scholarly journals Influence of alkaline pre-treatment on acid dissolution of cathode material of 18650 lithium battery

2021 ◽  
Vol 882 (1) ◽  
pp. 012001
Author(s):  
Dessy Amalia ◽  
Pritam Singh ◽  
Wensheng Zhang ◽  
Aleksandar N. Nikoloski
Keyword(s):  
Lithium Batteries ◽  
Cathode Materials ◽  
Lithium Battery ◽  
Lattice Structure ◽  
Lithium Concentration ◽  
Acid Leaching ◽  
Hydrogen Gas ◽  
Copper Extraction ◽  
Acid Dissolution ◽  
Pre Treatment

Abstract Lithium battery cathodes contain lithium, cobalt, nickel, and manganese. Recycling of spent lithium batteries aims to recover these elements for re-use. Liberation of cathode materials from other metals in the battery such as aluminium, copper, and iron, is essential to obtain a good leaching efficiency in the recovery of valuable metals from end-of-life lithium batteries. This study investigates the behaviour of cathode materials and other metals in spent 18650 lithium batteries during leaching in H2SO4 solution with and without NaOH pre-treatment. Dissolution of aluminium using NaOH is a selective method to separate the metal from other elements. The influence of a 2-hour NaOH pre-treatment on subsequent acid leaching of cathode materials was investigated at both room temperature and 80°C. The extraction of aluminium increased to 75% at a higher temperature. Lithium concentration in the pregnant leach solution from acid leaching also increases with NaOH pre-treatment. The pre-treatment had a negligible effect on nickel, manganese, iron, and copper extraction. However, the cobalt extraction with NaOH pre-treatment was significantly lower. The result was likely due to indirect impact of less hydrogen gas was generated from a lower Al amount. The lattice structure of the leach residue for the sample with NaOH pre-treatment was monoclinic rather than rhombohedral due to stronger delithiation.

scholarly journals Fabrication and Characterization of Nylon 66/PAN Nanofibrous Film Used as Separator of Lithium-Ion Battery

Polymers ◽  
2021 ◽  
Vol 13 (12) ◽  
pp. 1984
Author(s):  
Yu-Hsun Nien ◽  
Chih-Ning Chang ◽  
Pao-Lin Chuang ◽  
Chun-Han Hsu ◽  
Jun-Lun Liao ◽  
...  
Keyword(s):  
Lithium Ion Battery ◽  
Lithium Batteries ◽  
Lithium Battery ◽  
Coulombic Efficiency ◽  
Electronic Devices ◽  
Lithium Ion ◽  
Nylon 66 ◽  
Excellent Electrochemical Performance ◽  
Fabrication And Characterization

In recent years, portable electronic devices have flourished, and the safety of lithium batteries has received increasing attention. In this study, nanofibers were prepared by electrospinning using different ratios of nylon 66/polyacrylonitrile (PAN), and their properties were studied and compared with commercial PP separators. The experimental results show that the addition of PAN in nylon 66/PAN nanofibrous film used as separator of lithium-ion battery can enhance the porosity up to 85%. There is also no significant shrinkage in the shrinkage test, and the thermal dimensional stability is good. When the Li/LiFePO4 lithium battery is prepared by nylon 66/PAN nanofibrous film used as separator, the capacitor can be maintained at 140 mAhg−1 after 20 cycles at 0.1 C, and the coulombic efficiency is still maintained at 99%, which has excellent electrochemical performance.

Research on a New Type of Lithium Battery String Equalization and Management System

2011 ◽  
Vol 383-390 ◽  
pp. 1470-1476
Author(s):  
Hao Wang ◽  
Ding Guo Shao ◽  
Lu Xu
Keyword(s):  
Lithium Batteries ◽  
Management System ◽  
Lithium Battery ◽  
Large Scale ◽  
Control Method ◽  
Balance Control ◽  
Industrial Applications ◽  
Control Technique ◽  
New Type ◽  
Management Functions

Lithium battery has been employed widely in many industrial applications. Parameter mismatches between lithium batteries along a series string is the critical limits of the large-scale applications in high power situation. Maintaining equalization between batteries is the key technique in lithium batteries application. This paper summarizes normal equalization techniques and proposed a new type of lithium Battery Equalization and Management System (BEMS) employing the isolated DC-DC converter structure. The system is integrated both equalization functions and management functions by using distributed 3-level controlled structure and digital control technique. With this control method the flexibility of the balance control strategy and the compatibility for different battery strings are both improved dramatically. The experimental results show optimizing equalization, efficiency and the battery string life span has been extended.

Developments in Rechargeable Mno2Electrodes for Lithium Batteries

1988 ◽  
Vol 135 ◽  
Author(s):  
Michael M Thackeray
Keyword(s):  
Lithium Batteries ◽  
Lithium Battery ◽  
Electrode Materials ◽  
State Of The Art ◽  
Structural Features ◽  
Rechargeable Batteries ◽  
Current State ◽  
Alternative Systems ◽  
Battery Technology ◽  
Made In

AbstractConsiderable efforts are in progress to develop rechargeable batteries as alternative systems to the nickel-cadmium battery. In this regard, several advances have been made in ambient-temperature lithium battery technology, and specifically in the engineering of rechargeable lithium/manganese dioxide cells. This paper reviews the current state of the art in rechargeable Li/MnO2battery technology; particular attention is paid to the structural features of various MnO2electrode materials which influence their electrochemical and cycling behaviour in lithium cells.

Design and Implementation of Electric Vehicle Power Lithium Battery Protection Board

2010 ◽  
Vol 152-153 ◽  
pp. 192-196
Author(s):  
Ju Hua Huang ◽  
Ming Cao ◽  
Hang Guo
Keyword(s):  
Electric Vehicle ◽  
Electric Vehicles ◽  
Lithium Batteries ◽  
Lithium Battery ◽  
Short Circuit ◽  
Battery Life ◽  
Test Results ◽  
Charge Balance ◽  
Good Test ◽  
Li Ion

The performance of power lithium batteries directly affects the performance of electric vehicles. To ensure the safety of power lithium batteries and improve battery life, this paper uses Ricoh R5408 Series Li-ion battery protection IC to design the high-current protection board for electric vehicle, to achieve the power lithium battery group overcharge protection, over-discharge protection, over current, short circuit protection, temperature protection and charge balance protection, and has run on the pure electric vehicles with good test results.

Synthesis and Electrochemical Evaluation of Li, Mn-Rich Cathode Materials for Advanced Lithium Batteries

2016 ◽  
Vol 16 (2) ◽  
pp. 1549-1552
Author(s):  
Sun-Woo Yang ◽  
Min Young Kim ◽  
Ik Hyun Oh ◽  
Moo Sung Lee ◽  
Sun-Il Park ◽  
...  
Keyword(s):  
Lithium Batteries ◽  
Cathode Materials ◽  
Electrochemical Evaluation

Crystal Orientation Tuning of LiFePO4 Nanoplates for High Rate Lithium Battery Cathode Materials

Nano Letters ◽  
2012 ◽  
Vol 12 (11) ◽  
pp. 5632-5636 ◽  
Author(s):  
Li Wang ◽  
Xiangming He ◽  
Wenting Sun ◽  
Jianlong Wang ◽  
Yadong Li ◽  
...  
Keyword(s):  
Cathode Materials ◽  
Crystal Orientation ◽  
Lithium Battery ◽  
High Rate ◽  
Orientation Tuning

scholarly journals Effect of Acid Leaching Pre-Treatment on Gold Extraction from Printed Circuit Boards of Spent Mobile Phones

Materials ◽  
2021 ◽  
Vol 14 (2) ◽  
pp. 362
Author(s):  
Nicolò Maria Ippolito ◽  
Franco Medici ◽  
Loris Pietrelli ◽  
Luigi Piga
Keyword(s):  
Mobile Phones ◽  
Printed Circuit Boards ◽  
Acid Leaching ◽  
Economic Feasibility ◽  
Circuit Boards ◽  
Gold Extraction ◽  
Printed Circuit ◽  
Solid Ratio ◽  
Thiourea Complex ◽  
Pre Treatment

The effect of a preliminary acid leaching for the recovery of gold by thiourea from printed circuit boards (PCBs) of spent mobile phones, was investigated. Preliminary leaching is aimed to recover copper in the leachate that would compete with gold in the successive leaching of the residue with thiourea, thus preventing the formation of the gold-thiourea complex. Two hydrometallurgical routes were tested for the recovery of copper first, and gold after. The first one was based on a two-step leaching that utilizes sulfuric acid and hydrogen peroxide in the preliminary leaching and then thiourea for the recovery of gold in the successive leaching: A copper and gold recovery of 81% and 79% were obtained, respectively. In the second route, nitric acid was used: 100% of copper was recovered in the leachate and 85% of gold in the thiourea successive leaching. The main operative parameters, namely thiourea and ferric sulphate concentrations, leach time, liquid-solid ratio, and temperature were studied according to a factorial plan strategy. A flowsheet of the processes was proposed, and a mass balance of both routes was obtained. Finally, qualitative considerations on the technical and economic feasibility of the different routes were made.

Ni-Rich Li[Ni1−x−YCoxBy]O2 Cathode Materials for Next Lithium Batteries

2021 ◽  
Vol MA2021-01 (2) ◽  
pp. 86-86
Author(s):  
HoonHee Ryu ◽  
Dae Ro Yoon ◽  
Yang-Kook Sun
Keyword(s):  
Lithium Batteries ◽  
Cathode Materials
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