Effect of surface ligands with different terminal group on the optical stability and cytotoxicity of CuInS2/ZnS quantum dots with the crystal structure of sphalerite

2019 ◽  
Vol 6 (12) ◽  
pp. 125018
Author(s):  
Hui Zou ◽  
Yi Wu ◽  
Caixia Yao ◽  
Shiqi Duan ◽  
Zhiyuan Liu ◽  
...  
Author(s):  
Zhiyuan Lin ◽  
Jinhua Li ◽  
Ke Feng ◽  
Yue Wang ◽  
Xueying Chu ◽  
...  

In this paper, CdSe nanorods were prepared via solvothermal synthesis, the effect of surface ligands on the morphology of nanorods was investigated under the premise by tuning the percentage of surface ligands in the precursors. Experimental results show that the absorption and emission spectrum of CdSe nanorod with different aspect ratio varying from 4:1 to 2:1 have a red-shift, and the aspect ratio gradually decreases as the percentage of tetradecylphosphoric acid (TDPA) in the precursor increases. In addition, the CdSe optical stability improves as the percentage of TDPA increases. It is also shown that the crystal surface, which is not covered by TDPA, has an increased surface energy, which results in rapid growth of the crystal face and the formation of a rod-like structure. As a result, the effects of anisotropic absorption and emission, along the long axis properties can find many applications in the fields of optics, optical materials.


2012 ◽  
Vol 7 (1) ◽  
pp. 536 ◽  
Author(s):  
Fernanda O Silva ◽  
Melissa S Carvalho ◽  
Renato Mendonça ◽  
Waldemar AA Macedo ◽  
Karla Balzuweit ◽  
...  

2014 ◽  
Author(s):  
Sergey Dayneko ◽  
Dmitriy Lypenko ◽  
Pavel Linkov ◽  
Alexey Tameev ◽  
Igor Martynov ◽  
...  

Author(s):  
Haibo Zeng ◽  
Dandan Yang ◽  
Zhiheng Xu ◽  
Chunhui Gong ◽  
Xiaoming Li ◽  
...  

One of the main reasons for the stability issue of inorganic perovskite quantum dots (PQDs) is the fragile protection of surface ligands. Here, an armor-like passivation strategy is proposed to...


Nanoscale ◽  
2021 ◽  
Vol 13 (3) ◽  
pp. 1893-1903
Author(s):  
Wei Li Ang ◽  
Jiri Sturala ◽  
Nikolas Antonatos ◽  
Zdeněk Sofer ◽  
Alessandra Bonanni

The surface ligands on chemically modified germanenes have strong influence on the intrinsic fluorescence, on the bio-conjugation ability and the bio-recognition efficiency of the material towards the detection of a specific analyte.


Langmuir ◽  
2021 ◽  
Author(s):  
Kirill A. Svit ◽  
Alexandr A. Zarubanov ◽  
Tatyana A. Duda ◽  
Svetlana V. Trubina ◽  
Valentina V. Zvereva ◽  
...  

Crystals ◽  
2021 ◽  
Vol 11 (4) ◽  
pp. 419
Author(s):  
Saradh Prasad ◽  
Mamduh J. Aljaafreh ◽  
Mohamad S. AlSalhi ◽  
Abeer Alshammari

The notable photophysical characteristics of perovskite quantum dots (PQDs) (CsPbBr3) are suitable for optoelectronic devices. However, the performance of PQDs is unstable because of their surface defects. One way to address the instability is to passivate PQDs using different organic (polymers, oligomers, and dendrimers) or inorganic (ZnS, PbS) materials. In this study, we performed steady-state spectroscopic investigations to measure the photoluminescence (PL), absorption (A), transmission (T), and reflectance (R) of perovskite quantum dots (CsPbBr3) and ethylene vinyl acetate/terpene phenol (1%) (EVA-TPR (1%), or EVA) copolymer/perovskite composites in thin films with a thickness of 352 ± 5 nm. EVA is highly transparent because of its large band gap; furthermore, it is inexpensive and easy to process. However, the compatibility between PQDs and EVA should be established; therefore, a series of analyses was performed to compute parameters, such as the band gap, the coefficients of absorbance and extinction, the index of refractivity, and the dielectric constant (real and imaginary parts), from the data obtained from the above investigation. Finally, the optical conductivities of the films were studied. All these analyses showed that the EVA/PQDs were more efficient and stable both physically and optically. Hence, EVA/PQDs could become copolymer/perovskite active materials suitable for optoelectronic devices, such as solar cells and perovskite/polymer light-emitting diodes (PPLEDs).


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