Lifetimes and time scales in atmospheric chemistry

2007 ◽  
Vol 365 (1856) ◽  
pp. 1705-1726 ◽  
Author(s):  
Michael J Prather
Keyword(s):  
Atmospheric Chemistry ◽  
Time Scale ◽  
Stratospheric Ozone ◽  
Trace Gases ◽  
Lessons Learned ◽  
Atmospheric Composition ◽  
Environmental Damage ◽  
Trace Species ◽  
Linearized System ◽  
Chemical Response

Atmospheric composition is controlled by the emission, photochemistry and transport of many trace gases. Understanding the time scale as well as the chemical and spatial patterns of perturbations to trace gases is needed to evaluate possible environmental damage (e.g. stratospheric ozone depletion or climate change) caused by anthropogenic emissions. This paper reviews lessons learned from treating global atmospheric chemistry as a linearized system and analysing it in terms of eigenvalues. The results give insight into how emissions of one trace species cause perturbations to another and how transport and chemistry can alter the time scale of the overall perturbation. Further, the eigenvectors describe the fundamental chemical modes, or patterns, of the atmosphere's chemical response to perturbations.

Complexities of communicating atmospheric composition and its impacts during the COVID-19 public health crisis in 2020

2021 ◽  
Author(s):  
Claudia Volosciuk
Keyword(s):  
Public Health ◽  
Carbon Dioxide ◽  
Greenhouse Gases ◽  
Atmospheric Chemistry ◽  
Stratospheric Ozone ◽  
Scientific Information ◽  
Atmospheric Composition ◽  
Physical Parameters ◽  
Health Crisis ◽  
Public Health Crisis

<p>The Global Atmosphere Watch (GAW) Programme of the World Meteorological Organization (WMO) is driven by the need to understand the variability and trends in atmospheric composition and the related physical parameters, and to assess the consequences thereof. GAW provides reliable scientific information for a broad spectrum of users, including policymakers, on topics related to atmospheric chemical composition. The programme supports international environmental and climate agreements and improves our understanding of climate change and long-range transboundary air pollution through its work on greenhouse gases, aerosols, reactive gases, atmospheric deposition, stratospheric ozone, and ultraviolet radiation. GAW provides information based on combinations of observations, data analysis and modelling activities, and supports a number of applications at the global, regional and urban scale. This implies a variety of target groups and communication vectors. Due to the complexity and interrelations of the different constituents in atmospheric chemistry and the diversity of the target audience, communication of the related issues represents a substantial challenge. Some examples are questions like “If greenhouse gas emissions are falling, why do concentrations not decrease?”, “if satellite data show pollution reductions, why can’t we say that it is due to emission reductions?” etc.  </p><p>To sustain the credibility and increase the visibility of GAW within the WMO community and other national/international bodies, the broader scientific and policy communities, as well as the general public, increasing efforts towards “communicating GAW” are taken. The global pandemic related to COVID-19 was the dominating topic around the globe in 2020. This required adjustments to communication efforts. Due to in-person meetings being impossible, all communication efforts required delivery and engagement through virtual formats.</p><p>While emissions of carbon dioxide (among others) have decreased temporarily in 2020 due to COVID-19 restrictions, concentrations have continued to increase. This has led to confusion among many non-scientists who were surprised that the restrictions they were experiencing did not even have the effect of decreasing atmospheric concentrations of carbon dioxide. Thereby, the crisis has provided an opportunity to explain the difference between emissions and concentrations, emphasizing that carbon dioxide (and other greenhouse gases) are long-lived and remain in the atmosphere for a long time, and highlighting the importance to reach net-zero emissions. Similar confusion was related to the interpretation of the pollution levels and also required additional communication efforts.</p><p>Reflections on communication of atmospheric composition in the framework of WMO/GAW, including challenges and opportunities during the public health crisis will be presented.</p>

scholarly journals Copernicus stratospheric ozone service, 2009–2012: validation, system intercomparison and roles of input data sets

2015 ◽  
Vol 15 (5) ◽  
pp. 2269-2293 ◽  
Author(s):  
K. Lefever ◽  
R. van der A ◽  
F. Baier ◽  
Y. Christophe ◽  
Q. Errera ◽  
...  
Keyword(s):  
Data Assimilation ◽  
Atmospheric Chemistry ◽  
Ozone Depletion ◽  
Total Ozone ◽  
Chemical Constituents ◽  
Stratospheric Ozone ◽  
Atmospheric Composition ◽  
The Arctic ◽  
Data Sets ◽  
The Tropics

Abstract. This paper evaluates and discusses the quality of the stratospheric ozone analyses delivered in near real time by the MACC (Monitoring Atmospheric Composition and Climate) project during the 3-year period between September 2009 and September 2012. Ozone analyses produced by four different chemical data assimilation (CDA) systems are examined and compared: the Integrated Forecast System coupled to the Model for OZone And Related chemical Tracers (IFS-MOZART); the Belgian Assimilation System for Chemical ObsErvations (BASCOE); the Synoptic Analysis of Chemical Constituents by Advanced Data Assimilation (SACADA); and the Data Assimilation Model based on Transport Model version 3 (TM3DAM). The assimilated satellite ozone retrievals differed for each system; SACADA and TM3DAM assimilated only total ozone observations, BASCOE assimilated profiles for ozone and some related species, while IFS-MOZART assimilated both types of ozone observations. All analyses deliver total column values that agree well with ground-based observations (biases < 5%) and have a realistic seasonal cycle, except for BASCOE analyses, which underestimate total ozone in the tropics all year long by 7 to 10%, and SACADA analyses, which overestimate total ozone in polar night regions by up to 30%. The validation of the vertical distribution is based on independent observations from ozonesondes and the ACE-FTS (Atmospheric Chemistry Experiment – Fourier Transform Spectrometer) satellite instrument. It cannot be performed with TM3DAM, which is designed only to deliver analyses of total ozone columns. Vertically alternating positive and negative biases are found in the IFS-MOZART analyses as well as an overestimation of 30 to 60% in the polar lower stratosphere during polar ozone depletion events. SACADA underestimates lower stratospheric ozone by up to 50% during these events above the South Pole and overestimates it by approximately the same amount in the tropics. The three-dimensional (3-D) analyses delivered by BASCOE are found to have the best quality among the three systems resolving the vertical dimension, with biases not exceeding 10% all year long, at all stratospheric levels and in all latitude bands, except in the tropical lowermost stratosphere. The northern spring 2011 period is studied in more detail to evaluate the ability of the analyses to represent the exceptional ozone depletion event, which happened above the Arctic in March 2011. Offline sensitivity tests are performed during this month and indicate that the differences between the forward models or the assimilation algorithms are much less important than the characteristics of the assimilated data sets. They also show that IFS-MOZART is able to deliver realistic analyses of ozone both in the troposphere and in the stratosphere, but this requires the assimilation of observations from nadir-looking instruments as well as the assimilation of profiles, which are well resolved vertically and extend into the lowermost stratosphere.

scholarly journals An indirect-calibration method for non-target quantification of trace gases applied to a time series of fourth-generation synthetic halocarbons at the Taunus Observatory (Germany)

2021 ◽  
Vol 14 (6) ◽  
pp. 4669-4687
Author(s):  
Fides Lefrancois ◽  
Markus Jesswein ◽  
Markus Thoma ◽  
Andreas Engel ◽  
Kieran Stanley ◽  
...  
Keyword(s):  
Stratospheric Ozone ◽  
Trace Gases ◽  
Mass Range ◽  
Calibration Method ◽  
In Situ Measurements ◽  
Atmospheric Composition ◽  
Fourth Generation ◽  
Calibration Gas ◽  
Tof Ms

Abstract. Production and use of many synthetic halogenated trace gases are regulated internationally due to their contribution to stratospheric ozone depletion or climate change. In many applications they have been replaced by shorter-lived compounds, which have become measurable in the atmosphere as emissions increased. Non-target monitoring of trace gases rather than targeted measurements of well-known substances is needed to keep up with such changes in the atmospheric composition. We regularly deploy gas chromatography (GC) coupled to time-of-flight mass spectrometry (TOF-MS) for analysis of flask air samples and in situ measurements at the Taunus Observatory, a site in central Germany. TOF-MS acquires data over a continuous mass range that enables a retrospective analysis of the dataset, which can be considered a type of digital air archive. This archive can be used if new substances come into use and their mass spectrometric fingerprint is identified. However, quantifying new replacement halocarbons can be challenging, as mole fractions are generally low, requiring high measurement precision and low detection limits. In addition, calibration can be demanding, as calibration gases may not contain sufficiently high amounts of newly measured substances or the amounts in the calibration gas may have not been quantified. This paper presents an indirect data evaluation approach for TOF-MS data, where the calibration is linked to another compound which could be quantified in the calibration gas. We also present an approach to evaluate the quality of the indirect calibration method, select periods of stable instrument performance and determine well suited reference compounds. The method is applied to three short-lived synthetic halocarbons: HFO-1234yf, HFO-1234ze(E), and HCFO-1233zd(E). They represent replacements for longer-lived hydrofluorocarbons (HFCs) and exhibit increasing mole fractions in the atmosphere. The indirectly calibrated results are compared to directly calibrated measurements using data from TOF-MS canister sample analysis and TOF-MS in situ measurements, which are available for some periods of our dataset. The application of the indirect calibration method on several test cases can result in uncertainties of around 6 % to 11 %. For hydro(chloro-)fluoroolefines (denoted H(C)FOs), uncertainties up to 23 % are achieved. The indirectly calculated mole fractions of the investigated H(C)FOs at Taunus Observatory range between measured mole fractions at urban Dübendorf and Jungfraujoch stations in Switzerland.

scholarly journals ACE-FTS measurements of trace species in the characterization of biomass burning plumes

2011 ◽  
Vol 11 (6) ◽  
pp. 16611-16637 ◽  
Author(s):  
K. A. Tereszchuk ◽  
G. González Abad ◽  
C. Clerbaux ◽  
D. Hurtmans ◽  
P.-F. Coheur ◽  
...  
Keyword(s):  
Biomass Burning ◽  
Atmospheric Chemistry ◽  
Atmospheric Composition ◽  
Emission Region ◽  
Free Troposphere ◽  
Airborne Measurements ◽  
Convective Processes ◽  
Trace Species ◽  
Chemistry Experiment

Abstract. To further our understanding of the effects of biomass burning emission on atmospheric composition, we report measurements of trace species from biomass burning plumes made by the Atmospheric Chemistry Experiment Fourier Transform Spectrometer (ACE-FTS) instrument on the SCISAT-1 satellite. An extensive set of 15 molecules, C2H2, C2H6, CH3OH, CH4, CO, H2CO, HCN, HCOOH, HNO3, NO, NO2, N2O5, O3, OCS and SF6 are used in our analysis. Even though most biomass burning smoke is typically confined to the boundary layer, much of these emissions are injected directly into the free troposphere via fire-related convective processes and transported away from the emission region. Further knowledge of the aging of biomass burning emission in the free troposphere is needed. Tracer-tracer correlations are made between known pyrogenic species in these plumes in an effort to classify them and follow their chemical evolution. Criteria such as age and type of biomass material burned are considered. Emission factors are derived and compared to airborne measurements of biomass burning from numerous ecosystems to validate the ACE-FTS data.

scholarly journals ACE-FTS observations of pyrogenic trace species in boreal biomass burning plumes during BORTAS

2013 ◽  
Vol 13 (9) ◽  
pp. 4529-4541 ◽  
Author(s):  
K. A. Tereszchuk ◽  
G. González Abad ◽  
C. Clerbaux ◽  
J. Hadji-Lazaro ◽  
D. Hurtmans ◽  
...  
Keyword(s):  
Boreal Forest ◽  
Biomass Burning ◽  
Atmospheric Chemistry ◽  
Atmospheric Composition ◽  
Fire Season ◽  
Satellite Measurement ◽  
Free Troposphere ◽  
Molar Ratios ◽  
Convective Processes ◽  
Trace Species

Abstract. To further our understanding of the effects of biomass burning emissions on atmospheric composition, the BORTAS campaign (BOReal forest fires on Tropospheric oxidants over the Atlantic using Aircraft and Satellites) was conducted on 12 July to 3 August 2011 during the boreal forest fire season in Canada. The simultaneous aerial, ground and satellite measurement campaign sought to record instances of boreal biomass burning to measure the tropospheric volume mixing ratios (VMRs) of short- and long-lived trace molecular species from biomass burning emissions. The goal was to investigate the connection between the composition and the distribution of these pyrogenic outflows and their resulting perturbation to atmospheric chemistry, with particular focus on oxidant species to determine the overall impact on the oxidizing capacity of the free troposphere. Measurements of pyrogenic trace species in boreal biomass burning plumes were made by the Atmospheric Chemistry Experiment Fourier Transform Spectrometer (ACE-FTS) onboard the Canadian Space Agency (CSA) SCISAT-1 satellite during the BORTAS campaign. Even though biomass burning emissions are typically confined to the boundary layer, outflows are often injected into the upper troposphere by isolated convection and fire-related convective processes, thus allowing space-borne instruments to measure these pyrogenic outflows. An extensive set of 14 molecules – CH3OH, C2H2, C2H6, C3H6O, CO, HCN, HCOOH, HNO3, H2CO, NO, NO2, OCS, O3, and PAN – have been analysed. Included in this analysis is the calculation of age-dependent sets of enhancement ratios for each of the species originating from fires in North America (Canada, Alaska) and Siberia for a period of up to 7 days. Ratio values for the shorter lived primary pyrogenic species decrease over time primarily due to oxidation by the OH radical as the plume ages and values for longer lived species such as HCN and C2H6 remain relatively unchanged. Increasing negative values are observed for the oxidant species, including O3, indicating a destruction process in the plume as it ages such that concentrations of the oxidant species have dropped below their off-plume values. Results from previous campaigns have indicated that values for the molar ratios of ΔO3 /ΔO obtained from the measurements of the pyrogenic outflow from boreal fires are highly variable and range from negative to positive, irrespective of plume age. This variability has been attributed to pollution effects where the pyrogenic outflows have mixed with either local urban NOx emissions or pyrogenic emissions from the long-range transport of older plumes, thus affecting the production of O3 within the plumes. The results from this study have identified another potential cause of the variability in O3 concentrations observed in the measurements of biomass burning emissions, where evidence of stratosphere–troposphere exchange due to the pyroconvective updrafts from fires has been identified. Perturbations caused by the lofted emissions in these fire-aided convective processes may result in the intrusion of stratospheric air masses into the free troposphere and subsequent mixing of stratospheric O3 into the pyrogenic outflows causing fluctuations in observed ΔO3/ΔCO molar ratios.

scholarly journals ACE-FTS observations of pyrogenic trace species in boreal biomass burning plumes during BORTAS

2012 ◽  
Vol 12 (12) ◽  
pp. 31629-31661 ◽  
Author(s):  
K. A. Tereszchuk ◽  
G. González Abad ◽  
C. Clerbaux ◽  
J. Hadji-Lazaro ◽  
D. Hurtmans ◽  
...  
Keyword(s):  
Boreal Forest ◽  
Biomass Burning ◽  
Atmospheric Chemistry ◽  
Forest Fires ◽  
Atmospheric Composition ◽  
Fire Season ◽  
Satellite Measurement ◽  
Mixing Ratios ◽  
Trace Species ◽  
The Impact

Abstract. To further our understanding of the effects of biomass burning emissions on atmospheric composition, the Quantifying the impact of BOReal forest fires on Tropospheric oxidants over the Atlantic using Aircraft and Satellites (BORTAS) campaign was conducted on 12 July to 3 August 2011 during the Boreal forest fire season in Canada. The simultaneous aerial, ground and satellite measurement campaign sought to record instances of Boreal biomass burning to measure the tropospheric volume mixing ratios (VMRs) of short- and long-lived trace molecular species from biomass burning emissions. The goal was to investigate the connection between the composition and the distribution of these pyrogenic outflows and their resulting perturbation to atmospheric chemistry, with particular focus on oxidant species to determine the overall impact on the oxidizing capacity of the free troposphere. Measurements of pyrogenic trace species in Boreal biomass burning plumes were made by the Atmospheric Chemistry Experiment Fourier Transform Spectrometer (ACE-FTS) onboard the Canadian Space Agency (CSA) SCISAT-1 satellite during the BORTAS campaign. Even though most biomass burning smoke is typically confined to the boundary layer, emissions are often injected directly into the upper troposphere via fire-related convective processes, thus allowing space-borne instruments to measure these pyrogenic outflows. An extensive set of 15 molecules, CH3OH, CH4, C2H2, C2H6, C3H6O, CO, HCN, HCOOH, HNO3, H2CO, NO, NO2, OCS, O3 and PAN have been analyzed. Included in this analysis is the calculation of age-dependent sets of enhancement ratios for each of the species.

One year of MAX-DOAS measurements of tropospheric trace gases and aerosols in the suburban area of London

2020 ◽  
Author(s):  
Sebastian Donner ◽  
Steffen Dörner ◽  
Joelle Buxmann ◽  
Steffen Beirle ◽  
David Campbell ◽  
...  
Keyword(s):  
Trace Gases ◽  
Lower Troposphere ◽  
Anthropogenic Pollution ◽  
Tropospheric Chemistry ◽  
Atmospheric Composition ◽  
Vertical Column ◽  
Pollution Levels ◽  
Measurement Site ◽  
Trace Species ◽  
Prevailing Wind Direction

&lt;p&gt;Multi-AXis (MAX)-DOAS instruments record spectra of scattered sun light under different elevation angles. From such measurements tropospheric vertical column densities (VCDs) and vertical profiles of different atmospheric trace gases and aerosols can be determined for the lower troposphere. These measurements allow a simultaneous observation of multiple trace gases (e.g. HCHO, CHOCHO, NO&lt;sub&gt;2&lt;/sub&gt;, etc.) with the same measurement setup. Since November 2018, a MAX-DOAS instrument is operated at the Bayfordbury Observatory, which is located approximately 30 km north of London. This measurement site is operated by the University of Hertfordshire and equipped with an AERONET station, a LIDAR and multiple instruments to measure meteorological quantities and solar radiation. Depending on the prevailing wind direction the air masses at the measurement site can be dominated by the pollution of London (SE to SW winds) or rather pristine air (northerly winds). Therefore, this measurement site is well suited to study the influence of anthropogenic pollution on the atmospheric composition and chemistry at a rather pristine location in the vicinity of London, a major European capital with 9.8 million inhabitants and 4 major international airports.&lt;/p&gt;&lt;p&gt;In this study, trace gas and aerosol profiles are retrieved using the MAinz Profile Algorithm MAPA (Beirle et al., 2018) with a focus on tropospheric formaldehyde (HCHO) which plays an important role in tropospheric chemistry. The HCHO results are combined with the results of other trace species such as NO&lt;sub&gt;2&lt;/sub&gt;, CHOCHO and aerosols in order to identify different chemical regimes and pollution levels.&lt;/p&gt;

scholarly journals Critical issues in trace gas biogeochemistry and global change

2007 ◽  
Vol 365 (1856) ◽  
pp. 1629-1642 ◽  
Author(s):  
David J Beerling ◽  
C Nicholas Hewitt ◽  
John A Pyle ◽  
John A Raven
Keyword(s):  
Atmospheric Chemistry ◽  
Trace Gases ◽  
Ice Cores ◽  
Atmospheric Composition ◽  
Anthropogenic Sources ◽  
Theoretical Modelling ◽  
Trace Gas ◽  
Terrestrial Plants ◽  
Future Evolution ◽  
Critical Issues

The atmospheric composition of trace gases and aerosols is determined by the emission of compounds from the marine and terrestrial biospheres, anthropogenic sources and their chemistry and deposition processes. Biogenic emissions depend upon physiological processes and climate, and the atmospheric chemistry is governed by climate and feedbacks involving greenhouse gases themselves. Understanding and predicting the biogeochemistry of trace gases in past, present and future climates therefore demands an interdisciplinary approach integrating across physiology, atmospheric chemistry, physics and meteorology. Here, we highlight critical issues raised by recent findings in all of these key areas to provide a framework for better understanding the past and possible future evolution of the atmosphere. Incorporating recent experimental and observational findings, especially the influence of CO 2 on trace gas emissions from marine algae and terrestrial plants, into earth system models remains a major research priority. As we move towards this goal, archives of the concentration and isotopes of N 2 O and CH 4 from polar ice cores extending back over 650 000 years will provide a valuable benchmark for evaluating such models. In the Pre-Quaternary, synthesis of theoretical modelling with geochemical and palaeontological evidence is also uncovering the roles played by trace gases in episodes of abrupt climatic warming and ozone depletion. Finally, observations and palaeorecords across a range of timescales allow assessment of the Earth's climate sensitivity, a metric influencing our ability to decide what constitutes ‘dangerous’ climate change.

scholarly journals ACE-FTS measurements of trace species in the characterization of biomass burning plumes

2011 ◽  
Vol 11 (23) ◽  
pp. 12169-12179 ◽  
Author(s):  
K. A. Tereszchuk ◽  
G. González Abad ◽  
C. Clerbaux ◽  
D. Hurtmans ◽  
P.-F. Coheur ◽  
...  
Keyword(s):  
Boundary Layer ◽  
Biomass Burning ◽  
Atmospheric Chemistry ◽  
Atmospheric Composition ◽  
Fourier Transform Spectrometer ◽  
Free Troposphere ◽  
Convective Processes ◽  
Trace Species ◽  
Chemistry Experiment

Abstract. To further our understanding of the effects of biomass burning emissions on atmospheric composition, we report measurements of trace species in biomass burning plumes made by the Atmospheric Chemistry Experiment Fourier Transform Spectrometer (ACE-FTS) instrument on the SCISAT-1 satellite. An extensive set of 15 molecules, C2H2, C2H6, CH3OH, CH4, CO, H2CO, HCN, HCOOH, HNO3, NO, NO2, N2O5, O3, OCS and SF6 are used in our analysis. Even though most biomass burning smoke is typically confined to the boundary layer, some of these emissions are injected directly into the free troposphere via fire-related convective processes and transported away from the emission source. Further knowledge of the aging of biomass burning emissions in the free troposphere is needed. Tracer-tracer correlations are made between known pyrogenic species in these plumes in an effort to characterize them and follow their chemical evolution. Criteria such as age and type of biomass material burned are considered.

scholarly journals Role of the stratospheric chemistry–climate interactions in the hot climate conditions of the Eocene

2019 ◽  
Vol 15 (4) ◽  
pp. 1187-1203 ◽  
Author(s):  
Sophie Szopa ◽  
Rémi Thiéblemont ◽  
Slimane Bekki ◽  
Svetlana Botsyun ◽  
Pierre Sepulchre
Keyword(s):  
Atmospheric Chemistry ◽  
Thermal Structure ◽  
Stratospheric Ozone ◽  
Ozone Layer ◽  
Atmospheric Composition ◽  
Total Column Ozone ◽  
Climate Conditions ◽  
Ozone Distribution ◽  
Hot Climate

Abstract. The stratospheric ozone layer plays a key role in atmospheric thermal structure and circulation. Although stratospheric ozone distribution is sensitive to changes in trace gases concentrations and climate, the modifications of stratospheric ozone are not usually considered in climate studies at geological timescales. Here, we evaluate the potential role of stratospheric ozone chemistry in the case of the Eocene hot conditions. Using a chemistry–climate model, we show that the structure of the ozone layer is significantly different under these conditions (4×CO2 climate and high concentrations of tropospheric N2O and CH4). The total column ozone (TCO) remains more or less unchanged in the tropics whereas it is found to be enhanced at mid- and high latitudes. These ozone changes are related to the stratospheric cooling and an acceleration of stratospheric Brewer–Dobson circulation simulated under Eocene climate. As a consequence, the meridional distribution of the TCO appears to be modified, showing particularly pronounced midlatitude maxima and a steeper negative poleward gradient from these maxima. These anomalies are consistent with changes in the seasonal evolution of the polar vortex during winter, especially in the Northern Hemisphere, found to be mainly driven by seasonal changes in planetary wave activity and stratospheric wave-drag. Compared to a preindustrial atmospheric composition, the changes in local ozone concentration reach up to 40 % for zonal annual mean and affect temperature by a few kelvins in the middle stratosphere. As inter-model differences in simulating deep-past temperatures are quite high, the consideration of atmospheric chemistry, which is computationally demanding in Earth system models, may seem superfluous. However, our results suggest that using stratospheric ozone calculated by the model (and hence more physically consistent with Eocene conditions) instead of the commonly specified preindustrial ozone distribution could change the simulated global surface air temperature by as much as 14 %. This error is of the same order as the effect of non-CO2 boundary conditions (topography, bathymetry, solar constant and vegetation). Moreover, the results highlight the sensitivity of stratospheric ozone to hot climate conditions. Since the climate sensitivity to stratospheric ozone feedback largely differs between models, it must be better constrained not only for deep-past conditions but also for future climates.

Sign in / Sign up

Export Citation Format

Share Document