox biocatalysts can benefit from a carefully selected DES.

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