The effect of the thickness on structural, optical limiting, and dielectric properties of hybrid coatings rhodamine B dye films on an epoxy polymeric substrate for display applications

2021 ◽  
Author(s):  
Wissal Jilani ◽  
Abdelfatteh Bouzidi ◽  
Albandary Almahri ◽  
Hajer Guermazi ◽  
Ibrahim Yahia

Abstract Various thickness of Rhodamine B (RhB) laser dye was deposited on epoxy polymeric as a new dielectric organic substrate by spin coating method for the first time. This study focused on the newly considered RhB dye on an epoxy substrate for wide-scale applications. The thickness effect on structural, optical, and dielectric properties of the hybrid coating films was performed. The XRD patterns of the films indicated a large hump amorphous design and lack of Bragg peak intensity associated with the RhB laser dye, due to amorphous film concentration. From UV-Visible spectroscopy, the optical absorption edge shifts to the higher wavelengths direction (redshift) with the variation in RhB dye thicknesses. It was found that the energy band gap decreased when the RhB dye film thickness changed. The refractive index is an important parameter influencing the optical component design. Their values vary according to each relationship that extremely useful the films in optical devices. Laser power attenuation sensitivity of pure epoxy polymeric substrate and its coating films shows that under reducing the thicknesses of RhB dye, the laser power intensity effect increases. Several dielectric parameters are extracted from the series and parallel capacitance measurements. The present results offer new material films for luminescent energy solar concentrator applications.

2015 ◽  
Vol 241 ◽  
pp. 226-236 ◽  
Author(s):  
Neha Solanki ◽  
Rajshree B. Jotania

Influence of Ca substitution on structural, magnetic and dielectric properties of Ba3Co2-xCaxFe24O41(where x = 0.0, 0.2, 0.4, 0.6, 0.8 and 1.0), prepared by Sol-Gel auto-combustion method, has been investigated in present studies. The obtained powder was sintered at 950 oC for 4 hrs. in the static air atmosphere. Structural analysis of Ca-doped Ba3Co2-xCaxFe24O41powders revealed pure Z-type hexaferrite phase at low temperature. The frequency dependent dielectric constant (Єʹ) and magnetic properties such as remanent magnetization (Mr), saturation magnetization (Ms) and coercivity (Hc) were studied. It is observed that coercivity increased gradually with increase in calcium content. The real dielectric constant (Єʹ) and dielectric loss tangent (tan δ) were studied in the frequency range of 20Hz to 2MHz. The dielectric parameters for all samples show normal dielectric behavior as observed in hexaferrites. Contents of Paper


2002 ◽  
Vol 10 (3) ◽  
pp. 219-228 ◽  
Author(s):  
Ye.P. Mamunya ◽  
V.V. Davydenko ◽  
H. Zois ◽  
L. Apekis ◽  
A.A. Snarskii ◽  
...  

The authors have studied the dielectric properties of composite materials based on both thermoplastic and thermoset resins filled with nickel or copper, with various particle sizes and shapes. In addition, two types of particle distribution, random and segregated, were produced for composites filled with nickel. The main objective was to study the effect of the above factors on the dielectric properties of the composites. The concentration dependence of the dielectric parameters (i.e. the real, ∊′, and the imaginary, ∊″, parts of the complex dielectric permittivity and the dielectric loss tangent, tanδ), calculated for all the systems studied, demonstrates a critical behaviour in the percolation threshold region, with maximum values reached at a volume fraction ϕ = ϕc. The dependence of the dielectric parameters on concentration follows power-law behaviour in the ϕ < ϕc region. The critical exponent value for ∊′ is q = 0.75, in agreement with the theoretical one. The dielectric characteristics of the filled composites are more sensitive to the spatial filler distribution. For the segregated PVC-Ni system with an ordered filler distribution, the value of ϕc is much lower than for ER-Ni composites with a random filler distribution. Besides, for the segregated PVC-Ni system, the value of q is not constant, as it depends on the filler concentration. A model for the structure, which explains this behaviour, is proposed.


1995 ◽  
Vol 09 (22) ◽  
pp. 1471-1477 ◽  
Author(s):  
C. V. BINDHU ◽  
S. S. HARILAL ◽  
RIJU C. ISSAC ◽  
GEETHA K. VARIER ◽  
V. P. N. NAMPOORI ◽  
...  

Measurement of thermal lensing signal as a function of laser power made in Rhodamine B solutions in methanol give clear evidence of two photon absorption process within certain concentration ranges when 488 nm Ar + laser beam is used as the pump source. Only one photon process is found to occur when 514 nm and 476 nm beams are used as the pump.


Author(s):  
Vishal Singh Chandel ◽  
Atiq UR Rahmanm ◽  
J. P. Shukla ◽  
Rajiv Manohar ◽  
Mohd. Shafi Khan

Effect of fungicides' (thiram, captan, carbendazim, bagalol) treatment on dielectric constant and dielectric loss of a vegetable seed, namely the brinjal at given moisture content and bulk density was examined using Hewlett-Packard (HP-4194A) impedance/gain phase analyzer over the frequency range of 0.01 to 10 MHz and temperature range of 30-450C. Julabo (temperature controller, F-25, Germany) was used for keeping the temperature of seeds constant. Study showed that fungicide treatment cast considerable change in dielectric parameters namely the dielectric constant and dielectric loss.


2012 ◽  
Vol 557-559 ◽  
pp. 1797-1802
Author(s):  
Xiao Ying Sun ◽  
Jianan Wang ◽  
Jian Zhong Hang ◽  
Lu Jiang Jin ◽  
Li Yi Shi

Hybrid sols were synthesized through a combination of hydrolysis and condensation reactions of tetraetoxysilane and γ-Methacryloxypropyltrimethoxysilane together with the addition of a colloidal silica suspension. A transparent, hard UV-curable hybrid coatings based on hybrid sols were prepared in order to improve the scratch and abrasion resistance of PMMA substrate. The effects of the content of colloidal silica suspension on pencil hardness, transmittance, and haze were investigated. The pencil hardness of all coating films in this study can be tuned from 4H to 9H, whereas that of uncoated PMMA substrate is 1H. The higher hardness of the coatings can be attributed to the dense structure induced by the increase of network density with the addition of colloidal silica suspension. Furthermore, it is found that the transmittance of coatings slightly fluctuates between 91.8% and 93.6% with increasing colloidal silica content. These results indicate the good compatibility of the organic and inorganic components.


2012 ◽  
Vol 2012.61 (0) ◽  
pp. _420-1_-_420-2_
Author(s):  
MAKOTO Takekawa ◽  
Yoshihiko UEMATSU ◽  
Toshifumi KAKIUCHI ◽  
Takema TERATANI ◽  
Yoshifumi KOBAYASHI ◽  
...  

2020 ◽  
Vol 13 (2) ◽  
pp. 165-170

Abstract: In this work, samples of zinc oxide nanoparticles doped by molybdenum (Zn1-xMoxO with 0 ≤ x ≤ 0.1) were prepared by using the wet co-precipitation method. The characterization of the prepared samples was carried out by means of X-ray powder diffraction (XRD). The samples reserved their hexagonal wurtzite structure with Mo doping and showed a decrease in the crystallite size up to x = 0.04 followed by a further increase. On the other hand, dielectric measurements were performed using an LCR meter. The effect of frequency and temperature on the dielectric properties such as the real and imaginary parts of dielectric constant (ε^' and ε'', respectively), dielectric loss (tanδ) and ac-conductivity (σ_ac) of Mo-doped zinc oxide samples, was studied in the frequency range (100 Hz - 1 MHz) and at temperatures (300 - 773 K). The values of room temperature dielectric parameters were found to be strongly dependent on the Mo-doping. However, the increase in temperature caused an enhancement in the values of the dielectric parameters, particularly at 773 K. Keywords: Zinc oxide, XRD, Dielectric constants, Ac-conductivity.


2018 ◽  
Vol 70 (1) ◽  
pp. 155-160 ◽  
Author(s):  
Shanshuang Shi ◽  
Huapeng Wu ◽  
Yuntao Song ◽  
Heikki Handroos

Purpose This paper aims to present a study on composite coating films for solid lubrication applied on the surface of bearings and gears, which are exposed to the vacuum vessel of a tokamak fusion experimental device running under ultra-high vacuum conditions. Experimental advanced superconducting tokamak is a tokamak fusion experimental device running under ultra-high vacuum conditions. To avoid polluting the inner vessel environment, solid lubrication has been applied on the surface of bearings and gears, which are exposed to the vacuum. Design/methodology/approach Anti-friction MoS2 coatings integrated with Titanium and Carbon have been developed using the multi-target magnetron sputtering deposition technique. This paper presents the comparative testing of tribological properties for three kinds of MoS2-based coating layers. Findings Based on the test results, MoS2-Ti-C coating films are supposed to be the final selection because of the better performance of friction coefficient and lubrication longevity. Originality/value Finally, the detailed information has been characterized for the hybrid coatings, which can provide some references for applications of solid lubrications under similar conditions of high vacuum and temperature.


Sign in / Sign up

Export Citation Format

Share Document