scholarly journals Energy–momentum density and pressure relations for a relativistic ideal gas with a bulk motion

2020 ◽  
Vol 41 (6) ◽  
pp. 065602
Author(s):  
Ashok K Singal
Author(s):  
Ashok Singal

In the energy-momentum density expressions for a relativistic perfect fluid with a bulk motion, one comes across a couple of pressure-dependent terms, which though well known, are to an extent, lacking in their conceptual basis and the ensuing physical interpretation. In the expression for the energy density, the rest mass density along with the kinetic energy density of the fluid constituents due to their random motion, which contributes to the pressure as well, are already included. However, in a fluid with a bulk motion, there are, in addition, a couple of explicit, pressure-dependent terms in the energy-momentum densities, whose presence to an extent, is shrouded in mystery, especially from a physical perspective. We show here that one such pressure-dependent term appearing in the energy density, represents the work done by the fluid pressure against the Lorentz contraction during transition from the rest frame of the fluid to another frame in which the fluid has a bulk motion. This applies equally to the electromagnetic energy density of electrically charged systems in motion and explains in a natural manner an apparently paradoxical result that the field energy of a charged capacitor system decreases with an increase in the system velocity. The momentum density includes another pressure-dependent term, that represents an energy flow across the system, due to the opposite signs of work being done by pressure on two opposite sides of the moving fluid. From Maxwell's stress tensor we demonstrate that in the expression for electromagnetic momentum of an electric charged particle, it is the presence of a similar pressure term, arising from electrical self-repulsion forces in the charged sphere, that yields a natural explanation for the famous, more than a century old, 4/3 factor in the electromagnetic mass.


2020 ◽  
Author(s):  
Nayyereh hatefi ◽  
William Smith

<div>Ideal{gas thermochemical properties (enthalpy, entropy, Gibbs energy, and heat capacity, Cp) of 49 alkanolamines potentially suitable for CO2 capture applications and their carbamate and protonated forms were calculated using two high{order electronic structure methods, G4 and G3B3 (or G3//B3LYP). We also calculate for comparison results from the commonly used B3LYP/aug-cc-pVTZ method. This data is useful for the construction of molecular{based thermodynamic models of CO2 capture processes involving these species. The Cp data for each species over the temperature range 200 K{1500 K is presented as functions of temperature in the form of NASA seven-term polynomial expressions, permitting the set of thermochemical properties to be calculated over this temperature range. The accuracy of the G3B3 and G4 results is estimated to be 1 kcal/mol and the B3LYP/aug-cc-pVTZ results are of nferior quality..</div>


Author(s):  
Klaus Morawetz

The classical non-ideal gas shows that the two original concepts of the pressure based of the motion and the forces have eventually developed into drift and dissipation contributions. Collisions of realistic particles are nonlocal and non-instant. A collision delay characterizes the effective duration of collisions, and three displacements, describe its effective non-locality. Consequently, the scattering integral of kinetic equation is nonlocal and non-instant. The non-instant and nonlocal corrections to the scattering integral directly result in the virial corrections to the equation of state. The interaction of particles via long-range potential tails is approximated by a mean field which acts as an external field. The effect of the mean field on free particles is covered by the momentum drift. The effect of the mean field on the colliding pairs causes the momentum and the energy gains which enter the scattering integral and lead to an internal mechanism of energy conversion. The entropy production is shown and the nonequilibrium hydrodynamic equations are derived. Two concepts of quasiparticle, the spectral and the variational one, are explored with the help of the virial of forces.


1994 ◽  
Vol 72 (19) ◽  
pp. 2977-2980 ◽  
Author(s):  
J. I. Cirac ◽  
M. Lewenstein ◽  
P. Zoller
Keyword(s):  

Shock Waves ◽  
2021 ◽  
Author(s):  
C. Garbacz ◽  
W. T. Maier ◽  
J. B. Scoggins ◽  
T. D. Economon ◽  
T. Magin ◽  
...  

AbstractThe present study aims at providing insights into shock wave interference patterns in gas flows when a mixture different than air is considered. High-energy non-equilibrium flows of air and $$\hbox {CO}_2$$ CO 2 –$$\hbox {N}_2$$ N 2 over a double-wedge geometry are studied numerically. The impact of freestream temperature on the non-equilibrium shock interaction patterns is investigated by simulating two different sets of freestream conditions. To this purpose, the SU2 solver has been extended to account for the conservation of chemical species as well as multiple energies and coupled to the Mutation++ library (Multicomponent Thermodynamic And Transport properties for IONized gases in C++) that provides all the necessary thermochemical properties of the mixture and chemical species. An analysis of the shock interference patterns is presented with respect to the existing taxonomy of interactions. A comparison between calorically perfect ideal gas and non-equilibrium simulations confirms that non-equilibrium effects greatly influence the shock interaction patterns. When thermochemical relaxation is considered, a type VI interaction is obtained for the $$\hbox {CO}_2$$ CO 2 -dominated flow, for both freestream temperatures of 300 K and 1000 K; for air, a type V six-shock interaction and a type VI interaction are obtained, respectively. We conclude that the increase in freestream temperature has a large impact on the shock interaction pattern of the air flow, whereas for the $$\hbox {CO}_2$$ CO 2 –$$\hbox {N}_2$$ N 2 flow the pattern does not change.


Energies ◽  
2021 ◽  
Vol 14 (3) ◽  
pp. 772
Author(s):  
Jean-Christophe Hoarau ◽  
Paola Cinnella ◽  
Xavier Gloerfelt

Transonic flows of a molecularly complex organic fluid through a stator cascade were investigated by means of large eddy simulations (LESs). The selected configuration was considered as representative of the high-pressure stages of high-temperature Organic Rankine Cycle (ORC) axial turbines, which may exhibit significant non-ideal gas effects. A heavy fluorocarbon, perhydrophenanthrene (PP11), was selected as the working fluid to exacerbate deviations from the ideal flow behavior. The LESs were carried out at various operating conditions (pressure ratio and total conditions at inlet), and their influence on compressibility and viscous effects is discussed. The complex thermodynamic behavior of the fluid generates highly non-ideal shock systems at the blade trailing edge. These are shown to undergo complex interactions with the transitional viscous boundary layers and wakes, with an impact on the loss mechanisms and predicted loss coefficients compared to lower-fidelity models relying on the Reynolds-averaged Navier–Stokes (RANS) equations.


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