Self-organized nanocrack networks: a pathway to enlarge catalytic surface area in sputtered ceramic thin films, showcased for photocatalytic TiO2

2017 ◽  
Vol 29 (3) ◽  
pp. 035703 ◽  
Author(s):  
B Henkel ◽  
A Vahl ◽  
O C Aktas ◽  
T Strunskus ◽  
F Faupel
2002 ◽  
Vol 17 (1) ◽  
pp. 115-126 ◽  
Author(s):  
Maggie Paulose ◽  
Oomman K. Varghese ◽  
Craig A. Grimes

Sol-gel-derived metal oxide ceramic thin films deposited onto amorphous iron-rich substrates were found to form self-organized nanoporous structures dependent upon the extent to which the substrate is de-alloyed, a function of the substrate alloycomposition, acid concentration of the sol, and film drying conditions. Field emission scanning electron microscopy, transmission electron microscopy, and x-ray energy dispersive analysis were used to investigate details of the porous structure formation.Our studies showed the more electrochemically active elements in the amorphous substrate are de-alloyed by the sol in high-humidity environments, whereupon the liberated elements form oxides replicating the de-alloyed substrate matrix resulting in athree dimensional porous network structure.


Author(s):  
J.M. Schwartz ◽  
L.F. Francis ◽  
L.D. Schmidt ◽  
P.S. Schabes-Retchkiman

Ceramic thin films and coatings are of interest for electrical, optical, magnetic and thermal barrier applications. Critical for improved properties in thin films is the development of specific microstructures during processing. To this end, the sol-gel method is advantageous as a versatile processing route. The sol-gel process involves depositing a solution containing metalorganic or colloidal ceramic precursors onto a substrate and heating the deposited layer to form a crystalline or non-crystalline ceramic coating. This route has several advantages, including the ability to create tailored microstructures and properties, to coat large or small areas, simple or complex shapes, and to more easily prepare multicomponent ceramics. Sol-gel derived coatings are amorphous in the as-deposited state and develop their crystalline structure and microstructure during heat-treatment. We are particularly interested in studying the amorphous to crystalline transformation, because many key features of the microstructure such as grain size and grain size distribution may be linked to this transformation.


2008 ◽  
Author(s):  
Xiaomei Guo ◽  
Kewen Kevin. Li ◽  
Xuesheng Chen ◽  
Yingyin Kevin. Zou ◽  
Hua Jiang

2002 ◽  
Vol 38 (1) ◽  
pp. 50-56 ◽  
Author(s):  
Peng Miao ◽  
W. Balachandran ◽  
Ping Xiao

2012 ◽  
Vol 566 ◽  
pp. 145-149
Author(s):  
Hirotaka Tanabe ◽  
Keiji Ogawa ◽  
Yui Izumi ◽  
Tohru Takamatsu ◽  
Heisaburo Nakagawa ◽  
...  

In our previous study, it has been shown that improvement of the adhesive strength and substrate hardness of ceramic coated steels without compromising the film hardness can be achieved by applying laser quenching. In the present research, in order to demonstrate further development of this method, the fracture strength of laser-irradiated ceramic thin films (CrAlN, TiAlN and CrN) was investigated by sphere indentation testing. To prevent heat-induced changes in the substrate hardness, a cemented carbide WC-Co rather than steel was used as substrate material. While the fracture strength of each film decreased significantly through furnace heat treatment, it remained almost unchanged in case of the laser irradiated films. Laser quenching has been shown to effectively reduce the fracture strength loss of the ceramic thin films in coated steels.


RSC Advances ◽  
2015 ◽  
Vol 5 (6) ◽  
pp. 4443-4447 ◽  
Author(s):  
S. K. Shinde ◽  
D. P. Dubal ◽  
G. S. Ghodake ◽  
V. J. Fulari

We present a novel route for the synthesis of CuO thin films. The nano-flower like nanostructures provide high surface area, and the CuO shows excellent supercapacitive properties.


2014 ◽  
pp. 293-298
Author(s):  
Arjun Dey ◽  
Anoop Mukhopadhyay

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