The metamorphism of the Dalradian rocks of western Ireland and its relation to tectonic setting

1987 ◽  
Vol 321 (1557) ◽  
pp. 243-270 ◽  
Keyword(s):  
Thermal Evolution ◽  
Tectonic Setting ◽  
Regional Scale ◽  
Thermal Relaxation ◽  
The South ◽  
Volcanic Arc ◽  
High Pressure Metamorphism ◽  
Almost Everywhere ◽  
Western Ireland ◽  
Single Locality

The metamorphic evolution of Dalradian rocks exposed in the NW Mayo, Ox Mountains and Connemara inliers of western Ireland is reviewed, and new data and revised calculations are presented. There is evidence at a single locality for an early episode of moderately high-pressure metamorphism with the production of crossite—epidote schists. Subsequent Barrovian-style metamorphism overprinted this almost everywhere in NW Mayo and resulted in further heating to produce chlorite—biotite and garnet zones with the garnet isograd near 400—450 °C, and a staurolite—kyanite zone for which conditions were P = 8 ± 2 kbar (1 bar = 10 5 Pa) and T = 620 ± 30 °C. In Connemara, rare staurolite—kyanite schists are now inferred to have formed at lower pressures than those in the Barrovian zones because ilmenite is stable rather than rutile. The metamorphic zones now mapped result from regional scale heating by synorogenic intrusions exposed to the south, and took place at pressures of 4-6 kbar. There is, however, strong evidence to suggest progressive uplift during this heating phase, especially in the south. It is concluded that the thermal evolution of complex areas such as these can usefully be broken down into a series of modules, each corresponding to metamorphism in a distinct tectonic setting. The sequence identified in the Irish Dalradian is: (i) recrystallization during burial in a low heat flow setting; (ii) thermal relaxation and possibly uplift; and, in Connemara only, (iii) further heating and uplift, probably in the roots of a volcanic arc.

scholarly journals Volcanic activity and gas emissions along the South Sandwich Arc

2020 ◽  
Vol 83 (1) ◽  
Author(s):  
Emma J. Liu ◽  
Kieran Wood ◽  
Alessandro Aiuppa ◽  
Gaetano Giudice ◽  
Marcello Bitetto ◽  
...  
Keyword(s):  
Carbon Isotope ◽  
Volcanic Activity ◽  
Emission Rate ◽  
Tectonic Setting ◽  
Hydrothermal Systems ◽  
Molar Ratio ◽  
The South ◽  
Gas Emissions ◽  
Volcanic Arc

AbstractThe South Sandwich Volcanic Arc is one of the most remote and enigmatic arcs on Earth. Sporadic observations from rare cloud-free satellite images—and even rarer in situ reports—provide glimpses into a dynamic arc system characterised by persistent gas emissions and frequent eruptive activity. Our understanding of the state of volcanic activity along this arc is incomplete compared to arcs globally. To fill this gap, we present here detailed geological and volcanological observations made during an expedition to the South Sandwich Islands in January 2020. We report the first in situ measurements of gas chemistry, emission rate and carbon isotope composition from along the arc. We show that Mt. Michael on Saunders Island is a persistent source of gas emissions, releasing 145 ± 59 t day−1 SO2 in a plume characterised by a CO2/SO2 molar ratio of 1.8 ± 0.2. Combining this CO2/SO2 ratio with our independent SO2 emission rate measured near simultaneously, we derive a CO2 flux of 179 ± 76 t day−1. Outgassing from low temperature (90–100 °C) fumaroles is pervasive at the active centres of Candlemas and Bellingshausen, with measured gas compositions indicative of interaction between magmatic fluids and hydrothermal systems. Carbon isotope measurements of dilute plume and fumarole gases from along the arc indicate a magmatic δ13C of − 4.5 ± 2.0‰. Interpreted most simply, this result suggests a carbon source dominated by mantle-derived carbon. However, based on a carbon mass balance from sediment core ODP 701, we show that mixing between depleted upper mantle and a subduction component composed of sediment and altered crust is also permissible. We conclude that, although remote, the South Sandwich Volcanic Arc is an ideal tectonic setting in which to explore geochemical processes in a young, developing arc.

scholarly journals Influence of the North Atlantic oscillation on the atmospheric levels of benzo[a]pyrene over Europe

2021 ◽  
Author(s):  
Pedro Jiménez-Guerrero ◽  
Nuno Ratola
Keyword(s):  
Spatial Pattern ◽  
North Atlantic Oscillation ◽  
North Atlantic ◽  
Transport Model ◽  
Regional Scale ◽  
The South ◽  
Climatic Fluctuations ◽  
The North ◽  
The North Atlantic ◽  
The North Atlantic Oscillation

AbstractThe atmospheric concentration of persistent organic pollutants (and of polycyclic aromatic hydrocarbons, PAHs, in particular) is closely related to climate change and climatic fluctuations, which are likely to influence contaminant’s transport pathways and transfer processes. Predicting how climate variability alters PAHs concentrations in the atmosphere still poses an exceptional challenge. In this sense, the main objective of this contribution is to assess the relationship between the North Atlantic Oscillation (NAO) index and the mean concentration of benzo[a]pyrene (BaP, the most studied PAH congener) in a domain covering Europe, with an emphasis on the effect of regional-scale processes. A numerical simulation for a present climate period of 30 years was performed using a regional chemistry transport model with a 25 km spatial resolution (horizontal), higher than those commonly applied. The results show an important seasonal behaviour, with a remarkable spatial pattern of difference between the north and the south of the domain. In winter, higher BaP ground levels are found during the NAO+ phase for the Mediterranean basin, while the spatial pattern of this feature (higher BaP levels during NAO+ phases) moves northwards in summer. These results show deviations up to and sometimes over 100% in the BaP mean concentrations, but statistically significant signals (p<0.1) of lower changes (20–40% variations in the signal) are found for the north of the domain in winter and for the south in summer.

Petrogenesis and tectonic significance of the middle Neoproterozoic highly fractionated A-type granite in the South Qinling block

2021 ◽  
pp. 1-20
Author(s):  
Xiao-Fei Qiu ◽  
Qiong Xu ◽  
Tuo Jiang ◽  
Shan-Song Lu ◽  
Long Zhao
Keyword(s):  
Tectonic Setting ◽  
Eastern China ◽  
Continental Rift ◽  
The South ◽  
Yangtze Craton ◽  
Dabie Orogen ◽  
Northern Margin ◽  
South Qinling ◽  
Type Granite ◽  
High Alkali

Abstract The South Qinling block, a segment of the Yangtze craton involved in the Qinling–Dabie orogen, is critical for understanding the tectonic evolution of eastern China. However, the tectonic setting of the South Qinling block and the northern margin of the Yangtze block during middle Neoproterozoic time has long been the subject of debate, with two distinctly different models (continental rift or volcanic arc) proposed. Here, a comprehensive study of zircon U–Pb geochronology and geochemistry has been carried out on the Chengwan granitic pluton from the Suizao terrane in the South Qinling block. The granites are monzogranite and syenogranite in lithology, and are mainly composed of potash feldspar, quartz, plagioclase and biotite. This suite has long been regarded as a Palaeozoic magmatic pluton, but zircon U–Pb ages of 809 ± 9 Ma and 816 ± 4 Ma are obtained in this study. The granites are metaluminous to strongly peraluminous with high alkali contents, and exhibit highly fractionated features, including high SiO2, low Zr/Hf ratios, rare earth element tetrad effects and enrichment of K and Rb. They show Hf–Nd isotopic decoupling, which may be genetically related to their petrogenetic process. Based on the geochemical features and the positive εHf(t) values of the zircons, it is indicated that the granites may have been derived from partial melting of juvenile tonalitic rocks by biotite breakdown under fluid-absent conditions. The Chengwan granite geochemically belongs to the A2-subtype granites, suggesting that it might have formed in a post-orogenic tectonic setting. The highly fractionated A-type granite in this study may represent extensional collapse shortly after the collisional events in the South Qinling block, and thus indicate a tectonic regime switch, from compression to extension, as early as middle Neoproterozoic time. Integrating our new data with documented magmatic, metamorphic and sedimentary events during middle Neoproterozoic time in the region may support a continental rift model, and argues against arc models.

Heavy minerals solve structural and stratigraphic problems in Ordovician strata of the western Irish Caledonides

2003 ◽  
Vol 140 (1) ◽  
pp. 25-30 ◽  
Author(s):  
MARIA A. MANGE ◽  
JOHN F. DEWEY ◽  
DAVID T. WRIGHT
Keyword(s):  
Island Arc ◽  
Heavy Minerals ◽  
Metamorphic Complex ◽  
The South ◽  
Standard Sequence ◽  
Western Ireland ◽  
Complex Parts ◽  
Wide Horizon

Heavy minerals in Ordovician successions in western Ireland record, in the Upper Arenig Sheeffry Formation, the erosion of an ophiolite/island arc complex. The appearance of staurolite and garnet at a basin-wide horizon in the Lower Llanvirn Upper Derrylea Formation signals the unroofing of the Dalradian metamorphic complex. Parts of the Ordovician sequence on Inishturk and in two small inliers are correlated with the standard sequence with unexpected results. The garnet-, sillimanite-, and staurolite-bearing Letter Formation correlates with the Upper Derrylea Formation and, on Inishturk, heavy minerals in south-younging turbidites reveal a sinistral ramp zone, that places the Sheeffry Formation structurally above and to the south of the younger Derrylea Formation.

Age, evolution and tectonic history of the Highland Border Complex, Scotland

1984 ◽  
Vol 75 (2) ◽  
pp. 113-133 ◽  
Author(s):  
Gordon B. Curry ◽  
B. J. Bluck ◽  
C. J. Burton ◽  
J. K. Ingham ◽  
David J. Siveter ◽  
...  
Keyword(s):  
Regional Scale ◽  
Plate Boundary ◽  
North American Plate ◽  
Tectonic History ◽  
Lower Ordovician ◽  
Northwestern Margin ◽  
Comprehensive Survey ◽  
History Of ◽  
Early Palaeozoic ◽  
Western Ireland

I. ABSTRACT: Research interest in the Highland Border Complex has been pursued sporadically during the past 150 years. The results and conclusions have emphasised the problems of dealing with a lithologically disparate association which crops out in isolated, fault-bounded slivers along the line of the Highland Boundary fault. For much of the present century, the debate has centred on whether the rocks of the complex have affinities with the Dalradian Supergroup to the N, or are a discrete group. Recent fossil discoveries in a wide variety of Highland Border rocks have confirmed that many are of Ordovician age, and hence cannot have been involved in at least the early Grampian deformational events (now accurately dated as pre-Ordovician) which affect the Dalradian Supergroup. Such palaeontological discoveries form the basis for a viable biostratigraphical synthesis. On a regional scale, it is apparent that the geological history of the Highland Border rocks must be viewed in the context of plate boundary tectonism along the entire northwestern margin of Iapetus during Palaeozoic times.II. ABSTRACT: Silicified articulate brachiopods from the Lower Ordovician (Arenig) Dounans Limestone are extremely rare but the stratigraphically diagnostic generaArchaeorthisSchuchert and Cooper, andOrthidiumHall and Clarke, have been identified. In addition, three specimens with characteristic syntrophiid morphology have been recovered. Inarticulate brachiopods are known from Stonehaven and Bofrishlie Burn near Aberfoyle, and have also been previously recorded from Arran.III. ABSTRACT: Micropalaeontological investigation of the Highland Border Complex has produced a range of microfossils including chitinozoans, coleolids, calcispheres and other more enigmatic objects. The stratigraphical ranges of the species lie almost entirely within the Ordovician and reveal a scatter of ages for different lithologies from the Arenig through to the Caradoc or Ashgill, with a pronounced erosional break between the Llandeilo and the Caradoc.IV. ABSTRACT: A Lower Ordovician (Arenig Series) silicified ostracode fauna from the Highland Border Dounans Limestone at Lime Craig Quarry, Aberfoyle, Central Scotland, represents the earliest record of this group of Crustacea from the British part of the early Palaeozoic ‘North American’ plate.V. ABSTRACT: Palaeontological age determinations for a variety of Highland Border rocks are presented. The data are based on the results of recent prospecting which has demonstrated that macro- and microfossils are present in a much greater range of Highland Border lithologies than previously realised. Data from other studies are also incorporated, as are modern taxonomie re-assessments of older palaeontological discoveries, in a comprehensive survey of Highland Border biostratigraphy. These accumulated data demonstrate that all fossiliferous Highland Border rocks so far discovered are of Ordovician age, with the exception of the Lower Cambrian Leny Limestone.VI. ABSTRACT: The Highland Border Complex consists of at least four rock assemblages: a serpentinite and possibly other ophiolitic rocks of Early or pre-Arenig age; a sequence of limestones and conglomerates of Early Arenig age; a succession of dark shales, cherts, quartz wackes, basic lavas and associated volcanogenic sediments of Llanvirn and ? earlier age; and an assemblage of limestones, breccias, conglomerates and arenites with subordinate shales of Caradoc or Ashgill age. At least three assemblages are divided by unconformities and in theirmost general aspect have similarities with coeval rocks in western Ireland.The Highland Border Complex probably formed N of the Midland Valley arc massif in a marginal sea comparable with the Sunda shelf adjacent to Sumatra–Java. Strike-slip and thrust emplacement of the whole Complex in at least four episodes followed the probable generation of all or part of its rocks by pull-apart mechanisms.

Mesozoic Tectonic Setting of SE Sundaland After Magmatism and Suture Evidences in JS-1 Ridge Area

2021 ◽  
Keyword(s):  
Early Cretaceous ◽  
Late Cretaceous ◽  
Tectonic Setting ◽  
Plate Boundary ◽  
Early Jurassic ◽  
The South ◽  
Magmatic Arc ◽  
Plate Convergence ◽  
Ridge Area ◽  
Cretaceous Subduction

Mesozoic plate convergence in SE Sundaland has been a source of debate for decades. A determination of plate convergence boundaries and timing have been explained in many publications, but not all boundaries were associated with magmatism. Through integration of both plate configurations and magmatic deposits, the basement can be accurately characterized over time and areal extents. This paper will discuss Cretaceous subductions and magmatic arc trends in SE Sundaland area with additional evidence found in JS-1 Ridge. At least three subduction trends are captured during the Mesozoic in the study area: 1) Early Jurassic – Early Cretaceous trend of Meratus, 2) Early Cretaceous trend of Bantimala and 3) Late Cretaceous trend in the southernmost study area. The Early Jurassic – Early Cretaceous subduction occurred along the South and East boundary of Sundaland (SW Borneo terrane) and passes through the Meratus area. The Early Cretaceous subduction occurred along South and East boundary of Sundaland (SW Borneo and Paternoster terranes) and pass through the Bantimala area. The Late Cretaceous subduction occurred along South and East boundary of Sundaland (SW Borneo, Paternoster and SE Java – South Sulawesi terranes), but is slightly shifted to the South approaching the Oligocene – Recent subduction zone. Magmatic arc trends can also be generally grouped into three periods, with each period corresponds to the subduction processes at the time. The first magmatic arc (Early Jurassic – Early Cretaceous) is present in core of SW Borneo terrane and partly produces the Schwaner Magmatism. The second Cretaceous magmatic arc (Early Cretaceous) trend is present in the SW Borneo terrane but is slightly shifted southeastward It is responsible for magmatism in North Java offshore, northern JS-1 Ridge and Meratus areas. The third magmatic arc trend is formed by Late Cretaceous volcanic rocks in Luk Ulo, the southern JS-1 Ridge and the eastern Makassar Strait areas. These all occur during the same time within the Cretaceous magmatic arc. Though a mélange rock sample has not been found in JS-1 Ridge area, there is evidence of an accretionary prism in the area as evidenced by the geometry observed on a new 3D seismic dataset. Based on the structural trend of Meratus (NNE-SSW) coupled with the regional plate boundary understanding, this suggests that both Meratus & JS-1 Ridge are part of the same suture zone between SW Borneo and Paternoster terranes. The gradual age transition observed in the JS-1 Ridge area suggests a southward shift of the magmatic arc during Early Cretaceous to Late Cretaceous times.

Trace element and Pb isotopic constraints on the provenance of the Rosroe and Derryveeny formations, South Mayo, Ireland

2002 ◽  
Vol 93 (2) ◽  
pp. 101-110 ◽  
Author(s):  
Peter D. Clift ◽  
Amy E. Draut ◽  
Robyn Hannigan ◽  
Graham Layne ◽  
Jerzy Blusztajn
Keyword(s):  
Trace Element ◽  
Limited Range ◽  
Ion Microprobe ◽  
Pb Isotope ◽  
Metamorphic Belt ◽  
Volcanic Arc ◽  
Trace Element Chemistry ◽  
Lower Ordovician ◽  
Western Ireland ◽  
Laurentian Margin

The Rosroe Formation comprises a series of Lower Ordovician (Llanvirn) conglomerates and sandstones, that lies on the southern limb of the South Mayo Trough, within the Iapetus Suture Zone of western Ireland. Trace element chemistry of granite boulders within the formation indicates a continental, rather than a volcanic arc character that can be correlated to latest Precambrian granites within the Dalradian Metamorphic Block, part of the deformed Laurentian margin. A minority of the clasts may correlate with syn-collisional granites, similar to, but older than, the Oughterard Granite of Connemara. Pb isotope compositions of K-feldspar grains within the sandstones, measured by both ion microprobe and conventional mass spectrometry, show a clear Laurentian affinity, albeit with greater source variability in the sand grains compared to a limited range in the proximal boulders. Palaeo-current indicators demonstrate dominant derivation from the NE, with a significant axial E–W flow. We propose that the Rosroe Formation records unroofing of a rapidly exhuming Dalradian metamorphic belt in North Mayo, following extensional collapse of the Grampian Orogen starting at ˜468 Ma, with minor input from a southerly arc source. The lack of metamorphic input from the S until deposition of the Derryeeny Conglomerate argues that the Connemara terrane was not positioned S of South Mayo Trough through strike-slip faulting until after the end of Rosroe sedimentation (460–443 Ma).

scholarly journals Inferring <sup>222</sup>Rn soil fluxes from ambient <sup>222</sup>Rn activity and eddy covariance measurements of CO<sub>2</sub>

2016 ◽  
Vol 9 (11) ◽  
pp. 5523-5533 ◽  
Author(s):  
Sander van der Laan ◽  
Swagath Manohar ◽  
Alex Vermeulen ◽  
Fred Bosveld ◽  
Harro Meijer ◽  
...  
Keyword(s):  
Eddy Covariance ◽  
Activity Concentration ◽  
Regional Scale ◽  
Surface Flux ◽  
Surface Fluxes ◽  
Spatial And Temporal Variability ◽  
Single Pair ◽  
The South ◽  
Practical Applications ◽  
Soil Flux

Abstract. We present a new methodology, which we call Single Pair of Observations Technique with Eddy Covariance (SPOT-EC), to estimate regional-scale surface fluxes of 222Rn from tower-based observations of 222Rn activity concentration, CO2 mole fractions and direct CO2 flux measurements from eddy covariance. For specific events, the regional (222Rn) surface flux is calculated from short-term changes in ambient (222Rn) activity concentration scaled by the ratio of the mean CO2 surface flux for the specific event to the change in its observed mole fraction. The resulting 222Rn surface emissions are integrated in time (between the moment of observation and the last prior background levels) and space (i.e. over the footprint of the observations). The measurement uncertainty obtained is about ±15 % for diurnal events and about ±10 % for longer-term (e.g. seasonal or annual) means. The method does not provide continuous observations, but reliable daily averages can be obtained. We applied our method to in situ observations from two sites in the Netherlands: Cabauw station (CBW) and Lutjewad station (LUT). For LUT, which is an intensive agricultural site, we estimated a mean 222Rn surface flux of (0.29 ± 0.02) atoms cm−2 s−1 with values  > 0.5 atoms cm−2 s−1 to the south and south-east. For CBW we estimated a mean 222Rn surface flux of (0.63 ± 0.04) atoms cm−2 s−1. The highest values were observed to the south-west, where the soil type is mainly river clay. For both stations good agreement was found between our results and those from measurements with soil chambers and two recently published 222Rn soil flux maps for Europe. At both sites, large spatial and temporal variability of 222Rn surface fluxes were observed which would be impractical to measure with a soil chamber. SPOT-EC, therefore, offers an important new tool for estimating regional-scale 222Rn surface fluxes. Practical applications furthermore include calibration of process-based 222Rn soil flux models, validation of atmospheric transport models and performing regional-scale inversions, e.g. of greenhouse gases via the SPOT 222Rn-tracer method.

scholarly journals Heavy minerals in the Wajid Sandstone from Abha-Khamis Mushayt area, southwestern Saudi Arabia: implications on provenance and regional tectonic setting

GeoArabia ◽  
2004 ◽  
Vol 9 (4) ◽  
pp. 77-102 ◽  
Author(s):  
Mahbub Hussain ◽  
Lameed O. Babalola ◽  
Mustafa M. Hariri
Keyword(s):  
Saudi Arabia ◽  
Tectonic Setting ◽  
Principal Component ◽  
Heavy Mineral ◽  
Heavy Minerals ◽  
Coarse Grained ◽  
Distribution Data ◽  
The South ◽  
Quartz Content ◽  
The North

ABSTRACT The Wajid Sandstone (Ordovician-Permian) as exposed along the road-cut sections of the Abha and Khamis Mushayt areas in southwestern Saudi Arabia, is a mediun to coarse-grained, mineralogically mature quartz arenite with an average quartz content of over 95%. Monocrystalline quartz is the dominant framework grain followed by polycrystalline quartz, feldspar and micas. The non-opaque heavy mineral assemblage of the sandstone is dominated by zircon, tourmaline and rutile (ZTR). Additional heavy minerals, constituting a very minor fraction of the heavies, include epidote, hornblende, and kyanite. Statistical analysis showed significant correlations between zircon, tourmaline, rutile, epidote and hornblende. Principal component R-mode varimax factor analysis of the heavy mineral distribution data shows two strong associations: (1) tourmaline, zircon, rutile, and (2) epidote and hornblende suggesting several likely provenances including igneous, recycled sedimentary and metamorphic rocks. However, an abundance of the ZTR minerals favors a recycled sedimentary source over other possibilities. Mineralogical maturity coupled with characteristic heavy mineral associations, consistent north-directed paleoflow evidence, and the tectonic evolutionary history of the region indicate a provenance south of the study area. The most likely provenances of the lower part (Dibsiyah and Khusayyan members) of the Wajid Sandstone are the Neoproterozoic Afif, Abas, Al-Bayda, Al-Mahfid, and Al-Mukalla terranes, and older recycled sediments of the infra-Cambrian Ghabar Group in Yemen to the south. Because Neoproterozic (650-542 Ma) rocks are not widespread in Somalia, Eritrea and Ethiopia, a significant source further to the south is not likely. The dominance of the ultrastable minerals zircon, tourmaline and rutile and apparent absence of metastable, labile minerals in the heavy mineral suite preclude the exposed arc-derived oceanic terrains of the Arabian Shield in the west and north as a significant contributor of the sandstone. An abundance of finer-grained siliciclastic sequences of the same age in the north, is consistent with a northerly transport direction and the existence of a deeper basin (Tabuk Basin?) to the north. The tectonic and depositional model presented in this paper differs from the existing model that envisages sediment transportation and gradual basin filling from west to east during the Paleozoic.

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