scholarly journals Study on the leaching toxicity and performance of manganese slag-based cementitious materials

2021 ◽  
Author(s):  
Shuhui Zhang ◽  
Xiaodong Li ◽  
Wei Zhang ◽  
Fei Fan ◽  
Yingzi Wang
Keyword(s):  
Fly Ash ◽  
Surface Water ◽  
Resource Utilization ◽  
Rapid Development ◽  
Soil Surface ◽  
Cementitious Materials ◽  
Domestic Water ◽  
Electrolytic Manganese ◽  
Stabilization Effect ◽  
Manganese Slag

Abstract With the rapid development of electrolytic manganese industry, the environmental problems caused by the storage of electrolytic manganese slag are particularly prominent. It not only occupies land resources, but also easily causes heavy metal pollution in soil, surface water and groundwater. Therefore, it is necessary to treat electrolytic manganese slag safely and effectively. The paper mainly studies the solidification / stabilization of electrolytic manganese slag and its environmental safety for road filling, in order to open up a new way of harmless and resource utilization of electrolytic manganese slag. In this paper, lime and fly ash were used as stabilizers and cement was used as curing agent to stabilize manganese slag, and the stabilization effect of Mn and Pb in manganese slag was studied. The stabilization effect of manganese (Mn) and lead (Pb) in manganese slag was studied. The results show that the dosage of stabilizer quicklime is 2.5%, fly ash is 3%, and the dosage of solidifying agent cement is 12%, the solidification/stabilization effect is the best compared with other ratios, then the leaching concentrations of Mn and Pb meets the requirements of China's surface water environmental quality standards for category III water sources, which can be used as domestic water after treatment. Under the optimal ratio of stabilization effect, the compressive strength and slump are 13.8MPa and 50mm, respectively. The research results of the paper can provide a new way for the harmless treatment of manganese slag and the resource utilization of new materials.

scholarly journals Effect of Electrolytic Manganese Residue in Fly Ash-Based Cementitious Material: Hydration Behavior and Microstructure

Materials ◽  
2021 ◽  
Vol 14 (22) ◽  
pp. 7047
Author(s):  
Yaguang Wang ◽  
Na Zhang ◽  
Yongyu Ren ◽  
Yingtang Xu ◽  
Xiaoming Liu
Keyword(s):  
Fly Ash ◽  
Pore Structure ◽  
Mineralogical Composition ◽  
Cementitious Materials ◽  
Cementitious Material ◽  
Hydration Reaction ◽  
29Si Nmr ◽  
Polymerization Degree ◽  
Electrolytic Manganese ◽  
Electrolytic Manganese Residue

Electrolytic manganese residue (EMR) is a solid waste with a main mineralogical composition of gypsum. It is generated in the production of metal manganese by the electrolysis process. In this research, EMR, fly ash, and clinker were blended to make fly ash-based cementitious material (FAC) to investigate the effect of EMR on strength properties, hydration behavior, microstructure, and environmental performance of FAC. XRD, TG, and SEM studied the hydration behavior of FAC. The pore structure and [SiO4] polymerization degree were characterized by MIP and 29Si NMR, respectively. The experimental results indicate that FAC shows excellent mechanical properties when the EMR dosage is 10%. Moderate content of sulfate provided by EMR can promote hydration reaction of FAC, and it shows a denser pore structure and higher [SiO4] polymerization degree in this case. Heavy metal ions derived from EMR can be adsorbed in the hydration products of FAC to obtain better environmental properties. This paper presents an AFt covering model for the case of excessive EMR in FAC, and it importantly provides theoretical support for the recycling of EMR in cementitious materials.

Effect of ground granulated blast funrnace slag and fly ash on strength, permeability, and under-water abrasion of fine-grained concrete

2020 ◽  
Vol 71 (7) ◽  
pp. 775-788
Author(s):  
Quyet Truong Van ◽  
Sang Nguyen Thanh
Keyword(s):  
Fly Ash ◽  
Concrete Strength ◽  
Cementitious Materials ◽  
Supplementary Cementitious Materials ◽  
Chloride Permeability ◽  
Cement Replacement ◽  
Fine Grained ◽  
Granulated Blast Furnace Slag ◽  
Compressive Strength Test ◽  
Economic Ground

The utilisation of supplementary cementitious materials (SCMs) is widespread in the concrete industry because of the performance benefits and economic. Ground granulated blast furnace slag (GGBFS) and fly ash (FA) have been used as the SCMs in concrete for reducing the weight of cement and improving durability properties. In this study, GGBFS at different cement replacement ratios of 0%, 20%, 40% and 60% by weight were used in fine-grained concrete. The ternary binders containing GGBFS and FA at cement replacement ratio of 60% by weight have also evaluated. Flexural and compressive strength test, rapid chloride permeability test and under-water abrasion test were performed. Experimental results show that the increase in concrete strength with GGBFS contents from 20% to 40% but at a higher period of maturity (56 days and more). The chloride permeability the under-water abrasion reduced with the increasing cement replacement by GGBFS or a combination of GGBFS and FA

scholarly journals Coal Fly Ash and Polyacrylamide Influence Transport and Redistribution of Soil Nitrogen in a Sandy Sloping Land

Agriculture ◽  
2021 ◽  
Vol 11 (1) ◽  
pp. 47
Author(s):  
Kai Yang ◽  
Zejun Tang ◽  
Jianzhang Feng
Keyword(s):  
Fly Ash ◽  
Sandy Soil ◽  
Coal Fly Ash ◽  
Soil Layer ◽  
Nutrient Retention ◽  
Soil Surface ◽  
Rainfall Event ◽  
N Losses ◽  
N Concentration ◽  
Application Rates

Sandy soils are prone to nutrient losses, and consequently do not have as much as agricultural productivity as other soils. In this study, coal fly ash (CFA) and anionic polyacrylamide (PAM) granules were used as a sandy soil amendment. The two additives were incorporated to the sandy soil layer (depth of 0.2 m, slope gradient of 10°) at three CFA dosages and two PAM dosages. Urea was applied uniformly onto the low-nitrogen (N) soil surface prior to the simulated rainfall experiment (rainfall intensity of 1.5 mm/min). The results showed that compared with no addition of CFA and PAM, the addition of CFA and/or PAM caused some increases in the cumulative NO3−-N and NH4+-N losses with surface runoff; when the rainfall event ended, 15% CFA alone treatment and 0.01–0.02% PAM alone treatment resulted in small but significant increases in the cumulative runoff-associated NO3−-N concentration (p < 0.05), meanwhile 10% CFA + 0.01% PAM treatment and 15% CFA alone treatment resulted in nonsignificant small increases in the cumulative runoff-associated NH4+-N concentration (p > 0.05). After the rainfall event, both CFA and PAM alone treatments increased the concentrations of NO3−-N and NH4+-N retained in the sandy soil layer compared with the unamended soil. As the CFA and PAM co-application rates increased, the additive effect of CFA and PAM on improving the nutrient retention of sandy soil increased.

scholarly journals Effect of Digestate and Straw Combined Application on Maintaining Rice Production and Paddy Environment

2021 ◽  
Vol 18 (11) ◽  
pp. 5714
Author(s):  
Xue Hu ◽  
Hongyi Liu ◽  
Chengyu Xu ◽  
Xiaomin Huang ◽  
Min Jiang ◽  
...  
Keyword(s):  
Organic Matter ◽  
Surface Water ◽  
Soil Organic Matter ◽  
Paddy Soil ◽  
Rice Yield ◽  
Soil Surface ◽  
Rice Production ◽  
Straw Decomposition ◽  
Rice Grains ◽  
Combined Application

Few studies have focused on the combined application of digestate and straw and its feasibility in rice production. Therefore, we conducted a two-year field experiment, including six treatments: without nutrients and straw (Control), digestate (D), digestate + fertilizer (DF), digestate + straw (DS), digestate + fertilizer + straw (DFS) and conventional fertilizer + straw (CS), to clarify the responses of rice growth and paddy soil nutrients to different straw and fertilizer combinations. Our results showed that digestate and straw combined application (i.e., treatment DFS) increased rice yield by 2.71 t ha−1 compared with the Control, and digestate combined with straw addition could distribute more nitrogen (N) to rice grains. Our results also showed that the straw decomposition rate at 0 cm depth under DS was 5% to 102% higher than that under CS. Activities of catalase, urease, sucrase and phosphatase at maturity under DS were all higher than that under both Control and CS. In addition, soil organic matter (SOM) and total nitrogen (TN) under DS and DFS were 20~26% and 11~12% higher than that under B and DF respectively, suggesting straw addition could benefit paddy soil quality. Moreover, coupling straw and digestate would contribute to decrease the N content in soil surface water. Overall, our results demonstrated that digestate and straw combined application could maintain rice production and have potential positive paddy environmental effects.

scholarly journals Effect of fly ash on the self-healing capability of cementitious materials with crystalline admixture under different conditions

AIP Advances ◽  
2021 ◽  
Vol 11 (7) ◽  
pp. 075018
Author(s):  
Xi Wang ◽  
Hao Qiao ◽  
Ziwei Zhang ◽  
Shiying Tang ◽  
Shengjun Liu ◽  
...  
Keyword(s):  
Fly Ash ◽  
Cementitious Materials ◽  
The Self ◽  
Self Healing

scholarly journals New Approach for the Determination of Radiological Parameters on Hardened Cement Pastes with Coal Fly Ash

Materials ◽  
2021 ◽  
Vol 14 (3) ◽  
pp. 475
Author(s):  
Ana María Moreno de los Reyes ◽  
José Antonio Suárez-Navarro ◽  
Maria del Mar Alonso ◽  
Catalina Gascó ◽  
Isabel Sobrados ◽  
...  
Keyword(s):  
Fly Ash ◽  
Activity Concentration ◽  
Gamma Ray ◽  
Coal Fly Ash ◽  
Cementitious Materials ◽  
New Method ◽  
Supplementary Cementitious Materials ◽  
Hardened Cement ◽  
Cement Pastes ◽  
Activity Concentrations

Supplementary cementitious materials (SCMs) in industrial waste and by-products are routinely used to mitigate the adverse environmental effects of, and lower the energy consumption associated with, ordinary Portland cement (OPC) manufacture. Many such SCMs, such as type F coal fly ash (FA), are naturally occurring radioactive materials (NORMs). 226Ra, 232Th and 40K radionuclide activity concentration, information needed to determine what is known as the gamma-ray activity concentration index (ACI), is normally collected from ground cement samples. The present study aims to validate a new method for calculating the ACI from measurements made on unground 5 cm cubic specimens. Mechanical, mineralogical and radiological characterisation of 28-day OPC + FA pastes (bearing up to 30 wt % FA) were characterised to determine their mechanical, mineralogical and radiological properties. The activity concentrations found for 226Ra, 212Pb, 232Th and 40K in hardened, intact 5 cm cubic specimens were also statistically equal to the theoretically calculated values and to the same materials when ground to a powder. These findings consequently validated the new method. The possibility of determining the activity concentrations needed to establish the ACI for cement-based materials on unground samples introduces a new field of radiological research on actual cement, mortar and concrete materials.

Effects of compaction on soil surface water repellency

2007 ◽  
Vol 23 (3) ◽  
pp. 238-244 ◽  
Author(s):  
R. Bryant ◽  
S. H. Doerr ◽  
G. Hunt ◽  
S. Conan
Keyword(s):  
Surface Water ◽  
Soil Surface ◽  
Water Repellency

Domestic water buffaloes: Access to surface water, disease prevalence and associated economic losses

2018 ◽  
Vol 154 ◽  
pp. 102-112 ◽  
Author(s):  
Ehsan Elahi ◽  
Muhammad Abid ◽  
Huiming Zhang ◽  
Weijun Cui ◽  
Shabeh Ul Hasson
Keyword(s):  
Surface Water ◽  
Disease Prevalence ◽  
Economic Losses ◽  
Domestic Water ◽  
Water Buffaloes

Modeling of Alteration Behavior on Blended Cementitious Materials

2011 ◽  
Author(s):  
Hitoshi Owada ◽  
Tomoko Ishii ◽  
Mayumi Takazawa ◽  
Hiroyasu Kato ◽  
Hiroyuki Sakamoto ◽  
...  
Keyword(s):  
Blast Furnace ◽  
Fly Ash ◽  
Chemical Composition ◽  
Mineral Composition ◽  
Blast Furnace Slag ◽  
Fine Powder ◽  
Cementitious Materials ◽  
Leaching Tests ◽  
Measured Concentration ◽  
Furnace Slag

A “realistic alteration model” is needed for various cementitious materials. Hypothetical settings of mineral composition calculated based on the chemical composition of cement, such as Atkins’s model, have been used to estimate the alteration of cementitious material. However, model estimates for the concentration of certain elements such as Al and S in leachate have been different from experimental values. In a previous study, we created settings for a mineralogical alteration model by taking the initial chemical composition of cementitious materials from analysis results in experiments and applying their ratios to certain hydrated cement minerals, then added settings for secondary generated minerals in order to account for Ca leaching. This study of alteration estimates for ordinary portland cement (OPC) in groundwater showed that the change in Al and S concentrations in simulated leachate approached values for actual leachate[1]. In the present study, we develop an appropriate mineral alteration model for blended cementitious materials and conduct batch-type leaching experiments that use crushed samples of blast furnace slag cement (BFSC), silica cement (SC), and fly ash cement (FAC). The cement blends in these experiments used OPC blended with blast furnace slag of 70 wt.%, silica cement consisting of an amorphous silica fine powder of 20 wt.%, and fly ash of 30 wt.%. De-ionized water was used as the leaching solution. The solid-liquid ratios in the leaching tests were varied in order to simulate the alteration process of cement hydrates. The compositions of leachate and minerals obtained from leaching tests were compared with those obtained from models using hypothetical settings of mineral composition. We also consider an alteration model that corresponds to the diversity of these materials. As a result of applying the conventional OPC model to blended cementitious materials, the estimated Al concentration in the aqueous solution was significantly different from the measured concentration. We therefore propose an improved model that takes better account of Al behavior by using a more reliable initial mineral model for Al concentration in the solution.

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